Abstract
Kinetic studies of methylthiophene hydrogenation by dihydrogen in the presence of sulfurized aluminoppalladium catalysts were carried out at T=220–300°C and\(P_{H_2 } \)=3.3–9.5 MPa. An equation is suggested that accounts for the retarding effect of the product.
Abstract
Исследована кинетика реакции гидрирования метилтиофена молекулярным водородом в присутствии осерненного алюмопалладиевого катализатора при T=220–300°C, давлении водорода 3,3–9,5 МРа. Предложено уравнение, учи-тывающее тормозящее действие продукта.
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References
A. V. Mashkina: Heterogeneous Catalysis in Chemistry of Organic Sulfur Compounds. Nauka, Novosibirsk 1977.
G. L. Veitsman, T. S. Sukhareva, A. V. Mashkina: in Catalysts for Production and Conversion of Sulfurous Compounds, Inst. Catal., Novosibirsk 1979.
A. A. Zirka, R. A. Sagitullin, R. M. Masagutov, A. Kh. Shapirov, N. K. Lyapina, A. V. Mashkina: React. Kinet. Catal. Lett.,25, 171 (1984)
V. B. Benkovskii, V. S. Nikitina, N. K. Lyapina, R.A. Rashitova, T. S. Nikitina: Neftekhimiya,12, 271 (1972)
A. Yermakova, P. Valko, S. Vajda: Appl. Catal.,2, 130 (1982)
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Zirka, A.A., Yermakova, A. & Mashkina, A.V. Kinetic studies of methylthiophene hydrogenation on sulfurized aluminopalladium catalysts. React Kinet Catal Lett 43, 487–494 (1991). https://doi.org/10.1007/BF02064717
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DOI: https://doi.org/10.1007/BF02064717