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Activity of catalysts in 1-butanol reaction with H2S

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Abstract

Reaction of 1-butanol with H2S has been studied at 300 °C and 0.1 MPa on catalysts of various composition. The catalysts that contain mainly strong proton sites on their surface accelerate dehydration of alcohol alone. In the presence of catalysts possessing acidic and basic Lewis sites 1-butanethiol is formed. Reaction rate increases as the concentration and strength of Lewis acid sites increase.

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Authors and Affiliations

  1. Federal Scientific Center, Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    A. V. Mashkina, V. N. Yakovleva & L. N. Khairulina

Authors
  1. A. V. Mashkina
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  2. V. N. Yakovleva
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  3. L. N. Khairulina
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Mashkina, A.V., Yakovleva, V.N. & Khairulina, L.N. Activity of catalysts in 1-butanol reaction with H2S. React Kinet Catal Lett 56, 205–211 (1995). https://doi.org/10.1007/BF02066969

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  • DOI: https://doi.org/10.1007/BF02066969

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