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Contrasting evolution of fluorine- and boron-rich tin systems

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Abstract

Individual Sn provinces or regions within provinces are sometimes enriched in fluorine or boron, giving rise to fluorine-rich and boron-rich environments. The structural styles of mineralisation within these environments are similar except that hydrothermal intrusive breccia pipes are more common in boron-rich environments and apogranite/massive greisen systems are more common in fluorine-rich environments. The increased solubility of H2O in B-bearing magmas compared to F-bearing magmas may play a role in the structural evolution of the mineralising systems. The greater mechanical energy produced during crystallisation of B-rich magmas provides a mechanism for breccia pipe and stockwork formation, while the more passive crystallisation of F-rich magmas often results in the formation of disseminated mineralisation. The partitioning of boron toward the aqueous fluid phase and the enhanced solubility of silica in the fluid phase frequently results in tourmalinisation and silicification of the wall-rocks in B-rich environments. In contrast, feldspathic and sericitic alterations usually predominate in F-rich environments.

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References

  • Alexandrov, S.M.: Geochemistry of boron-tin mineralisation in magnesian skarns of Chukotka. Geochem. Int. 11:532–539 (1974)

    Google Scholar 

  • Alexandrov, S.M.: Geochemical aspects of B-Sn formation in Alaska deposits. Geochem. Int. 12:139–150 (1975)

    Google Scholar 

  • Allmann-Ward, P., Halls, C., Rankin, A., Bristow, C.M.: An intrusive hydrothermal breccia body at Wheal Remfry in the western part of the St. Austell Granite pluton, Cornwall, England. In A.M. Evans (ed.) Metallization Associated with Acid Magmatism (Wiley Interscience, New York), 1–28 (1982)

    Google Scholar 

  • Antipin, V.S., Kovalenko, V.I., Kuznetsova, A.I., Periskova, L.A.: Distribution coefficients for tin and tungsten in ore-bearing acid igneous rocks. Geochem. Int. 19:92–105 (1982)

    Google Scholar 

  • Barsukov, V.L.: The geochemistry of tin. Geochemistry 1:41–52 (1957)

    Google Scholar 

  • Barsukov, V.L., Kuril'chikova, G.Ye: On the forms in which tin is transported in hyrothermal solutions. Geochem. Int. 3:759–764 (1966)

    Google Scholar 

  • Barsukov, V.L., Ryabchikov, I.D.: Physico-chemical factors of migration and concentration of metals. In M. Stěmprok, L. Burnol and G. Tischendorf (eds.) Metallization associated with acid magmatism (Geol. Surv., Prague) vol. 2:99–104 (1977)

  • Barsukov, V.L., Sushchevskaya, T.M.: Evolution of composition of hydrothermal solutions in the formation of tin-ore deposits. Geochem. Int. 10:363–375 (1973)

    Google Scholar 

  • Baumann, L., Stěmprok, M., Tischendorf, G., Zoubek, V.: Metallogeny of tin and tungsten in the Krŭsne Hóry — Erzgebirge. Pre Symp. Excursion Guide IGCP-MAWAM Symp. Karlovy Vary (Geol. Surv. Prague), 66 p (1974)

  • Benard, F., Moutou, P., Pichavant, M.: Phase relations of tourmaline leucogranites and the significance of tourmaline in silicic magmas. J. Geol. 93:271–291 (1985)

    Google Scholar 

  • Beus, A.A.: Metallogeny of Precambrian rare-metal granitoids. Revista Brasilaria de Geociencias 12:410–413 (1982)

    Google Scholar 

  • Burnham, C.W.: Magmas and hydrothermal fluids. In H.L. Barnes (ed.) Geochemistry of hydrothermal ore deposits (Wiley, New York), 2nd. ed., 71–136 (1979)

    Google Scholar 

  • Burt, D.M.: Acidity-salinity diagrams — application to greisen and porphyry deposits. Econ. Geol. 76:832–843 (1981)

    Google Scholar 

  • Burt, D.M., Sheridan, M.F., Bikun, J.V., Christiansen, E.H.: Topaz rhyolites — distribution, origin and significance for exploration. Econ. Geol. 77:1818–1836 (1982)

    Google Scholar 

  • Charoy, B.: Definition et importance des phénomenes deutériques et les fluids associés dans les granites. Consequences metallogéniques. Sci. Terre Mem. 37, 364 p (1979)

