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Kinetics of aquation of pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion

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Summary

The aquation of pentaammine (substituted salicylato) cobalt(III) complexes [(NH3)5CoO2CC6H3(X)OH]2+,X = 5-SO3, 5-Br, 5-NO2, and 3-NO2 in the presence of ferric ion was studied spectrophotometrically in the 65°–80° range. Ferric ion catalyses the aquation of the substratesvia formation of a reactive binuclear species.

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References

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Authors and Affiliations

  1. Department of Chemistry, Utkal University, Bhubaneswar-4, India

    Anadi C. Dash & Rabindra K. Nanda

  2. Department of Chemistry, B. J. B. College, Bhubaneswar-6, India

    Himansu K. Patnaik

Authors
  1. Anadi C. Dash
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  2. Rabindra K. Nanda
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  3. Himansu K. Patnaik
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Dash, A.C., Nanda, R.K. & Patnaik, H.K. Kinetics of aquation of pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion. Transition Met Chem 2, 183–185 (1977). https://doi.org/10.1007/BF01402717

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  • DOI: https://doi.org/10.1007/BF01402717

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