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Intramolecular charge transfer complexes

13. Copolymers of acryloyl-β-hydroxyethyl-3,5-dinitrobenzoate with N-(2-hydroxyethyl)carbazolyl acrylate and methacrylate

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Summary

The synthesis of acryloyl-β-hydroxyethyl-3,5-dinitrobenzoate (DNBA) and of its copolymers with N-(2-hydroxyethyl)carbazolyl acrylate (HECA) and methacrylate (HECM) is presented. A copolymerization mechanism implying intermonomeric charge transfer complexes (CTC) is evidenced, although according to the Kelen-Tüdös equation the terminal model seemed to be valid. The copolymers obtained are intramolecular CTC.

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Authors and Affiliations

  1. “P.Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Romania

    Virgil Percec, Almeria Natansohn & Cristofor I. Simionescu

Authors
  1. Virgil Percec
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  2. Almeria Natansohn
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  3. Cristofor I. Simionescu
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Dedicated to Professor G. Manecke's 65th anniversary

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Percec, V., Natansohn, A. & Simionescu, C.I. Intramolecular charge transfer complexes. Polymer Bulletin 4, 247–253 (1981). https://doi.org/10.1007/BF00256313

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  • DOI: https://doi.org/10.1007/BF00256313

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