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Influence of the substructure of supported titanium-magnesium catalysts on their activity in olefin polymerization

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Abstract

The influence of the substructure of magnesium chloride on the composition and activity of catalysts prepared by supporting TiCl4 on MgCl2 has been studied. Strong binding of TiCl4 with the formation of highly active catalysts is shown to occur upon interaction with defects in the magnesium chloride structure.

Abstract

Исследовано влияние субструры хлорида магния на состав и активность катадизаторов, получаемых при нанесении TiCl4 на MgCl2. Установлено, что прочное связывание TiCl4 образованием высокоактивных катализаторов происходит при взаимодействии его с дефектами структуры хлорида магния.

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Makhtarulin, S.I., Moroz, E.M., Vermel, E.E. et al. Influence of the substructure of supported titanium-magnesium catalysts on their activity in olefin polymerization. React Kinet Catal Lett 9, 269–274 (1978). https://doi.org/10.1007/BF02070498

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  • DOI: https://doi.org/10.1007/BF02070498

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