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Composition of olefins formed in the dehydrogenation of n-decane over aluminum-platinum catalysts

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The amounts of α-, cis-, and trans-decenes formed by dehydrogenation of n-decane over an aluminum-platinum catalyst corresponded on average to the proportions 1∶8∶11, and they were little affected by changes in catalyst composition and reaction conditions.

  2. 2.

    Decenes with nonterminal double bonds were formed preferentially (∼95 rel.%).

  3. 3.

    The proportions of the different forms of decenes were close to the calculated values.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. V. Isagulyants, O. D. Sterligov, A. P. Barkova, I. P. Yakovlev, M. A. Panfilova, L. K. Maslova & N. A. Eliseev

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  1. G. V. Isagulyants
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  2. O. D. Sterligov
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  3. A. P. Barkova
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  4. I. P. Yakovlev
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  5. M. A. Panfilova
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  6. L. K. Maslova
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  7. N. A. Eliseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2049–2053, September, 1984.

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Isagulyants, G.V., Sterligov, O.D., Barkova, A.P. et al. Composition of olefins formed in the dehydrogenation of n-decane over aluminum-platinum catalysts. Russ Chem Bull 33, 1869–1873 (1984). https://doi.org/10.1007/BF00948632

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  • DOI: https://doi.org/10.1007/BF00948632

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