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Measurement of adsorption heats of nitrogen on metal nitrides

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Abstract

Adsorption heats q and activation energies of the nitrogen exchange on several metal nitrides have been compared. For the systems capable of changing readily their composition upon varying conditions, the isotope exchange is suggested to be the most reliable method of the determination of q.

Abstract

Проведено сопоставление теплот адсорбции с энергией активации изотопного обмена азота на ряде нитридов металлов. Сделан вывод, что для систем, спосо бных сравнительно легко менять свой состав при изменении условий, изотопный обмен является наиболее надёжным методом определения величины р.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    A. S. Kharitonov, G. K. Boreskov, G. I. Panov & Yu. D. Pankratiev

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  1. A. S. Kharitonov
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  2. G. K. Boreskov
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  3. G. I. Panov
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  4. Yu. D. Pankratiev
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Kharitonov, A.S., Boreskov, G.K., Panov, G.I. et al. Measurement of adsorption heats of nitrogen on metal nitrides. React Kinet Catal Lett 22, 309–314 (1983). https://doi.org/10.1007/BF02066193

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  • DOI: https://doi.org/10.1007/BF02066193

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