Abstract
The initiating ability of tetramethylene zwitterions formed from cyclobutane adducts of donor olefins with TCNE was investigated. Polar solvents increased the ability of vinyl ether-TCNE cyclobutane adducts to initiate the cationic polymerization of N-vinylcarbazole. The concept of charge separation in the tetramethylene zwitterions was also investigated.
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Voit, B.I., Padias, A.B. & Hall, H.K. Initiation of cationic polymerization by tetramethylene zwitterions from tetracyanocyclobutanes. Polymer Bulletin 24, 45–52 (1990). https://doi.org/10.1007/BF00298320
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DOI: https://doi.org/10.1007/BF00298320