    Google Scholar 

  • Charoy, B.: Tourmalinisation in Cornwall, England. In A.M. Evans (ed.) Metallization associated with acid magmatism (Wiley Interscience, New York), 63–70 (1982)

    Google Scholar 

  • Christiansen, E.H., Burt, D.M., Sheridan, M.F., Wilson, R.T.: The petrogenesis of topaz rhyolites from the western United States. Contrib. Mineral. Petrol. 83:16–30 (1983)

    Google Scholar 

  • Cuney, M., Autran, A., Burnol, L.: Premiers resultats par le sondage GPF de 900 m réalisé sur le granite sodolithique et fluoré à minéralisation disseminée de Beauvoir. Chron. rech. min. 481:59–63 (1985)

    Google Scholar 

  • Dingwell, D.B., Scarfe, C.M.: Major element partitioning in the system haplogranite-HF-H2O: implications for leucogranites and high-silica rhyolites. EOS 64:312 (1983)

    Google Scholar 

  • Dingwell, D.B., Scarfe, C.M., Cronin, D.J.: The effect of fluorine on viscosities in the system Na2O-Al2O3-SiO2: implications for phonolites, trachytes and rhyolites. Am. Mineral. 70:80–87 (1985)

    Google Scholar 

  • Eadington, P.J.: Calculated solubilities of cassiterite in high temperature hydrothermal brines and some applications to mineralisation in granitic rocks and skarns. In S. Somiya (ed.) Proc. 1st Int. Symp. on Hydrothermal Reactions, Tokyo, 335–346 (1982)

  • Eadington, P.J.: Fluid inclusion investigation of ore formation in a tin-mineralised granite, New England, New South Wales. Econ. Geol. 78:1204–1221 (1983)

    Google Scholar 

  • Eadington, P.J., Sun, S.S.: Variations in temperature, chemical composition and oxygen isotope ratios of hydrothermal solutions in the Mole Granite. In P.G. Flood and B. Runnegar (eds.) Proc. Symp. Geol. New England (Dept. Geol. Univ. New England, Armidale), 321–326 (1982)

    Google Scholar 

  • Einaudi, M.T., Meinert, L.D., Newberry, R.J.: Skarn deposits. Econ Geol. 75th Anniv. Vol., 317–391 (1981)

  • Eugster, H.P., Wilson, G.A.: Transport and deposition of ore-forming elements in hydrothermal systems associated with granites. In High heat production (HHP) granites, hydrothermal circulation and ore genesis (Int. Min. Metall., London), 87–98 (1985)

    Google Scholar 

  • Goode, A.J.J., Taylor, R.T.: Intrusive and pneumatolytic breccias in south-west England. I.G.S. Rep. 80/2, 23 p (1980)

  • Grant, J.N., Halls, C., Avila, W. Avila, G.: Igneous geology and the evolution of hydrothermal systems in some subvolcanic tin deposits of Bolivia. In Volcanic processes in ore genesis (Inst. Min. Metall. and Geol. Soc. Lond., London), 117–16 (1977)

    Google Scholar 

  • Grant, J.N., Halls, C., Sheppard, S.M.F., Avila, W.: Evolution of the porphyry tin deposits of Bolivia. Mining Geol. Spec. Issue 8:151–173 (1980)

    Google Scholar 

  • Groves, D.I., Taylor, R.G.: Greisenisation and mineralisation at Anchor tin mine, northeast Tasmania. Trans. Inst. Min. Metall. Sect. B (Appl. Earth Sci.), 82:B135–146 (1973)

    Google Scholar 

  • Hards, N.J.: Distribution of elements between the fluid phase and the silicate melt phase of granites and nepheline syenites. N.E.R.C. Rpt. Prog. Exp. Petrol. 3:88–90 (1976)

    Google Scholar 

  • Hosking, K.F.G.: Primary mineral deposits. In D.J. Gobbett and C.S. Hutchison (eds.), Geology of the Malay Peninsula (West Malaysia and Singapore) (Wiley, New York), 335–390 (1973)

    Google Scholar 

  • Hudson, T., Arth, J.G.: Tin granites of the Seward Peninsula, Alaska. Geol. Soc. Am. Bull. 94:768–790 (1983)

    Google Scholar 

  • Jackson, K.J., Helgeson, H.C.: Chemical and thermodynamic constraints on the hydrothermal transport and deposition of tin: 1. Calculation of the solubility of cassiterite at high pressures and temperatures. Geochim. Cosmochim. Acta 49:1–22 (1985)

