Skip to main content
Log in

195Pt and119Sn NMR studies of Pt−Sn complexes in the Pt(II)−Sn(II)-i-C3H7OH system

Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

According to195Pt and119Sn NMR studies of the interaction of (C3H6)PtCl2 with SnCl2·2H2O in dehydrated isopropanol solution, three types of complexes with atomic ratios Pt:Sn=1∶5, 1∶2 and 1∶1, being in a dynamic equilibrium, have been revealed. A removal of the free HCl promotes the formation of the Pt:Sn=1∶2 complex.

Abstract

Методом ЯМР на ядрах195Pt и119Sn изучено взаимодействие (C3H6)PtCl2 со SnCl2 2H2O в растворе абсолютированного изопропанола. Обнаружено три типа комплексов с атомным отношением Pt:Sn=1∶5, 1∶2 и 1∶1, находящихся между собой в подвижном равновесии. Удаление из раствора свободной HCl способствует образованию комплекса Pt:Sn=1∶2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. B. Shitova, L. Ya. Alt, A. S. Belyi, V. P. Perevalova, V. K. Duplyakin: React. Kinet. Catal. Lett.,23, 17 (1983).

    Article  CAS  Google Scholar 

  2. L. Ya. Alt, A. S. Belyi, V. K. Duplyakin, V. P. Perevalova, N. B. Shitova: React. Kinet. Catal. Lett.,23, 13 (1983).

    Article  CAS  Google Scholar 

  3. V. P. Perovalova, A. S. Belyi, L. Ya. Alt, V. K. Duplyakin: Zh. Koord. Khim. (in press).

  4. J. H. Nelson, V. Cooper, R. W. Rudolf: Inorg. Chem. Lett.,16, 263 (1980).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alt, L.Y., Melnikova, V.P., Startsev, A.N. et al. 195Pt and119Sn NMR studies of Pt−Sn complexes in the Pt(II)−Sn(II)-i-C3H7OH system. React Kinet Catal Lett 23, 21–23 (1983). https://doi.org/10.1007/BF02065657

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02065657

Keywords

Navigation