Summary
The methylmercury concentrations in three existing marine biological certified reference materials — TORT-1, DORM-1 and DOLT-1 — are determined by gas chromatography with electron capture detection, cold vapour atomic absorption spectrometry and inductively coupled plasma mass spectrometry after selective isolation of methylmercury. Two such procedures were used. These and the three analytical techniques are evaluated and compared. The certified methylmercury concentrations are: TORT-1, 0.128 ± 0.014; DORM-1, 0.731±0.060; and DOLT-1, 0.080 ± 0.011 Μg Hg/g dry weight.
Similar content being viewed by others
References
Berman SS, McLaren JW, Jamieson WD (1985) In: TaylorJK, Stanley TW (ds) Quality assurance for environmental measurements. ASTM Spec Tech Publ No 867, Philadelphia
Berman SS (1985) In: Wolf WR (ed) Biological reference materials: availability, uses and need for validation of nutrient measurement. Wiley, New York, pp 79–88
Berman SS, Sturgeon RE (1987) Fresenius Z Anal Chem 326:712–715
Williams S (ed) (1984) Official methods of analysis of the Association of Official Analytical Chemists, 14th edn. Association of Official Analytical Chemists Inc., Arlington, VA, pp 472–473
Uthe JF, Solomon J, Grift B (1972) J Assoc Off Anal Chem 55:583–589
Avery B, Cossa D, private communication
O'Reilly JE (1982) J Chromatogr 238:433–444
MacPherson HB, Mykytiuk AP, Berman SS, Russell DS (1982) Can J Spectrosc 27:132–136
Beauchemin D, Siu KWM, Berman SS (1988) Anal Chem 60:2587–2590
Cappon JC, Smith JC (1977) Anal Chem 49:365–369
Olafsson J (1983) In: Grasshoff K, Ehrhardt M, Kremling K (eds) Methods of seawater analysis, 2nd edn. Verlag Chemie, Weinheim, pp 213–217
May K, Stoeppler M, Reisinger K (1987) Toxicol Environ Chem 13:153–159
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Berman, S.S., Siu, K.W.M., Maxwell, P.S. et al. Marine biological reference materials for methylmercury: analytical methodologies used in certification. Z. Anal. Chem. 333, 641–644 (1989). https://doi.org/10.1007/BF00496938
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00496938