Summary
Myrcene (7-methyl-3-methylene-1,6-octadiene) binary copolymers with styrene, methyl methacrylate or p-fluorostyrene were synthesized. Polymer compositions were measured by H-NMR and reactivity ratios were calculated using a nonlinear least squares error-in-variables method. For myrcene-styrene copolymerizations the polymer radicals have a marked preference for myrcene monomer. In the case of the myrcene-MMA copolymerization the growing polymer chains prefer to add the other monomer, i.e. the crossover reaction dominates. The same is true for the myrcene/p-fluorostyrene copolymerization, although the myrcene radical has a higher preference for myrcene monomer in this copolymerization than it does in the myrcene-MMA copolymerization.
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References
R. A. Newmark and R. N. Majumdar, J. Polym. Sci., Polym. Chem. Ed., 26, 71 (1988).
C. S. Marvel and C. C. L. Hwa, J. Polym. Sci., 45, 25 (1960).
R. P. Quirk, U.S. Pat. 4, 374, 957 (1983).
R. P. Quirk and T. L. Huang, “New Monomers and Polymers”, B. M. Cullertson and C. V. Pittman, Jr., Eds., Plenum Press, New York, 1984.
A. L. Rummelsburg, U.S. Pat. 2, 373, 419 (1945).
M. C. Throckmorton and W. W. Saltman, U.S. Pat. 3, 856, 764 (1973).
C. J. Carlson and S. E. Holne, Jr., U.S. Pat. 3. 728, 325 (1973).
J. L. Cawse, J. L. Stanford and R. H. Hill, J. Appl. Polym. Chem., 31, 1963 (1986).
N. Hayashi and H. Komae, Chem. Ind. (London), 548 (1982).
A. J. Johanson, F. L. McKennon and L. A. Goldblatt, Ind. Eng. Chem., 40, 500 (1948).
D. L. Trumbo, Polym. Bull., 26, 271 (1991).
R. McFarlane, P. M. Reilly and K. F. O'Driscoll, J. Polym. Sci., Polym. Chem. Ed., 18, 251 (1980).
K. F. O'Driscoll and P. M. Reilly, Makromol. Chem. Macromol. Symp., 10/11, 355 (1987).
I. Crescentini, G. B. Getchele and A. Zanella, J. Appl. Polym. Sci., 9, 1323 (1965).
R. D. Gilbert and H. L. Williams, J. Am. Chem. Soc., 74, 4114 (1952).
F. M. Lewis, C. Walling, W. Cummings, E. Briggs and W. J. Wenisch, J. Am. Chem. Soc., 1527 (1948).
G. Saini, A. Leoni and S. France, Makromol. Chem., 1244, 235 (1971).
P. J. Flory, “Principles of Polymer Chemistry”, Cornell Univ. Press, Ithaca, NY, 1953.
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Trumbo, D.L. Free radical copolymerization behavior of myrcene. Polymer Bulletin 31, 629–636 (1993). https://doi.org/10.1007/BF00300120
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DOI: https://doi.org/10.1007/BF00300120