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Disorder and Strain-Induced Complexity in Functional Materials pp 67–77Cite as

Magnetic Interactions Governing the Inverse Magnetocaloric Effect in Martensitic Ni–Mn-Based Shape-memory Alloys

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Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 148))

Abstract

Ni–Mn–X Heusler-type alloys (X: group IIIB–VB elements) undergo martensitic transformations, and many of them exhibit magnetic shape-memory and field-induced effects, one of the most predominant being the inverse magnetocaloric effect. To understand the cause of the inverse magnetocaloric effect, which involves a magnetic entropy increase with applied field, it is necessary to understand the nature of the magnetic coupling in the temperature vicinity of the martensitic transition.We present results on neutron polarization analysis experiments on Ni–Mn-based martensitic Heusler systems, with which we show that around M <M sare antiferromagnetic. We discuss the relationship of the magnetic coupling and the inverse magnetocaloric effect.

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Acknowledgment

We would like to thank J. Minar and H.C. Herper for helpful discussions. This work was supported by the Deutsche Forschungsgemeinschaft (SPP 1239) and ILL-Grenoble.

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Authors and Affiliations

  1. Faculty of Engineering & Natural Sciences, Sabanci University, 34956, Istanbul, Turkey

    S. Aksoy

  2. Physics Department, University of Duisburg-Essen, 47048, Duisburg, Germany

    M. Acet & E. F. Wassermann

  3. Thyssen Krupp Electrical Steel GmbH, 45881, Gelsenkirchen, Germany

    T. Krenke

  4. Faculty of Physics & CeNIDE, University Duisburg-Essen, 47048, Duisburg, Germany

    M. Gruner & P. Entel

  5. Departament d’Estructura i Constituents de la Matèria, Facultat de Física, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Catalonia, Spain

    L. Mañosa

  6. Facultat de Física, Departament d’Estructura i Constituents de la Matèria, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Catalonia, Spain

    A. Planes

  7. Institut de Nanociència i Nanotecnologia, Universitat de Barcelona, Barcelona, Catalonia, Spain

    A. Planes

  8. European Spallation Source ESS AB, 176, SE-221 00, Lund, Sweden

    P. P. Deen

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  1. S. Aksoy
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  2. M. Acet
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Corresponding author

Correspondence to M. Acet .

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Editors and Affiliations

  1. , Graduate School of Engineering, Osaka University, Yamada-oka, Suita 2-1, Osaka, 565-0871, Japan

    Tomoyuki Kakeshita

  2. , Graduate School of Engineering, Osaka University, Yamada-oka, Suita 2-1, Osaka, 565-0871, Japan

    Takashi Fukuda

  3. Theoretical Division, T-11, MS B262, Los Alamos National Lab, Los Alamos, 87545, New Mexico, USA

    Avadh Saxena

  4. Dept. d'Estructura i Constituents, de la Matèria, Universidad de Barcelona, Diagonal 647, Barcelona, 08028, Spain

    Antoni Planes

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Aksoy, S. et al. (2012). Magnetic Interactions Governing the Inverse Magnetocaloric Effect in Martensitic Ni–Mn-Based Shape-memory Alloys. In: Kakeshita, T., Fukuda, T., Saxena, A., Planes, A. (eds) Disorder and Strain-Induced Complexity in Functional Materials. Springer Series in Materials Science, vol 148. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20943-7_4

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  • DOI: https://doi.org/10.1007/978-3-642-20943-7_4

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