Skip to main content
Log in

The influence of niobium supersaturation in austenite on the static recrystallization behavior of low carbon microalloyed steels

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

This work describes the effect of Nb supersaturation in austenite, as it applies to the strain-induced precipitation potential of Nb(CN), on the suppression of the static recrystallization of austenite during an isothermal holding period following deformation. Four low carbon steels, microalloyed with Nb, were used in this investigation. Three of the steels had variations in Nb levels at constant C and N concentrations. Two steels had different N levels at constant C and Nb concentrations. The results from the isothermal deformation experiments and the subsequent measurement of the solution behavior of Nb in austenite show that the recrystallization-stop temperature (T RXN) increases with increasing Nb supersaturation in austenite. Quantitative transmission electron microscopy analysis revealed that the volume fraction of Nb(CN) at austenite grain boundaries or subgrain boundaries was 1.5 to 2 times larger than Nb(CN) volume fractions found within the grain interiors. This high, localized volume fraction of Nb(CN) subsequently led to high values for the precipitate pinning force (F PIN). These values forF PIN were much higher than what would have been predicted from equilibrium thermodynamics describing the solution behavior of Nb in austenite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K.J. Irvine, F.B. Pickering, and T. Gladman:J. Iron Steel Inst., 1967, Feb., p. 161.

  2. K.J. Irvine:Low Alloy High Strength Steels, Nuremberg, The Metallurg Companies, Düsseldorf, 1970, p. 1.

    Google Scholar 

  3. I. Kozasu and T. Osuka: inProcessing and Properties of Low Carbon Steel, J.M. Gray, ed., TMS-AIME, New York, NY, 1973, p. 47.

    Google Scholar 

  4. F.B. Pickering:Microalloying 75, Washington, DC, M. Korchynsky, ed., Union Carbide Corporation, New York, NY, 1977, p. 9.

    Google Scholar 

  5. W.J. McG. Tegart and A. Gittins:The Hot Deformation of Austenite, Cleveland OH, J.B. Bailance, ed., TMS-AIME, Warrendale, PA, 1977, p. 1.

    Google Scholar 

  6. P.K. Amin and F.B. Pickering:Thermomechanical Processing of Microalloyed Austenite, Pittsburgh PA, A.J. DeArdo, G.A. Ratz, and P.J. Wray, eds., TMS-AIME, Warrendale, PA, 1982, p. 1.

    Google Scholar 

  7. J.H. Woodhead:Fundamentals of Microalloying Forging Steels, Golden CO, G. Krauss and S.K. Banerji, eds., TMS-AIME, Warrendale, PA, 1987, p. 3.

    Google Scholar 

  8. C.I. Garcia, E.J. Palmiere, and A.J. DeArdo:Mechanical Working and Steel Processing Proc, Dearborn, MI, Iron and Steel Society, Warrendale, PA, 1989, p. 59.

    Google Scholar 

  9. T. Gladman and F.B. Pickering:J. Iron Steel Inst., 1967, June, p. 653.

  10. M. Ali Bepari:Metall. Trans. A, 1989, vol. 20A, p. 13.

    CAS  Google Scholar 

  11. L.J. Cuddy:Thermomechanical Processing of Microalloyed Austenite, Pittsburgh, PA, A.J. DeArdo, G.A. Ratz, and P.J. Wray, eds., TMS- AIME, Warrendale, PA 1982, p. 129.

    Google Scholar 

  12. L.J. Cuddy:Metall. Trans. A, 1981, vol. 12A, pp. 1313–20.

    Google Scholar 

  13. W. Roberts and B. Ahlblom:Acta Metall., 1978, vol. 26, p. 801.

    Article  CAS  Google Scholar 

  14. R.A.P. Djaic and J.J. Jonas:Metall. Trans., 1973, vol. 4, pp. 621–24.

    Article  CAS  Google Scholar 

  15. R.A. Petkovic, M.J. Luton, and J.J. Jonas:Can. Metall. Q., 1975, vol. 14, p. 137.

    CAS  Google Scholar 

  16. M.J. White and W.S. Owen:Metall. Trans. A, 1980, vol. 11A, pp. 597–604.

    CAS  Google Scholar 

  17. H. Weiss, A. Gittins, G.G. Brown, and W.J. McG. Tegart:J. Iron Steel Inst., 1973, vol. 211, p. 703.

    CAS  Google Scholar 

  18. M.J. Luton, R. Dorvel, and R.A. Petkovic:Metall. Trans. A, 1980, vol. 11A, pp. 411–20.

    CAS  Google Scholar 

  19. S.S. Hansen, J.B. Vander Sande, and M. Cohen:Metall. Trans. A, 1980, vol. 11A, pp. 387–402.

    CAS  Google Scholar 

  20. M.L. Santella: Ph.D. Thesis, University of Pittsburgh, Pittsburgh, PA, 1981, p. 49.

    Google Scholar 

  21. J.G. Speer, J.R. Michael, and S.S. Hansen:Metall. Trans. A, 1987, vol. 18A, pp. 211–22.

    CAS  Google Scholar 

  22. J.G. Speer and S.S. Hansen:Metall. Trans. A, 1989, vol. 20A, pp. 25–38.

    CAS  Google Scholar 

  23. S.S. Brenner, M.G. Burke, L.J. Cuddy, M.K. Miller, and J. Piller:Proc. 29th Int. Field Emission Symp., Göteborg, Sweden, H.-O. Andrén and H. Nordén, eds., Almquist and Wiksell International, Stockholm, 1982, p. 457.

