Abstract
The reaction of equal millimolar quantities of CdBr2 and 2-hydroxyethyl sulfide in 3∶1 CH3CN∶CH3OH produced [Cd(OH2)2(μBr)4 (Cd(2-hydroxy ethyl sulfide) (μ-Br))2]n. The compound crystallizes as a bromide-bridged polymer with hydrogen bonding interactions between the polymeric chains. Each of the two unique metal centers has a distorted octahedral geometry. The thioether ligand is bidentate to one cadmium position with one alcoholic terminus uncoordinated. The uncoordinated portion of the molecule is disordered with each conformation participating in slightly different hydrogen bonding environments. The other unique cadmium center is coordinated to four bridging bromides and twotrans water molecules.
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Rogers, R.D., Bond, A.H. & Aguinaga, S. Synthesis and crystallographic characterization of [Cd(OH2)2 (μ-Br)4 (Cd(2-hydroxyethyl sulfide) (μ-Br))2]n . Journal of Crystallographic and Spectroscopic Research 23, 857–862 (1993). https://doi.org/10.1007/BF01195732
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DOI: https://doi.org/10.1007/BF01195732