Conclusions
-
1.
On the basis of an analysis of the ESR parameters of Cu(II) ions stabilized in polymers derived from substituted chrysoidines and an examination of the effect of various reagents, a model is proposed for the copper-containing centers.
-
2.
The data obtained indicate the high lability and reactivity of the copper-containing centers in polymers which are catalytically active with respect to the liquid-phase oxidation of hydrocarbons.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
M. P. Terpugova, I. L. Kotlyarevskii, V. G. Mazur, and E. A. Martenko, Izv. Akad. Nauk SSSR, Ser. Khim., 602 (1973).
M. P. Terpugova, Yu. I. Amosov, and I. L. Kotlyarevskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2388 (1978).
C. M. Gury, I. B. Reunor, and M. C. D. Symons, J. Chem. Soc. A, 2299 (1969).
V. Malatesta and B. R. McGarvey, Can. J. Chem.,53, 3791 (1975).
P. W. Lau and W. C. Lin, J. Inorg. Nucl. Chem.,37, 2389 (1975).
D. R. Lorenz, I. R. Wasson, P. R. Jonson, and D. A. Thornton, J. Inorg. Nucl. Chem.,37, 2297 (1975).
J. Sabramanien, J.-H. Fahrhop, A. Salek, and A. Jossaur, J. Magn. Reson.,15, 19 (1974).
M. Hedaytullah, Bull. Soc. Chim. France, 2957 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1526–1530, July, 1980.
Rights and permissions
About this article
Cite this article
Shklyaev, A.A., Terpugova, M.P., Amosov, Y.I. et al. Structure of copper-containing centers in polyazopolyarenes derived from substituted chrysoidines. Russ Chem Bull 29, 1072–1076 (1980). https://doi.org/10.1007/BF00949156
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00949156