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A New Layered Compound Containing [PMo12O40]3- and Both 5- and 6-Coordinated Homoleptic (1-(2-Chloroethyl)tetrazole)Copper(II) Cations

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Molecular Magnets Recent Highlights

Summary

The synthesis, crystal structure and physical properties of the complex obtained from the reaction between the polyoxometalate anion [PMo12O40]3- copper(II) and the ligand 1-(2-chloroethyl)tetrazole (teec) are described. This compound has been synthesized as a model for designing materials containing both magnetic polyoxometalate anions and iron(II) spin-crossover cations. Keywords. Coordination chemistry; Heterocycles; Polyoxometalates; Structure elucidation; Tetrazole.

The compound, with formula [Cu(teec 5]2[Cu(teec 6][PMo12O40]2 · 2H2O, consists of alternating layers of polyoxometalates and cationic complexes. Both, five and six coordinated Cu(II) ions are present,each positioned in different layers. Despite these layers having a similar width, the layer of pentacoordinated Cu(II) ions contains twice as many cationic complexes as the layer of hexacoordinated Cu(II) ions. This unusual coexistence of complexes with different coordination number is most likely caused by the steric hindrance induced by the bulky polyoxometalates in the layer of pentacoordinated Cu(II) which prevents the presence of a sixth teec ligand.

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References

  1. Palleux R, Schmalle HW, Huber R, Fischer P, Hauss T, Ouladdiaf B, Decurtins S (1997) Inorg Chem 36: 2301

    Article  Google Scholar 

  2. Coronado E, Galan-Mascaros JR, Gomez-Garcia CJ, Laukhin V (2000) Nature 408: 447

    Article  CAS  Google Scholar 

  3. Decurtins S, Schmalle HW, Schneuwly P, Pellaux R, Ensling J (1995) Mol Cryst Liq Cryst 273: 167

    Article  Google Scholar 

  4. Hauser A, von Arx ME, Pellaux R, Decurtins S (1996) Mol Cryst Liq Cryst 286: 225

    Article  Google Scholar 

  5. von Arx ME, Hauser A, Riesen H, Pellaux R, Decurtins S (1996) Phys Rev B: 15800

    Google Scholar 

  6. Pope MT (1983) Heteropoly and Isopoly Oxometalates; Springer: Berlin

    Google Scholar 

  7. Gouzern P, Proust A (1998) Chem Rev 98: 77

    Article  Google Scholar 

  8. Rhule JT, Hill CL, Judd DA, Schinazi RF (1998) Chem Rev 98: 327

    Article  CAS  Google Scholar 

  9. Müller A, Peters F, Pope MT, Gatteschi D (1998) Chem Rev 98: 239

    Article  Google Scholar 

  10. Coronado E, Gümez-Garcia CJ (1998) Chem Rev 98: 273

    Article  CAS  Google Scholar 

  11. Stassen AF, Driessen WL, Haasnoot JG, Reedijk J, Inorg Chim Acta (in press)

    Google Scholar 

  12. Stassen AF, Kooijman H, Spek AL, de Jongh LJ, Haasnoot JG, Reedijk J, Inorg Chem (in press)

    Google Scholar 

  13. Stassen AF, Roubeau O, Ferrero Gramage I, Linarès J, Varret F, Mutikainen I, Turpeinen U, Haasnoot JG, Reedijk J (2001) XXX Polyhedron 20: 1699

    Article  CAS  Google Scholar 

  14. Stassen AF, Dova E, Ensling J, Schenk H, Gütlich P, Haasnoot JG, Reedijk J (2002) Inorg Chim Acta 335: 61

    Article  CAS  Google Scholar 

  15. Dova E, Stassen AF, Driessen AJR, Sonneveld E, Goubitz K, Peschar R, Haasnoot JG, Reedijk J, Schenk H (2001) Acta Cryst B 57: 531

