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Characterization of silica-supported vanadia-promoted rhodium catalysts by51V-NMR spectroscopy

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Abstract

Vanadium oxide promoted Rh/SiO2 catalyst precursors which were calcined at 573, 773, 973 and 1173 K, were characterized by51V-NMR. V2O5 is present in all materials and RhVO4 is formed at 1173 K. An additional interaction species with vanadium in distorted tetrahedral oxygen environment is found after calcination at 973 K. These phases might have relevance for catalytic promotion of reduced Rh° metal catalysts by VOx. In addition, distorted tetrahedral VO4 species which are capable of interacting with water molecules (V2 species) and distorted octahedral species having water molecules in their coordination sphere (V5 species) have been detected.

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References

  1. M. Ichikawa, K. Shikakura and M. Hawai, in:Proc. Symp. on Heterogenous Catalysis Related to Energy Problems, Dalian, P.R. China, 1982, paper A 08 J.

  2. G. van der Lee, L. Schuller, H. Post, T.L.F. Favre and V. Ponec, J. Catal. 98 (1986) 522.

    Google Scholar 

  3. G. van der Lee, A.G.T.M. Bastein, J. van den Boogert, B. Schuller, H.-Y. Luo and V. Ponec, J. Chem. Soc., Faraday Trans. I, 83 (1987) 1893.

    Google Scholar 

  4. H.-Y. Luo, A.G.T.M. Bastein, A.A.J.P. Mulder and V. Ponec, Appl. Catal. 38 (1988) 241.

    Google Scholar 

  5. B.J. Kip, P.A.T. Smeets, J. van Grondelle and V. Prins, Appl. Catal. 33 (1987) 181.

    Google Scholar 

  6. B.J. Kip, E.G.F. Hermanns and R. Prins, Appl. Catal. 35 (1987) 141.

    Google Scholar 

  7. F.G.A. van den Berg, J.H.E. Glezer and W.M.H. Sachtler, J. Catal. 93 (1985) 340.

    Google Scholar 

  8. W.M.H. Sachtler, in:Proc. 8th Intern. Congr. Catal., Berlin, 1984 (Dechema, Frankfurt, and Verlag Chemie, Weinheim, 1984) Vol. I, p. 151.

    Google Scholar 

  9. T. Mori, A. Miyamoto, N. Takahashi, M. Fukagaya, T. Hattori and Y. Murakami, J. Phys. Chem. 90 (1986) 5197.

    Google Scholar 

  10. W.M.H. Sachtler and M. Ichikawa, J. Phys. Chem. 90 (1986) 4752.

    Google Scholar 

  11. H. Knözinger, in eds.,Homogeneous and Heterogeneous Catalysis eds. Yu. Yermakov and V. Likholobov (VNU Press, Utrecht, 1986), p. 789.

    Google Scholar 

  12. R.-H. Wang and Y.-S. Xu, J. Mol. Catal. 54 (1988) 478.

    Google Scholar 

  13. Yu. I. Yermakov, Yu. A. Ryndin, O.S. Alekseev, V.I. Zaikovskii and A.V. Pashis, Appl. Catal. 26 (1986) 313.

    Google Scholar 

  14. A. Trunschke, H. Ewald, D. Gutschick, H. Miessner, M. Skupin, B. Walter and H.-C. Boettcher, J. Mol. Catal. 56 (1989) 95.

    Google Scholar 

  15. Z. Hu, T. Wakasugi, A. Maeda, K. Kunimori and T. Uchijima, J. Catal. 127 (1991) 276.

    Google Scholar 

  16. B.J. Hip, P.A.T. Smeets, J.H.M.C. van Wolput, H.W. Zandbergen, J. van Grondelle and R. Prins, Appl. Catal. 33 (1987) 157.

    Google Scholar 

  17. I.S. Shaplygin, I.I. Prosychev and V.B. Lazarev, Russ. J. Inorg. Chem. 23 (1978) 773.

    Google Scholar 

  18. L.W. Vernoni and W.O. Milligan, Texas J. Sci. 3 (1951) 82.

    Google Scholar 

  19. V.M. Mastikhin, O.B. Lapina, V.N. Krasilnikov and A.A. Ivakin, React. Kinet. Catal. Lett. 24 (1984) 119.

    Google Scholar 

  20. V.M. Mastikhin, O.B. Lapina and L.G. Simonova, React. Kinet. Catal. Lett. 24 (1984) 127.

    Google Scholar 

  21. K.I. Zamaraev and V.M. Mastikhin, Colloids and Surfaces 12 (1984) 401.

    Google Scholar 

  22. T.P. Gorshkova, R.I. Maksimovskaya, D.V. Tarasova, N.N. Chumachenko and T.A. Nikoro, React. Kinet. Catal. Lett. 24 (1984) 107.

    Google Scholar 

  23. L.R. LeCostumer, B. Taouk, M. LeMeur, E. Payen, M. Guelton and J. Grimblot, J. Phys. Chem. 92 (1988) 1230.

    Google Scholar 

  24. B. Taouk, H. Guelton, J. Grimblot and J.P. Bonnelle, J. Phys. Chem. 92 (1988) 6700.

    Google Scholar 

  25. H. Eckert and I.E. Wachs, J. Phys. Chem. 93 (1989) 6796.

    Google Scholar 

  26. O.B. Lapina, V.M. Mastikhin, L.G. Simonova and Yu. O. Bulgakova, J. Mol. Catal. 69 (1991) 61.

    Google Scholar 

  27. A.A. Fotiev, B.V. Slobodin and M. Ya. Hodos,'Vanadates: Composition, Synthesis, Structure, Properties (Nauka, Moscow, 1988) p. 268.

    Google Scholar 

  28. T. Beutel, A. Siborov, V.I. Zaikovskii and H. Knözinger, in preparation.

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Authors and Affiliations

  1. Siberian Branch of the Academy of Sciences of the USSR, Institute of Catalysis, 630090, Novosibirsk, USSR

    O. B. Lapina, V. M. Mastikhin & A. V. Nosov

  2. Institut für Physikalische Chemie, Universität München, Sophienstrasse 11, 8000, München 2, Germany

    T. Beutel & H. Knözinger

Authors
  1. O. B. Lapina
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  2. V. M. Mastikhin
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  3. A. V. Nosov
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  4. T. Beutel
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  5. H. Knözinger
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Lapina, O.B., Mastikhin, V.M., Nosov, A.V. et al. Characterization of silica-supported vanadia-promoted rhodium catalysts by51V-NMR spectroscopy. Catal Lett 13, 203–211 (1992). https://doi.org/10.1007/BF00770992

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  • DOI: https://doi.org/10.1007/BF00770992

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