Abstract
The local and long-range ordering of a-phenylcinnamic acid stereoisomers (with the emphasis on the Z isomer) has been studied by mid and far FT-IR spectroscopy in solution and in the solid phase. The main structural feature in solution and in the solid state was the presence of strong C=O-H-O hydrogen bonding interactions between the carboxylic groups (local order). The degree of ordering was higher in the solid state, owing to relatively strong C (aromatic) -H … O hydrogen bonds (long-range order). A similar type of bonding was not detectable in solution.
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© 1997 Springer-Verlag Wien
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Pálinkó, I., Kiss, J.T. (1997). Local and Long-range Ordering of α-Phenylcinnamic Acid Stereoisomers — a Mid and Far FT-IR Spectroscopic Investigation. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_49
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DOI: https://doi.org/10.1007/978-3-7091-6840-0_49
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