Kinetics of grain coarsening during sintering of Co-Cu and Fe-Cu Alloys with low liquid contents

Abstract

The coarsening of grains immersed in varying amount of liquid matrix is investigated in Fe-Cu and Co-Cu alloys at the liquid phase sintering temperatures. Specimens containing 20, 30, and 50 wt pct Cu have been prepared by compacting and sintering mixtures of fine powders. With 50 wt pct of Cu, spherical grains are dispersed in the liquid matrix. With 20 wt pct of Cu, anhedral grains are in contact with the neighbors across grain boundaries or thin liquid films, and the liquid matrix forms continuous prisms along the three grain contacts. The form of the rate law for grain coarsening at all compositions agrees with predictions of the diffusion controlled Ostwald ripening theories of Lifshitz, Slyozov, Wagner, and others. The coarsening rate also increases with decreasing matrix content. The activation energy for grain coarsening does not vary with specimen composition. Therefore, the rate controlling mechanism for coarsening of the anhedral grains in contact with each other appears to be the solution and reprecipitation of solute atoms by diffusion through the liquid matrix.