Skip to main content
SpringerLink
Log in

A note on the influence of water vapour in the oxidation of propene to acrylic acid on a mixed oxide catalyst

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The interaction of propene and H2 18O in the absence of gaseous oxygen was studied on a Mo−W−Sn−Te−O catalyst prepared for the production of acrylic acid. The flow reactor working at low pressures was placed close to the ion source of the mass spectrometer. It was found that the formation of an acrolein-lattice oxygen complex is an intermediate step in the formation of acrylic acid. The acrolein type complex reacts further with oxygen from water to give acrylic acid. Evidence was found for the formation of unstable products from water on mixed oxide catalysts of molybdate type.

Abstract

Было исследовано взаимодействие пропилене и H2O18 в отсутствии газового кислорода с катализатором предназначенным для производства акриловой кислоты. Измерения проводились при низких давлениях в проточном реакторе помещенном вблизи ионного источника масс спектрометра. Было установлено, что акролеин возникает за счет кислорода решетки катализатора. Комплекс типа акролеина окисляется в далнейшем кислородом воды в акриловую кислоту. Некоторые результаты можно объяснить возникновением нестабильных продуктов при взаимодействии воды и смешанных катализаторов молибдатного типа.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Y. Moro-Oka, Y. Takita, A. Ozaki: J. Catal.,27, 177 (1972).

    Google Scholar 

  2. Y. Moro-Oka, T. Ohhahata, Y. Takita, A. Ozaki: Bull. Chem. Soc. Jap.,46, 681 (1973).

    CAS  Google Scholar 

  3. N. Giordano, A. Vaghi, J. C. J. Bart, A. Castellan: J. Catal.,38, 11 (1975).

    CAS  Google Scholar 

  4. Z. Dolejšek, J. Nováková: J. Catal.,37, 540 (1975).

    Google Scholar 

  5. French. Pat. 1,4258 71 (1966).

  6. W. M. H. Sachtler, V. H. V. De Boer: Proc. 3rd Intern. Congress on Catalysis,1, 252 (1965).

    CAS  Google Scholar 

  7. T. V. Andruskevich, G. K. Boreskov, L. L. Kuznetsova, L. M. Plyasova, Yu. N. Tyurin, Yu. M. Scekoscichin: Kinet. Katal.,15, 424 (1974).

    Google Scholar 

  8. T. V. Andruskevich, G. K. Boreskov, Yu. N. Tyurin, T. B. Dneprovskaya, L. V. Starchenko: Dokl. Akad. Nauk SSR,215, 110 (1974).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. J. Heyrovsky Institute of Physical Chemistry and Electrochemistry, ČSAV, Máchova 7, 121 38, Prague 2, Czechoslovakia

    J. Nováková, Z. Dolejšek & K. Habersberger

Authors
  1. J. Nováková
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Dolejšek
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Habersberger
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nováková, J., Dolejšek, Z. & Habersberger, K. A note on the influence of water vapour in the oxidation of propene to acrylic acid on a mixed oxide catalyst. React Kinet Catal Lett 4, 389–395 (1976). https://doi.org/10.1007/BF02342580

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02342580

Keywords

Search

Navigation