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Manganese dioxide depolarizer for biomedical electrodes

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Abstract

The electrochemical and toxicological characteristics of manganese dioxide (MnO2) have been described. Details of the construction and testing of surface MnO2 electrode are presented. The reported data and the results of tests confirm that a MnO2 electrode sufficiently stable and free from polarization effects can be constructed.

Sommaire

On a décrit les caractéristiques électrochimiques et toxicologiques du dioxyde de manganèse (MnO2). On donne les détails de la construction et l'essayage d'une électrode de surface MnO2. Les données expérimentales signalées et les résultats des épreuves confirment qu'on peut construire une électrode MnO2 suffisamment stable et exempte des effets de la polarisation.

Zusammenfassung

Die elektrochemischen und toxikologischen Eigenschaften von Mangandioxid (MnO2) wurden beschrieben. Einzelheiten des Baues und der Prüfung einer Oberflächen-MnO2-Elektrode werden vorgelegt. Die berichteten Daten und die Ergebnisse von Prüfungen bestätigen, daß eine MnO2-Elektrode gebaut werden kann, die genügend beständig und frei von Polarisationswirkungen ist.

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References

  • Balewski, L. andBrenet, J. P. (1967) A new method for the study of the electrochemical reactivity of manganese dioxide.Electrochem. Technol. 5, 527–531.

    Google Scholar 

  • Benson, P., Price, W. B. andTye, F. L. (1967) Potential-pH relationship of gamma manganese dioxide.Electrochem. Technol. 5, 517–523.

    Google Scholar 

  • Bienvenu, P., Nofre, C. andCier, A. (1963) Toxicité générale comparée des ions métalliques. Relation avec la classification périodique.C. R. hébd. seanc Acad. Sci., Paris 256, 1043–1044.

    Google Scholar 

  • Borg, D. C. andCotzias, G. C. (1958) Manganese metabolism in man. Rapid exchange of56Mn with tissue as demonstrated by blood clearance and liver uptake.J. clin. Invest. 37, 1269–1278.

    Article  Google Scholar 

  • Chreitzberg, A. M. Jr., Allenson, D. R. andVosburgh, W. C. (1955) Formation of manganese (II) ion in the discharge of the manganese dioxide electrode.J. electrochem. Soc. 102, 557–561.

    Google Scholar 

  • Chreitzberg, A. M. Jr andVosburch, W. C. (1957) The overpotential of the manganese dioxide electrode.J. electrochem. Soc. 104, 1–5.

    Google Scholar 

  • Cotzias, G. C. (1962) Manganese. InMineral metabolism. Eds:C. L. Comar andF. Bronner, Vol. 0, Part B, pp. 403–442. Academic Press, New York.

    Google Scholar 

  • Covington, A. K., Talukdar, P. K. andThirsk, H. R. (1957) Standard electrode potentials of some synthetic manganese dioxides.Electrochem. Technol. 5, 523–527.

    Google Scholar 

  • Era, A., Takehara, Z. andYoshizawa, S. (1967) Discharge mechanism of the manganese dioxide electrode.Electrochim. Acta 12, 1199–1212.

    Article  Google Scholar 

  • Ferrell, D. T. Jr andVosburgh, W. C. (1951) A proposed mechanism for the discharge of the managanese dioxide electrode.J. electrochem. Soc. 98, 334–341.

    Google Scholar 

  • Gabano, J. P., Morignat, B. andLaurent, J. F. (1967) Chemical and electrochemical reduction of γ-manganese dioxide.Electrochem. Technol. 5, 531–534.

    Google Scholar 

  • Janz, G. J. andIves, D. J. (1968) Silver, silver chloride electrodes.Ann. N.Y. Acad. Sci. 148, 210–221.

    Google Scholar 

  • Jennings, C. W. andVosburgh, W. C. (1952) A proposed mechanism for selfdischarge of the Leclanché cell.J. electrochem. Soc. 99, 309–316.

    Google Scholar 

  • Johnson, R. S. andVosburgh, W. C. (1952) The reproducibility of the manganese dioxide electrode and the change of electrode potential with pH.J. electrochem. Soc. 99, 317–322.

