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Kinetics of hydrolysis of silatranes in a neutral medium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of hydrolysis of 1-organyl- and 1-alkoxylsilatranes in a neutral medium was studied by UV spectroscopy.

  2. 2.

    A scheme has been proposed for the neutral hydrolysis of silatranes with the formation of a four-centered intermediate at the first stage, followed by slow opening of the silatrane skeleton.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    M. G. Voronkov, D. -S. D. Toryashinova, V. P. Baryshok, B. A. Shainyan & É. I. Brodskaya

Authors
  1. M. G. Voronkov
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  2. D. -S. D. Toryashinova
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  3. V. P. Baryshok
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  4. B. A. Shainyan
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  5. É. I. Brodskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12,.pp. 2673–2676, December, 1984.

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Voronkov, M.G., Toryashinova, D.S.D., Baryshok, V.P. et al. Kinetics of hydrolysis of silatranes in a neutral medium. Russ Chem Bull 33, 2447–2450 (1984). https://doi.org/10.1007/BF00960256

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  • DOI: https://doi.org/10.1007/BF00960256

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