    Google Scholar 

  24. O. Kwon and A.J. DeArdo:Acta Metall., 1991, vol. 39, p. 529.

    Article  CAS  Google Scholar 

  25. E.J. Palmiere: Ph.D. Thesis, University of Pittsburgh, Pittsburgh, PA, 1991, p. 60.

    Google Scholar 

  26. R.W.K. Honeycombe:The Plastic Deformation of Metals, 2nd ed., ASM, Metals Park, OH, 1984, p. 287.

    Google Scholar 

  27. W.C. Leslie:The Physical Metallurgy of Steels, McGraw-Hill Book Company, New York, NY, 1981, p. 43.

    Google Scholar 

  28. J.W. Martin and R.D. Doherty:Stability of Microstructure in Metallic Systems, Cambridge University Press, Cambridge, United Kingdom, 1976, p. 40.

    Google Scholar 

  29. R.W. Cahn:Recrystallization, Grain Growth and Textures, New York, NY, H. Margolin, ed., ASM, Metals Park, OH, 1966, p. 99.

    Google Scholar 

  30. P.A. Beck and P.R. Sperry:Trans. AIME, 1949, vol. 185, p. 240.

    Google Scholar 

  31. P.A. Beck and P.R. Sperry:J. Appl. Phys., 1950, vol. 21, p. 150.

    Article  CAS  Google Scholar 

  32. J.E. Bailey and P.B. Hirsch:Proc. R. Soc. (London), 1962, vol. A267, p. 11.

    Google Scholar 

  33. A. Kelly and G.W. Groves:Crystallography and Crystal Defects, Addison-Wesley Publishing Company, Reading, MA, 1970, p. 198.

    Google Scholar 

  34. J.D. Verhoeven:Fundamentals of Physical Metallurgy, John Wiley and Sons, New York, NY, 1975, p. 77.

    Google Scholar 

  35. C. Zener:Trans. AIME, 1949, vol. 175, p. 15.

    Google Scholar 

  36. M.F. Ashby:Recrystallization and Grain Growth of Multi-Phase and Particle Containing Materials: 1st RISO Int. Symp. on Metallurgy and Material Science, Denmark, N. Hansen, A.R. Jones, and T. Leffers, eds., RISO National Laboratory, Roskilde, Denmark, 1980, p. 325.

    Google Scholar 

  37. T. Gladman:Proc. R. Soc. (London), 1966, vol. 294, p. 298.

    Article  CAS  Google Scholar 

  38. L.J. Cuddy:Recrystallization and Grain Growth of Multi-Phase and Particle Containing Materials: 1st RISO Int. Symp. on Metallurgy and Material Science, Denmark, N. Hansen, A.R. Jones, and T. Leffers, eds., RISO National Laboratory, Roskilde, Denmark, 1980, p. 317.

    Google Scholar 

  39. J.M. Silcock:J. Iron Steel Inst, 1963, vol. 201, p. 409.

    CAS  Google Scholar 

  40. A.T. Davenport, L.C. Brossard, and R.E. Miner:J. Met., 1975, vol. 27, p. 21.

    Google Scholar 

  41. E.J. Palmiere, C.I. Garcia, and A.J. DeArdo:Metall. Trans. A, 1994, vol. 25A, p. 277.

    CAS  Google Scholar 

  42. G. Fitzsimons, H.A. Kuhn, A.J. DeArdo, and V.M. Sample:ASTM Symp. Compression Testing of Homogeneous Materials and Composites, ASTM, Williamsburg, VA, 1982, p. 27.

    Google Scholar 

  43. E.J. Palmiere, C.I. Garcia, and A.J. DeArdo:Int. Symp. on Low- Carbon Steels for the 90's, R. Asfahani and G. Tither, eds., TMS- AIME, Warrendale, PA, 1993, p. 121.

    Google Scholar 

  44. M.F. Ashby and R. Ebeling:Trans. AIME, 1966, vol. 236, p. 1396.

    CAS  Google Scholar 

  45. P.M. Kelly:Met. Forum, 1982, vol. 5, p. 13.

    CAS  Google Scholar 

  46. W. Charnock and J. Nutting:J. Met. Sci., 1967, vol. 1, p. 123.

    Article  CAS  Google Scholar 

  47. H. Nordberg and B. Aronsson:J. Iron Steel Inst., 1968, Dec, p. 1263.

  48. J.P. Hirth:Metall. Trans., vol. 3, 1972, pp. 3047–67.

    CAS  Google Scholar 

  49. A.S. Keh:Direct Observation of Imperfections in Crystals, J.B. Newkirk and J.H. Wernick, eds., Wiley-Interscience, New York, NY, 1962, p. 213.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Palmiere, E.J., Garcia, C.I. & DeArdo, A.J. The influence of niobium supersaturation in austenite on the static recrystallization behavior of low carbon microalloyed steels. Metall Mater Trans A 27, 951–960 (1996). https://doi.org/10.1007/BF02649763

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02649763

Keywords

Navigation