Abstract
The electrochemical de-oxidation process, also called FFC-Cambridge process, has been proposed previously to produce reactive metals and their alloys through reduction of their metal oxides. The process works by introducing metal oxides into a molten salt bath where it is electrolysed to form metal powders offering both economic and environmental benefits over the traditional metal production methods. Within the frame of the EU-financed project SCALE (GA 730105), SINTEF is investigating the optimal parameters of the direct electrolytic reduction of Sc2O3 and Sc2O3–Al2O3 precursors (dross from Al-Sc alloy production), giving Sc and Al-Sc metallic powders, respectively, in a molten CaCl2-based electrolyte at a working temperature of ca. 900 °C. The influence of the applied cathodic potential in the reduction mechanism and in the metal product has been studied.
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J. Røyset and N. Ryum, Inter. Mater. Rev., 50 (2005) 19.
G.Z. Chen, D.J. Fray and T.W. Farthing, Nature, 407 (6802) (2000) 361.
D. A. Wenz, I. Johnson and R. D. Wolson: J. Chem. Eng. Data 14 (2) (1969) 250–252.
K. Ono and R. O. Suzuki, JOM, 54(2) (2002) 164–166.
HSC 7.11 © Outotec Research Center, 1974–2011.
M. Harata, T. Nakamura, H. Yakushiji and T.H. Okabe, Trans. Inst. Min. Metall. Sect. C, 117 (2) (2008).
E.g. S.J. Oosthuizen, J. South. African Inst. Min. and Metall., 11 (2011) 199–202.
M. Maeda and A. McLean, Trans. ISS (1986) 61–65.
Ito, Shimada and Kawamura, Proc. Electrochem. Soc. (1992) 574.
Aluminium, Vol 11 (2016) 38–39 (https://www.tomorrowtechnology.it/images/pdf/news/TT-Tomorrow-article.pdf).
R.A. Sharma, J. Phys. Chem., 74 (1974) 3896–3900.
M.A. Bredie, in “Molten Salt Chemistry,” M. Blander (Ed.), Interscience, New York, (1964) p 364.
J.D. Corbett, in “Fused Salts” B.R. Sundheim (Ed.), McGraw-Hill, New York (1964) p 341.
Acknowledgements
This work has received funding from the European Union’s H2020 Programme under Grant Agreement No. 730105 (SCALE project: http://scale-project.eu/).
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Martinez, A.M., Osen, K.S., Gudbrandsen, H., Sommerseth, C., Wang, Z., Darell, O. (2018). Direct Method for Producing Scandium Metal and Scandium-Aluminium Intermetallic Compounds from the Oxides. In: Martin, O. (eds) Light Metals 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72284-9_203
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DOI: https://doi.org/10.1007/978-3-319-72284-9_203
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