Abstract
The consequence of filling NO and N2 thermodesorption states and the adsorption rate are found to depend on the initial surface structure. The initial sticking coefficients for (1×1) and (hex) structures are 1 and 0.35, respectively. If ΘNO < 0.3 ML, the dissociation probability of NO is shown to be higher when adsorption occurs on the unreconstructed surface.
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Zemlyanov, D.Y., Smirnov, M.Y. & Gorodetskii, V.V. NO adsorption on reconstructed and unreconstructed Pt(100) surface at 300 K TDS studies. React Kinet Catal Lett 53, 87–95 (1994). https://doi.org/10.1007/BF02070117
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DOI: https://doi.org/10.1007/BF02070117