    Article  CAS  Google Scholar 

  16. Franke PL, Haasnoot JG, Zuur AP (1982) Inorg Chim Acta 59: 5

    Article  CAS  Google Scholar 

  17. Addison AW, Rao TN, Reedijk J, vanRijn J, Verschoor GC (1984) J Chem Soc Dalton Trans 1349

    Google Scholar 

  18. Stassen AF, Kooijman H, Spek AL, Haasnoot JG, Reedijk J (2001) J Chem Cryst 185

    Google Scholar 

  19. Wijnands PEM, Wood JS, Reedijk J, Maaskant WJA (1996) Inorg Chem 35: 1214

    Article  CAS  Google Scholar 

  20. Virovets AV, Podbererskaya NV, Lavrenova LG (1994) XXX Polyhedron 13: 2929

    Article  CAS  Google Scholar 

  21. Virovets AV, Podbererskaya NV, Lavrenova LG, Bikzhanova GA (1995) Acta Cryst C 6: 1084

    Article  Google Scholar 

  22. Virovets AV, Baidina IA, Alekseev VI, Podbererskaya NV, Lavrenova LG (1996) J Struc Chem 37: 288

    Article  Google Scholar 

  23. Virovets AV, Bikzhanova GA, Podberershaya NV, Lavreneva LG (1997) Zh Strukt Khim 38: 128

    Google Scholar 

  24. Kolthoff IM, Elving PJ (1963) Treatise on Analytical Chemistry New York, Vol. 4

    Google Scholar 

  25. Farrugia LJ (1999) J Appl Crystallorg 32: 837

    Article  CAS  Google Scholar 

  26. Altomare A, Burla MC, Camalli M, Cascarano G, Giacovazzo C, Guagliardi A, Moliterni AGG, Polidori G, Spagna R (1999) J Appl Crystallogr 115

    Google Scholar 

  27. Sheldrick GM SHELXL-97 (1997) Program for crystal structure refinement. Univ of Göttingen, Germany

    Google Scholar 

  28. Carson C (ed), POVRAY (1996–1999) Rendering engine for Windows

    Google Scholar 

  29. Spek AL (2000) PLATON, A multi-purpose crystallographic tool. Utrecht Univ, The Netherlands. Internet: http://www.cryst.chem.uu.nl/platon/

    Google Scholar 

  30. Spiering H, Meissner E, Köppen H, Müller EW, Gütlich P (1982) Chem Phys 68: 65

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA, Leiden, The Netherlands

    Arno F. Stassen, Jaap G. Haasnoot & Jan Reedijk

  2. Instituto de Ciencia Molecular, Universidad de Valencia, 46100, Burjassot, Spain

    Eugenia Martínez Ferrero, Carlos Giménez-Saiz & Eugenio Coronado

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  1. Arno F. Stassen
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  2. Eugenia Martínez Ferrero
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  3. Carlos Giménez-Saiz
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  4. Eugenio Coronado
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  5. Jaap G. Haasnoot
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  6. Jan Reedijk
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Editors and Affiliations

  1. Institute of Applied Synthetic Chemistry, Vienna University of Technology, Vienna, Austria

    Wolfgang Linert

  2. “Chimie Inorganique et Matériaux Moléculaires” Laboratory, Pierre et Marie Curie University, Paris, France

    Michel Verdaguer (Chairman of the “Molecular Magnets” Programme of the European Science Foundation) (Chairman of the “Molecular Magnets” Programme of the European Science Foundation)

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© 2002 Springer-Verlag Wien

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Stassen, A.F., Ferrero, E.M., Giménez-Saiz, C., Coronado, E., Haasnoot, J.G., Reedijk, J. (2002). A New Layered Compound Containing [PMo12O40]3- and Both 5- and 6-Coordinated Homoleptic (1-(2-Chloroethyl)tetrazole)Copper(II) Cations. In: Linert, W., Verdaguer, M. (eds) Molecular Magnets Recent Highlights. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6018-3_9

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  • DOI: https://doi.org/10.1007/978-3-7091-6018-3_9

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-7091-7300-8

  • Online ISBN: 978-3-7091-6018-3

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