Skip to main content

Calculation of Equilibrium Oxygen Concentration

  • Conference paper

Abstract

In the chemical literature solubility of a gas is generally given as the Bunsen absorption coefficient, α, which is a function of temperature and of the electrolyte content of the solvent. Hydrostatic pressure has little effect on solubility, but with increasing head the escaping tendency of the gas increases. Therefore, at constant concentration, a POS gives a higher reading at greater depth. This effect is negligible (< 1%) at depths less than 100m.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Andrews FC (1972) Gravitational effects on concentrations and partial pressures in solutions: A thermodynamic analysis. Science 178:1199–1201

    Article  PubMed  CAS  Google Scholar 

  2. Benson BB, Krause D, Peterson MA (1979) The solubility and isotopic fractionation of gases in dilute aqueous solution: I Oxygen. J Solution Chem 8:655–690

    Article  CAS  Google Scholar 

  3. Benson BB, Krause D (1980) The concentration and isotopic fractionation of gases dissolved in fresh water in equilibrium with the atmosphere: I Oxygen. Limnol Oceanogr 25 (4):662–671

    Article  CAS  Google Scholar 

  4. Carritt DE, Carpenter JH (1966) Comparison and evaluation of currently employed modifications of the Winkler for determining dissolved oxygen in seawater; a NASCO Report. J Mar Res 24:286–318

    CAS  Google Scholar 

  5. Eckert CA (1973) The thermodynamics of gases dissolved at great depth. Science 180:426–427

    Article  PubMed  CAS  Google Scholar 

  6. Enns T, Scholander PF, Bradstreet ED (1965) Effect of hydrostatic pressure on gases dissolved in water. J Phys Chem 69:389–393

    Article  PubMed  CAS  Google Scholar 

  7. Fenn WO (1972) Partial pressure of gases dissolved at great depth. Science 176:1011–1012

    Article  PubMed  CAS  Google Scholar 

  8. Fox CJJ (1909) On the coefficients of absorption of nitrogen and oxygen in distilled water and sea water and of atmospheric carbon dioxide in sea water. Trans Faraday Soc 5:68

    Article  Google Scholar 

  9. Green EJ, Carritt DE (1967) Oxygen solubility in sea water: thermodynamic influence of sea salt. Science 157:191

    Article  CAS  Google Scholar 

  10. Gilbert W, Pawley W, Park K (1968) Carpenter’s oxygen solubility tables and nomograph for seawater as function of temperature and salinity. Off Nav Res Data Rep no 29

    Google Scholar 

  11. Hitchman ML (1978) Measurement of dissolved oxygen. John Wiley &Sons and Orbisphere Corp, New York

    Google Scholar 

  12. Hutchinson GE (1957) A treatise on limnology. I. Geography, physics and chemistry. John Wiley, New York

    Google Scholar 

  13. Knudsen M, Forch C, Sörensen SPL (1902) Bericht über die chemische und physikalische Untersuchung des Meereswassers und die Aufstellung der neuen hydrographischen Tafeln. Wiss Meeresunters Abt Kiel 6:123–184

    Google Scholar 

  14. Mortimer CH (1982) The oxygen content of air-saturated fresh waters within ranges of temperature and atmospheric pressure of limnological interest. Mitt Int Ver Limnol 22: 1–23

    Google Scholar 

  15. Ricker WE (1934) A critical discussion of various measures of oxygen saturation in lakes. Ecology 15:348–363

    Article  CAS  Google Scholar 

  16. Schassmann H (1949) Die Sauerstoffsättigung natürlicher Wässer, ihre Ermittlung undihre Bedeutung in der Hydrologie. Schweiz Z Hydrol 11:430–463

    Article  Google Scholar 

  17. Setschenow J (1889) Concerning the concentration of salt solutions on the basis of their behaviour to carbonic acid. Z Phys Chem 4: 117

    Google Scholar 

  18. Truesdale GA, Downing AL, Lowden GF (1955) The solubility of oxygen in pure water and sea water. J Appl Chem 5: 53–63

    Article  CAS  Google Scholar 

  19. Weiss RF (1970) The solubility of nitrogen, oxygen, and argon in water and sea water. Deep-Sea Res 17:721–735

    CAS  Google Scholar 

  20. Weitkamp DE, Katz M (1980) A review of dissolved gas supersaturation literature. Trans Am Fish Soc 109:659–702

    Article  Google Scholar 

  21. Winkler LW (1888) Die Bestimmung des in Wasser gelösten Sauerstoffs. Ber Dtsch Chem Ges 21:2843–2854

    Article  Google Scholar 

  22. Winkler LW (1889) Die Löslichkeit des Sauerstoffs in Wasser. Ber Dtsch Chem Ges 22:1764–1774

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Forstner, H., Gnaiger, E. (1983). Calculation of Equilibrium Oxygen Concentration. In: Gnaiger, E., Forstner, H. (eds) Polarographic Oxygen Sensors. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81863-9_28

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-81863-9_28

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81865-3

  • Online ISBN: 978-3-642-81863-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics