Skip to main content
SpringerLink
Log in

Reactivity of some acetylenic derivatives in electroinitiated polymerization

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The charge distribution in phenylacetylene, methyl propiolate, diphenyldiacetylene as well as in their anion-radieals was calculated by GNDO/2 and EHT methods. According to the obtained results, the electroinitiated polymerization of these monomers takes place by their direct reduction. A good agreement between theoretical and electroanalytical data was observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • FARAFONOV,V.V., GROVU,M. and SIMIONESCU,C.I.: J.Polym.Sci.15, 2041 (1977)

    CAS  Google Scholar 

  • GEIDERICH,M.A., DAVIDOV,B.E., ZALIZNAIA,N.F. and MINAEVA,B.S.: Vysokomol.Soed.A 18, 1264 (1976)

    Google Scholar 

  • HENDRICKSON,J.B., CRAM,D.J. and HAMMOND,G.S.: Chimie organică, Ed.Stiinţifică şi Enciclopedică, Bucurşti, 1976

  • HOFFMANN,R.: J.Chem.Phys.39, 1397 (1963);40, 2474, 2480, 2745 (1964)

    Article  CAS  Google Scholar 

  • MISSIN,V.M., KISILITSA, P.P., BOLONDAEVA,N.I. and CHERKASHIN,M.I.: Vysokomol. Soed.A 18, 1726 (1976)

    Google Scholar 

  • POPLE,J.A. and SEGAL,G.A.: J.Chem.Phys.44, 3289 (1966)

    Article  CAS  Google Scholar 

  • SIMIONESCU,C.I., FARAFONOV,V.V. and GROVU,M.: Rev.Roum.Chim.24, 379 (1979)

    CAS  Google Scholar 

  • SIMIONESCU,C.I. and GROVU,M.: Angew.Makromolek.Chem.111, 149 (1983a)

    Article  CAS  Google Scholar 

  • SIMIONESCU,C.I., GROVU,M. and DUCA,A.: Angew. Makromolek.Chem.115, 47 (1983b)

    Article  CAS  Google Scholar 

  • SIMIONESCU,C.I. and GROVU-IVANOIU,M.: unpublished data

  • SUBRAMANIAN,R.V., JAKUBOWSKI,J.J. and GARG,B.K.: Prepr.A.Chem. Soc.,Div.Polym.Chem.19, 517 (1978)

    Google Scholar 

  • TEYSSIE,PH. and KORN-GIRARD,A.C.: J.Polym.Sci.A 2, 2849 (1964)

    Google Scholar 

  • WALLACH,J. and MANASSEN,J.: J.Polym.Sci.A 1, 1983 (1969)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Macromolecular Chemistry, Polytechnic Institute, 23 August 11, R-6600, Jassy, România

    M. Grovu-lvănoiu, C. I. Simionescu & I. Cocârlă

Authors
  1. M. Grovu-lvănoiu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. I. Simionescu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Cocârlă
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grovu-lvănoiu, M., Simionescu, C.I. & Cocârlă, I. Reactivity of some acetylenic derivatives in electroinitiated polymerization. Polymer Bulletin 14, 117–122 (1985). https://doi.org/10.1007/BF00708468

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00708468

Keywords

Search

Navigation