Summary
An intramolecular charge transfer complex (CTC) was obtained by radical copolymerization of N-(2-hydro-xyethyl) carbazolyl acrylate with 2′-ethylacryl-4, 5, 7-trinitro-9-fluorenone-2-carboxylate. The copolymerization mechanism is simple terminal, and the obtained CTC does not present decomplexation even at high temperatures. This is the first intramolecular CTC containig both carbazole- and trinitrofluorenone-substituted structural units.
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V.PERCEC, A.NATANSOHN and C.I.SIMIONESCU, Preprint Makro Mainz, 1, 345 (1979)
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polymer, 21, 417 (1980)
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polym. Bull., 2, 57 (1980)
A.NATANSOHN, D.GALEA, V.PERCEC and C.I.SIMIONESCU, J.Macromol.Sci.,Chem., A15, 393 (1980)
V.PERCEC, A.NATANSOHN and C.I.SIMIONESCU, J.Macromol.Sci.,Chem., A15, 405 (1980)
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polym. Bull., 2, 435 (1980)
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polym. Bull., 2, 441 (1980)
V.PERCEC, A.NATANSOHN, V.BARBOIU, B.C.SIMIONESCU and D.GALEA, Polym.Bull., 2, 505 (1980)
C.I.SIMIONESCU, V.PERCEC and A.NTANSOHN, J.Polym. Sci., Polym.Chem.Ed., submitted
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polym. Bull., 3, 529 (1980)
C.I.SIMIONESCU, V.PERCEC and A.NATANSOHN, Polym. Bull., 3, 535 (1980)
C.I.SIMIONESCU, A.NATANSOHN and V.PERCEC, Polym. Bull., 3, 543 (1980)
V.PERCEC, A.NATANSOHN and C.I.SIMIONESCU, Macro Florence Preprints, 2, 138 (1980)
S.R.TURNER, Preprints Makro Mainz, 1, 13 (1979)
S.R.TURNER and M.STOLKA, U.S.Pat. 4, 013, 623 (1977) C.A. 87:6643e
S.R.TURNER, private communication
T.SULZBERG and R.J.COTTER, J.Org.Chem., 35, 2762 (1970)
J.E.KUDER, J.M.POCHAN, S.R.TURNER and D.F.HINMAN, J.Electrochem.Soc., 125, 1750 (1978)
S.R.TURNER and C.AUCLAIR, Macromolecules, 9, 868 (1976)
C.I.SIMIONESCU, S.DUMITRESCU, M.GRIGORAS and V.PERCEC, J.Polym.Sci., Polym.Lett.Ed., 17, 287 (1979)
T.KELEN, F.TÜDÖS and B.TURCSANYI, Polym.Bull., 2, 71 (1980)
L.S.BRESLER, F.TÜDÖS, T.KELEN and B.TURCSANYI, Macro Florence Preprints, 2, 91 (1980)
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Simionescu, C.I., Percec, V. & Natansohn, A. Intramolecular charge transfer complexes. Polymer Bulletin 3, 551–557 (1980). https://doi.org/10.1007/BF00256298
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DOI: https://doi.org/10.1007/BF00256298