    Google Scholar 

  • Jackson, N.J.: Geology of the Cornubian tinfield — a review. Bull. Geol. Soc. Malaysia 11:209–237 (1979)

    Google Scholar 

  • Katz, M.B., Tuckwell, D.D.: Controls of tin-bearing pegmatites in the Precambrian of Broken Hill, Australia. Bull. Geol. Soc. Malaysia 11:253–266 (1979)

    Google Scholar 

  • Kilinc, I.A., Burnham, C.W.: Partitioning of chloride between a silicate melt and coexisting aqueous phase from 2 to 8 kilobars. Econ. Geol. 67:231–235 (1972)

    Google Scholar 

  • Kovalenko, V.I., Kuz'min, M.I., Antipin, V.S., Petrov, L.L.: Topazbearing quartz keratophyre (ongonite), a new variety of subvolcanic igneous vein rock. Doklad. Acad. Nauk. SSSR 199:132–135 (1971)

    Google Scholar 

  • Kovalenko, V.I., Kovalenko, N.I.: Ongonites (topaz-bearing quartz keratophyre)- subvolcanic analogue of rare-metal Li-F granites. Trans. Joint Soviet-Mongolian Sci. Res. Geol. Exped. 15, 128 p. (1976) (in Russian).

  • Kwak, T.A.P., Askins, P.W.: Geology and genesis of the laminar Fe-Sn-W (-Be-Zn) skarn at Moina, Tasmania, Australia. Econ. Geol. 76:439–467 (1981a)

    Google Scholar 

  • Kwak, T.A.P., Askins, P.W.: The nomenclature of carbonate replacement deposits with emphasis on Sn-F (-Be-Zn) ‘wrigglite’ skarns. J. geol. Soc. Aust. 28:123–136 (1981b)

    Google Scholar 

  • Legache, M., Weisbrod, A.: The system: two alkali feldspars-KCl-NaCl-H2O at moderate to high temperatures and low pressures. Contrib. Mineral. Petrol. 62:77–101 (1977)

    Google Scholar 

  • Manning, D.A.C.: The effect of fluorine on liquidus phase relationships in the system Qz-Ab-Or with excess water at 1 kb. Contrib. Mineral. Petrol. 76: 206–215 (1981)

    Google Scholar 

  • Manning, D.A.C., Exley, C.S.: The origin of late-stage rocks in the St. Austell granite — a reinterpretation. J. geol. Soc. Lond. 141:581–591 (1984)

    Google Scholar 

  • Manning, D.A.C., Pichavant, M.: Volatiles and their bearing on the behaviour of metals in granitic systems. C.I.M. Spec. Vol. 39. (1987)

  • Martin, J.S.: An experimental study on the effect of Li on the granite system. Proc. Ussher Soc. 5:417–420 (1983)

    Google Scholar 

  • Montoya, J.W., Hemley, J.J.: Activity relations and stabilities in alkali felspar and mica alteration reactions. Econ. Geol. 70:577–583 (1975)

    Google Scholar 

  • Nutalaya, P., Campbell, K.V., Macdonald, A.S., Aranyakanon, P., Suthakorn, P.: Review of the geology of Thai tinfields. Bull. Geol. Soc. Malaysia 11:137–160 (1979)

    Google Scholar 

  • Orville, P.M.: Alkali ion exchange between vapour and feldspar phases. Am. J. Sci. 261:201–237 (1963)

    Google Scholar 

  • Phillips, W.J.: Mechanical effects of retrograde boiling and its probable importance in the formation of some porphyry ore deposits. Trans. Inst. Min. Metall. Sect. B (Appl. Earth Sci.) 83:B90–98 (1973)

    Google Scholar 

  • Pichavant, M.: An experimental study of the effect of boron on a water saturated haplogranite at 1 Kbar vapour pressure. Contrib. Mineral. Petrol. 76:430–439 (1981)

    Google Scholar 

  • Pichavant, M.: (Na, K) exchange between alkali feldspars and aqueous solutions containing borate and fluoride anions, experimental results at P=1 Kbar. 3rd NATO advanced study institute on feldspars, Rennes, 102 (1983)

  • Pichavant, M.: The effect of boron on liquidus phase relationships in the system Qz-Or-Ab-H2O at 1 Kbar. Trans. Am. Geophys. Union 65:298 (1984)

    Google Scholar 

  • Pichavant, M., Manning, D.: Petrogenesis of tourmaline granites and topaz granites: the contribution of experimental data. Phys. Earth Plan. Int. 35:31–50 (1984)

