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Binary nonadditive hard-sphere mixtures at high dimension

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Abstract

At high spatial dimension, a suitably scaled classical system of interacting particles truncates at second virial terms. A binary mixture of nonadditive hard spheres with sufficiently repulsive interaction between unlike particles decomposes at sufficiently high density into two coexisting phases. The region around the critical density behaves classically.

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Authors and Affiliations

  1. Courant Institute of Mathematical Sciences, New York University, 10012, New York, New York

    H. -O. Carmesin & J. K. Percus

  2. Chemistry Department, SUNY at Albany, 12222, New York, New York

    H. -O. Carmesin & H. L. Frisch

  3. Universität Bremen, Postfach 330 440, 2800, Bremen 33, Germany

    J. K. Percus

  4. Physics Department, New York University, 10003, New York, New York

    H. L. Frisch

Authors
  1. H. -O. Carmesin
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  2. H. L. Frisch
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  3. J. K. Percus
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Carmesin, H.O., Frisch, H.L. & Percus, J.K. Binary nonadditive hard-sphere mixtures at high dimension. J Stat Phys 63, 791–795 (1991). https://doi.org/10.1007/BF01029212

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  • DOI: https://doi.org/10.1007/BF01029212

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