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Study of cryostructurization of polymer systems

IV. Cryostructurization of the system: Solvent — vinyl monomer — divinyl monomer — initiator of polymerization

  • Polymer Science
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Abstract

The influence of freezing on the properties of forming cross-linked polyacrylamide gels as examplified by the system: water — acylamide — N,N′-methylene-bis-acrylamide — (ammonium persulfate + N,N,N′,N'-tetramethylethylenediamine) was investigated. In cryostructurization, the freezing out of the solvent is shown to lead to a decrease in the critical concentration of gelation due to the concentrating effects of the reacting substances. A comparative analysis of the osmotic characteristics of gels prepared in liquid or crystallized solvent media is presented.

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Author notes

  1. V. I. Lozinsky

    Present address: A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow, USSR

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, USSR Academy of Sciences, Moscow, USSR

    E. S. Vainerman, E. F. Titova, E. M. Belavtseva & S. V. Rogozhin

Authors
  1. V. I. Lozinsky
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  2. E. S. Vainerman
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  3. E. F. Titova
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  4. E. M. Belavtseva
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  5. S. V. Rogozhin
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Lozinsky, V.I., Vainerman, E.S., Titova, E.F. et al. Study of cryostructurization of polymer systems. Colloid & Polymer Sci 262, 769–774 (1984). https://doi.org/10.1007/BF01451705

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  • DOI: https://doi.org/10.1007/BF01451705

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