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Synthesis and some reactions of 2-X-perfluoro-2-methyl-3-pentanones

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Some 2-X-perfluoro-2-methyl-3-pentanones (X=Cl, Br) were obtained by reacting perfluoro-2-methyl-2-pentene oxide with NaCl or NaBr in diglyme. 2-Chloroperfluoro-2-methyl-3-pentanone was also obtained by reacting 2-H-perfluoro-2-methyl-3-pentanone with PCl5.

  2. 2.

    In the 2-X-perfluoro-2-methyl-3-pentanone series (X=F, Cl, Br) the haloform decomposition using aqueous alkali and alkali-metal fluorides is most easily accomplished when X=F.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry of the Ural Scientific Center, Academy of Sciences of the USSR, Sverdlovsk

    L. V. Saloutina, T. I. Filyakova, A. Ya. Zapevalov, M. I. Kodess & I. P. Kolenko

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  1. L. V. Saloutina
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  2. T. I. Filyakova
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  3. A. Ya. Zapevalov
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  4. M. I. Kodess
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  5. I. P. Kolenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1893–1896, August, 1982.

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Saloutina, L.V., Filyakova, T.I., Zapevalov, A.Y. et al. Synthesis and some reactions of 2-X-perfluoro-2-methyl-3-pentanones. Russ Chem Bull 31, 1685–1687 (1982). https://doi.org/10.1007/BF00956911

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  • DOI: https://doi.org/10.1007/BF00956911

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