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Interaction of hydrogen sulfide with molybdophosphoric heteropolyacid

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Abstract

The effect of hydrogen sulfide on P−12Mo heteropolyacid has been studied using ESR, IR spectroscopic and thermal analysis methods. It has been established that hydrogen sulfide can be chemisorbed like water and no entering of sulfur into the anion structure takes place.

Abstract

С помощью методов ЭПР, ИКС и ТА исследовано воздействие сероводорода на P−12Mo гетерополикислоту. Показано, что сероводород может хемосорбироваться аналогично воде. Вхождение серы в структуру аниона не происходит.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, Russia

    T. Kh. Shokhireva, T. M. Yurieva, A. A. Altynnikov, V. F. Anufrienko, L. M. Plyasova & G. S. Litvak

  2. Institute of Kinetics and Catalysis, Sofia, Bulgaria

    A. A. Spojakina & N. Kostova

Authors
  1. T. Kh. Shokhireva
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  2. T. M. Yurieva
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  3. A. A. Altynnikov
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  4. V. F. Anufrienko
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  5. L. M. Plyasova
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  6. G. S. Litvak
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  7. A. A. Spojakina
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  8. N. Kostova
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Shokhireva, T.K., Yurieva, T.M., Altynnikov, A.A. et al. Interaction of hydrogen sulfide with molybdophosphoric heteropolyacid. React Kinet Catal Lett 47, 177–185 (1992). https://doi.org/10.1007/BF02137647

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  • DOI: https://doi.org/10.1007/BF02137647

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