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Acidity of ortho-, meta-, and para-barenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The acidity of o-, m-, and p-barenes and some of their derivatives in various solvents was determined by polarography and potentiometric titration.

  2. 2.

    Depending on the nature of the solvent, the acidity can vary greatly, for example, in the case of o-barene the acidity increases by ten units of pKa as we go from alcohol to pyridine.

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Literature cited

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Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University and Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Kashin, K. P. Butin, V. I. Stanko & I. P. Beletskaya

Authors
  1. A. N. Kashin
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  2. K. P. Butin
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  3. V. I. Stanko
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  4. I. P. Beletskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1917–1920, September, 1969.

In conclusion, we should like to thank Professor A. I. Shatenshtein for participating in the discussion of the results.

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Kashin, A.N., Butin, K.P., Stanko, V.I. et al. Acidity of ortho-, meta-, and para-barenes. Russ Chem Bull 18, 1775–1777 (1969). https://doi.org/10.1007/BF00905804

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  • DOI: https://doi.org/10.1007/BF00905804

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