    Google Scholar 

  • Pichavant, M., Ramboz, C.: Premiere détermination experimentale des relations de phases dans le systéme haplogranitique en conditions de sous saturation en eau. C.R. Acad. Sci. Paris 301, Série II, 9:607–610 (1985)

    Google Scholar 

  • Pichavant, M., Herrera, J.V., Boulmier, S., Briqueu, L., Joron, J., Juteau, M., Marin, L., Michard, A., Sheppard, S.M.F., Treuil, M., Vernet, M.: The Macusani glasses, SE Peru: evidence of chemical fractionation in peraluminous magmas. In B.O. Mysen (ed.) Magmatic Processes: Physicochemical Principles, Geochem. Soc. Spec. Pub. 1. (1987)

  • Pyatenko, I.K., Sitnin, A.A., Lavrinenko, A.F.: Geochemical features of metasomatically altered granitic rocks in Azov region. Int. Geol. Rev. 9:1430–1443 (1967)

    Google Scholar 

  • Ramboz, C., Pichavant, M., Weisbrod, A.: Fluid immiscibility in natural processes; use and misuse of fluid inclusion data. II Interpretation of fluid inclusion data in terms of immiscibility. Chem. Geol. 37:29–48 (1982)

    Google Scholar 

  • Rivas, S.: Geology of the principal tin deposits of Bolivia. Bull. Geol. Soc. Malaysia 11:161–180 (1979)

    Google Scholar 

  • Scott, K.M.: Wall-rock alteration in disseminated tin deposits, southeastern Australia. Proc. Aust. I.M.M. 280:17–28 (1981)

    Google Scholar 

  • St#x011B;mprok, M., Skv321–1r, P.: Composition of tin-bearing granites from the Krŭsne Hóry metallogenic province of Czechoslovakia. Sbornik Geol. Rad. 6:7–83 (1974)

    Google Scholar 

  • Sirinawin, T., Tate, N.M., Pollard, P.J., Taylor, R.G.: Resource evaluation of primary tin potential of the Phuket-Ranong region, southwestern Thailand — a distict analysis. Unpubl. ESCAP rept., 82 p. (1986)

  • Stewart, D.B.: Petrogenesis of lithium-rich pegmatites. Am. Mineral. 63:970–980 (1978)

    Google Scholar 

  • Strauss, C.A.: The geology and mineral deposits of the Potgeitersrus tinfields. Mem. Geol. Surv. South Africa 46, 241 p. (1954)

  • Taylor, R.G. Geology of Tin Deposits (Elsevier, Amsterdam), 543 p. (1979a)

    Google Scholar 

  • Taylor, R.G.: Some observations upon the primary tin deposits of Australia. Bull. Geol. Soc. Malaysia 11:181–207 (1979b)

    Google Scholar 

  • Tischendorf, G.: The metallogenetic basis of tin exploration in the Erzgebirge. Trans. Inst. Min. Metall. Sect. B (Appl. Earth Sci.) 82:B9–24 (1973)

  • Tischendorf, G.: Geochemical and petrographic characteristics of silicic magmatic rocks associated with rare-element mineralisation. In M. Stěmprok, L. Burnol and G. Tischendorf (eds.) Metallization associated with acid magmatism (Geol. Surv. Prague) vol. 2, 41–96 (1977)

  • Waters, D.J., Moore, J.M.: Kornerupine in Mg-Al-rich gneisses from Namaqualand, South Africa: mineralogy and evidence for late-metamorphic fluid activity. Contrib. Mineral. Petrol. 91:369–382 (1985)

    Google Scholar 

  • Wells, K.: Geology and mineralisation in the south Heemskirk tinfield, west Tasmania. MSc dissert. James Cook University of North Queensland (unpubl.) 72 p. (1978)

    Google Scholar 

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Authors and Affiliations

  1. Department of Geology, James Cook University of North Queensland, 4811, Townsville, Australia

    P. J. Pollard

  2. Centre de Recherches Petrographiques et Geochimiques, BP 20, 54501, Vandoeuvre Les Nancy, France

    M. Pichavant & B. Charoy

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  1. P. J. Pollard
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  2. M. Pichavant
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Pollard, P.J., Pichavant, M. & Charoy, B. Contrasting evolution of fluorine- and boron-rich tin systems. Mineral. Deposita 22, 315–321 (1987). https://doi.org/10.1007/BF00204525

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