Skip to main content
Log in

A new modified pulping process alternative to sulphate method “Alkali-Sulfite-Antraquinone-Ethanol (ASAE)”

  • Originals
  • Published:
Wood Science and Technology Aims and scope Submit manuscript

Summary

In this study, ASAM method was modified by the use of ethanol instead of methanol. This new organosolv pulping method is referred to as ASAE. Brutia pine (Pinus brutia Ten.) was chosen as raw material in cooking because of its wide-spread usage in Turkish sulphate mills. 28 cooks were made by changing the cooking conditions systematically to achieve the most effective cooking parameters for yield and physical properties of ASAE pulps. Also, a control sulphate cook was made. After statistical evaluations of the data optimum pulping conditions were determined to be 20% Na2SO3 with 50% ethanol ratios and 150 min cooking time at maximal temperature. It was found that ASAE pulps had higher yield, viscosity, brigthness and strength properties than sulphate control pulps with the exception of breaking length. Furthermore bad-odour problems were absent during the blowing and washing process in the laboratory trials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Aziz, S.; Sarkanen, K. V. 1989: Organosolv pulping —a review. Tappi 57: 83–85

    Google Scholar 

  • Black, N. P. 1991: ASAM alkaline sulfite pulping process shows potential for large-scale application. Tappi 74: 87–93

    Google Scholar 

  • Browing, B. L. 1967: Methods of wood chemistry, Vol. I–II, Interscience Publishers, New York, London

    Google Scholar 

  • Casey, J. P. 1966: Pulp and Paper, Vol. 1. Interscience Publishers inc., New York

    Google Scholar 

  • Ingruber, O. V.; Stradal, nM.; Histed, J. A. 1982: Alkaline sulfite antraquinone pulping of Eastern Canadian Woods. Pulp and Paper Canada, 83: 342–349.

    Google Scholar 

  • Kordsachia, O.; Patt, R. 1987: Untersuchungen zum Aufschluß von Buche nach dem ASAM-Verfahren und zur Bleiche der Zellstoffe in unterschiedlichen Sequenzen. Das Papier 41: 340–351

    Google Scholar 

  • McGee, J. K.; April, G. C. 1982: Chemicals from renewable resources: hemicellulose behaviour during organosolv delignification of southern yellow pine, Chemical Engineering Communication 19: 49–56

    Google Scholar 

  • Ojanen, E.; Tulppalla, J.; Virkola, N. E. 1982: Neutral sulfite antraquinone (NS-AQ) cooking of pine and birch wood chips, Paperi ja Puu, 18: 453–464

    Google Scholar 

  • Patt, R.; Kordsachia, O. 1986: Herstellung von Zellstoffen unter Verwendung von alkalischen Sulfitlösungen mit Zusatz von Antrachinon und Methanol. Das Papier 40 (10A): 1–8

    Google Scholar 

  • SCAN Test Methods: Scandinavian Pulp, Paper and Board Commitee, Stockholm, Sweden

  • Sundquist, J.; Laamanen, L.; Poppius, K. 1988: Problems of nonconventional pulping processes in the peroxyformic acid cooking experiments. Paperi ja Puu 70: 143–148

    Google Scholar 

  • TAPPI Standards, 1979: Official test methods and provisional test methods, Technical Association Pulp and Paper Industry, Atlanta

    Google Scholar 

  • Weber, E. 1967: Grundriß der biologischen Statistik, 6. Auflage, Gustav Fischer Verlag, Stuttgart

    Google Scholar 

  • Winkler, A.; Patt, R. 1988: Herstellung von Zellstoffen aus vier verschiedenen Holzarten nach dem ASAM-Verfahren. Holz RohWerkstoff 46: 341–345

    Google Scholar 

  • Wise, L. E.; John, E. C. 1952: Wood Chemistry, 2. Ed. Vol. I–II, Reinhold Publication co., New York

    Google Scholar 

  • Yalinkilic, M. K. 1990: Utilization Possibilities of Biodegradation Made by Pleurotus ostreatus Jacq (ex. Fr.) in Biopulping Trials, Thesis of Ph.D., K.T.U. Fen Bil. Ens. 217p.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kirçi, H., Bostançi, S. & Yalinkiliç, M.K. A new modified pulping process alternative to sulphate method “Alkali-Sulfite-Antraquinone-Ethanol (ASAE)”. Wood Sci.Technol. 28, 89–99 (1994). https://doi.org/10.1007/BF00192688

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00192688

Keywords

Navigation