    Google Scholar 

  • Kang, H. Y. andLiang, C. C. (1968) The anodic oxidation of manganese oxides in alkaline electrolytes.J. electrochem. Soc. 115, 6–10.

    Google Scholar 

  • Kozawa, A., Kalnoki-Kiss andYeager, J. F. (1966) Solubilities of Mn(II) and Mn(III) ions in concentrated alkaline solutions.J. electrochem. Soc. 113, 405–409.

    Google Scholar 

  • Massie, H., Racine, P., Pasker, R., Hahn, A. W. andSun, H. H. (1968) Study of power generating implantable electrodes.Med. biol. Engng 6, 503–516.

    Article  Google Scholar 

  • Nencini, R. andPasquali, E. (1968) Manganese dioxide electrodes for stimulation and recording.Med. biol. Engng 6, 193–197.

    Article  Google Scholar 

  • Nichols, J. G. W. (1932) Electrolytic manganese dioxide.Trans. electrochem. Soc. 62, 393–403.

    Google Scholar 

  • Nofre, C., Clement, J. M. andCier, A. (1963) Toxicité comparée de quelques ions métalliques et de leur chélate a l'acide éthylènediaminetétracétique.Path. Biol. (Paris) 11, 853–865.

    Google Scholar 

  • Oettingen, W. T. von (1935) Manganese; its distribution, pharmacology and health hazards.Physiol. Rev. 15, 175–207.

    Google Scholar 

  • Rodier, J. (1955) Manganese poisoning in Moroccan miners.Br. J. Ind. Med. 12, 21–35.

    Google Scholar 

  • Sabatini-Smith, S. andHolland, W. C. (1969) Influence of manganese and oubain on the rate of action of calcium on atrial contractions.Am. J. Physiol. 216, 244–248.

    Google Scholar 

  • Sabbatani, L. (1931) Ricerche farmacologiche sul manganese.Archs Sci. Biol. 16, 141–159.

    Google Scholar 

  • Schwan, H. P. (1968) Electrode polarization impedance and measurements in biological materials.Ann. N.Y. Acad. Sci. 148, 191–209.

    Google Scholar 

  • Sollmann, T. (1957) Ina Manual of Pharmacology and its Applications to Therapeutics and Toxicology, pp. 1278–1280. Saunders, Philadelphia.

    Google Scholar 

  • Spector, W. S. (1956) InHandbook of Toxicology, Vol. I. Saunders, Philadelphia.

    Google Scholar 

  • Sullivan, M. (1940) Manganese hydroxide in treatment of acne vulgaris, pustular acne, furuncolosis, sycosis vulgaris and psoriasis.J. Am. med. Ass. 114, 246–248.

    Google Scholar 

  • Vetter, K. J. andJaeger, N. (1966) Potentialausbildung and der Mangandioxidelectrode als oxidelectrode mit nichstöchiometrischem oxid.Electrochim. Acta 11, 401–419.

    Article  Google Scholar 

  • Vosburgh, W. C. (1959) The manganese dioxide electrode.J. electrochem. Soc. 106, 839–845.

    Google Scholar 

  • Vosburgh, W. C., Johnson, R. S., Reiser, J. S. andAllenson, D. R. (1955) A further study of electrodeposited manganese dioxide electrodes.J. electrochem. Soc. 102, 151–155.

    Google Scholar 

  • Vosburgh, W. C., Pribble, M. J., Kozawa, A. andAhmad Sam (1958) Formation of manganese (II) ion in the discharge of the managanese dioxide electrode-II. Effect of volume and pH of electrolyte.J. electrochem. Soc. 105, 1–4.

    Google Scholar 

  • Weinman, J. andMahler, J. (1964) An analysis of electrical properties of metal electrodes.Med. biol. Engng 2, 299–310.

    Article  Google Scholar 

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Nencini, R., Pasquali, E. Manganese dioxide depolarizer for biomedical electrodes. Med. & biol. Engng. 8, 137–143 (1970). https://doi.org/10.1007/BF02509322

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