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Luminescent Cyclometalated Diimine Platinum(II) Complexes: Photophysical Studies and Applications

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Transition Metal and Rare Earth Compounds

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 241))

Abstract

The photoluminescent properties of mono- and polynuclear cyclometalated platinum(II) complexes are discussed. Spectroscopic studies have revealed weak intra- or intermolecular metal-metal and ligand-ligand interactions that are affected by the molecular structure and microenvironment. The structure-emission relationships observed in these platinum(II) complexes are described and comparisons with palladium(II) analogues regarding the structural and photoluminescent properties are highlighted. With judicious modification of cyclometalated and/or ancillary ligands, robust platinum luminophores with tunable emission energies and lifetimes have been synthesized. These complexes can be employed as luminescent sensors and electrophosphorescent materials in organic light-emitting devices (OLED).

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Acknowledgements

We are grateful for financial support from the University Development Fund of The University of Hong Kong, the Hong Kong University Foundation, and the Research Grants Council of the Hong Kong SAR, China [HKU 7039/03P].

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Authors and Affiliations

  1. Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong

    Siu-Wai Lai & Chi-Ming Che

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  1. Siu-Wai Lai
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  2. Chi-Ming Che
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Correspondence to Chi-Ming Che .

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Lai, SW., Che, CM. Luminescent Cyclometalated Diimine Platinum(II) Complexes: Photophysical Studies and Applications. In: Transition Metal and Rare Earth Compounds. Topics in Current Chemistry, vol 241. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b96859

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  • DOI: https://doi.org/10.1007/b96859

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-20948-5

  • Online ISBN: 978-3-540-39904-9

  • eBook Packages: Springer Book Archive

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