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Steroid saponins and sapogenins ofAllium. XV. Eruboside B fromAllium erubescens

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Abstract

A new steroid glycoside of the spirostan series — eruboside B (I) — has been isolated from an ethanolic extract of the bulbs ofAllium erubescens C. Koh. In an acid hydrolysate, the aglycone β-chlorogenin (II) and the sugars D-glucose and D-galactose in a ratio of 3:1 have been found. By methylation, partial hydrolysis, and oxidation the structure of the spirostanol (I) has been established as (25R)-5α-spirostan-3β,6β-diol 3-O-{[O-β-D-glucopyranosyl-(1→3)]-[O-β-D-glucopyranosyl-(1→2)]-O-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside}.

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Authors
  1. D. G. Chincharadze
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  2. A. N. Kel'ginbaev
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  3. M. B. Gorovits
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  4. L. I. Éristavi
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  5. T. T. Gorovits
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  6. N. K. Abubakirov
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Additional information

Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Tbilisi State Medical Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 509–514, July–August, 1979.

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Chincharadze, D.G., Kel'ginbaev, A.N., Gorovits, M.B. et al. Steroid saponins and sapogenins ofAllium. XV. Eruboside B fromAllium erubescens . Chem Nat Compd 15, 442–446 (1979). https://doi.org/10.1007/BF00565042

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  • DOI: https://doi.org/10.1007/BF00565042

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