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Synthetic and physicochemical studies of divalent metal complexes with cyclic hydrazone and semicarbazone ligands

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The syntheses of 3,4,10,11-tetraphenyl-1,2,5,6,8,9,12,13-octaazacyclotetradeca-7, 14-dione-2,4,9,11-tetraene (dbdch) and 6-methoxy-1,6-diphenyl-4-oxo-3,4,5,6-tetrahydro-2,3,5-triazine (bsc) and their complexes with divalent metal ions (copper, nickel, cobalt, zinc, cadmium and mercury) are reported. All compounds were characterized by 1H n.m.r., 13C n.m.r., i.r. and u.v.-vis. spectroscopy and by FAB mass spectrometry; possible structures are presented and discussed.

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Authors and Affiliations

  1. Departamento de Química, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain

    Pilar Souza, M. Antonia Mendiola, Ana I. Matesanz & Vicente Fernández

  2. Departamento A.T.S.I., Facultad de Informática, Campus de Montegancedo s/n, 28660-Boadilla del Monte, Madrid, Spain

    Agueda Arquero

Authors
  1. Pilar Souza
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  2. M. Antonia Mendiola
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  3. Ana I. Matesanz
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  4. Vicente Fernández
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  5. Agueda Arquero
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Souza, P., Mendiola, M.A., Matesanz, A.I. et al. Synthetic and physicochemical studies of divalent metal complexes with cyclic hydrazone and semicarbazone ligands. Transition Met Chem 20, 157–161 (1995). https://doi.org/10.1007/BF00167020

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  • DOI: https://doi.org/10.1007/BF00167020

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