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Catalytic properties of palladium complexes with silica-anchored phosphine ligands in vinyl exchange reaction

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Abstract

Catalytic properties of Pd complexes with phosphine ligands anchored to silica have been studied. The valence state of Pd and the acidity of the alcohol were found to influence the rate of vinyl exhange. A possible reaction mechanism is proposed.

Abstract

Изучены каталитические свойства комплексов палладия с закрепленными на поверхности силикагеля фосфиновыми лигандами. Исследовано влияние степени окисления иона палладия и кислотности спиртов на скорость реакции винильного обмена. Предложен возможный механизм реакции винильного обмена.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    S. I. Chistyakov, V. A. Semikolenov, V. A. Likholobov & Yu. I. Yermakov

Authors
  1. S. I. Chistyakov
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  2. V. A. Semikolenov
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  3. V. A. Likholobov
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  4. Yu. I. Yermakov
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Chistyakov, S.I., Semikolenov, V.A., Likholobov, V.A. et al. Catalytic properties of palladium complexes with silica-anchored phosphine ligands in vinyl exchange reaction. React Kinet Catal Lett 12, 177–181 (1979). https://doi.org/10.1007/BF02071907

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  • DOI: https://doi.org/10.1007/BF02071907

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