Abstract
Emulsion templating is a versatile approach used for the preparation of hierarchical macroporous polymers with well-defined porosity. The basis of the approach is constituted on using concentrated emulsions as template for the creation of porous structures. With this approach, hierarchical polymer foams are usually produced by using high internal phase emulsions (HIPEs) as precursor templates. HIPEs, is defined as the emulsions having internal phase volume fraction (Ø) greater than 0.74. When a HIPE is prepared to contain monomer(s), polymerization of the monomer containing phase result in polymers known as polyHIPEs. PolyHIPEs are macroporous polymers exhibiting low density. The pore structure of polyHIPEs can be easily altered by variating the precursor HIPE templates. Thereby, polyHIPEs are good candidates to be used in the applications such as adsorption, chromatography, catalysis, tissue engineering, and storage of gases, liquids, and energy, where high permeability and shape stabilization is required. In this respect, numerous polyHIPEs exhibiting different chemistries and properties developed by scientists are in serve of the above-mentioned fields. To expand the use of polyHIPEs in industrial applications, it is necessary to adopt the emulsification process and properties of HIPEs, polymerization strategies and properties of polyHIPEs, and approaches and methods for their development. Regarding this, a retrospective analysis of HIPEs and polyHIPEs can be the key to developing novel materials for future applications.
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References
Agrawal, M., Yadav, A., Nandan, B., Srivastava, R.K.: Facile synthesis of templated macrocellular nanocomposite scaffold via emulsifier-free HIPE-ROP. Chem. Commun. 56, 12604–12607 (2020). https://doi.org/10.1039/d0cc05331g
Akay, G., Birch, M.A., Bokhari, M.A.: Microcellular polyHIPE polymer supports osteoblast growth and bone formation in vitro. Biomaterials 25, 3991–4000 (2004). https://doi.org/10.1016/j.biomaterials.2003.10.086
Alexandratos, S.D., Beauvais, R., Duke, J.R., Jorgensen, B.S.: Functionalized polymer foams as metal ion chelating agents with rapid complexation kinetics. J. Appl. Polym. Sci. 68, 1911–1916 (1998). https://doi.org/10.1002/(SICI)1097-4628(19980620)68:12%3c1911::AID-APP3%3e3.0.CO;2-O
Althubeiti, K.M., Horozov, T.S.: Efficient preparation of macroporous poly(methyl methacrylate) materials from high internal phase emulsion templates. Reacti. Func. Polym. 142, 207–212 (2019). https://doi.org/10.1016/j.reactfunctpolym.2019.06.015
Audouin, F., Birot, M., Pasquinet, É., Deleuze, H., Besnard, O., Poullain, D.: Synthesis of porous materials by 2-nitroresorcinol/cyanuric chloride thermal polycondensation in emulsions. J. Appl. Polym. Sci. 108, 2808–2813 (2008)
Ayres, N.: Atom transfer radical polymerization: a robust and versatile route for polymer synthesis. Polym. Rev. 51, 138–162 (2011). https://doi.org/10.1080/15583724.2011.566402
Azhar, U., Huyan, C., Wan, X., Zong, C., Xu, A., Liu, J., Ma, J., Zhang, S., Geng, B.: Porous multifunctional fluoropolymer composite foams prepared via humic acid modified Fe3O4 nanoparticles stabilized Pickering high internal phase emulsion using cationic fluorosurfactant as co-stabilizer. Arabian J. Chem. 12, 559–572 (2019). https://doi.org/10.1016/j.arabjc.2018.04.003
Balderrama, J.A.M., Dourges, M.A., Magueresse, A., Maheo, L., Deleuze, H., Glouannec, P.: Emulsion-templated pullulan monoliths as phase change materials encapsulating matrices. Mater. Today Commun. 17, 466–473 (2018). https://doi.org/10.1016/j.mtcomm.2018.10.012
Barbara, I., Dourges, M.A., Deleuze, H.: Preparation of porous polyurethanes by emulsion-templated step growth polymerization. Polymer 132, 243–251 (2017). https://doi.org/10.1016/j.polymer.2017.11.018
Barbetta, A., Cameron, N.R.: Morphology and surface area of emulsion-derived (polyHIPE) solid foams prepared with oil-phase soluble porogenic solvents: three-component surfactant system. Macromolecules 37, 3202–3213 (2004). https://doi.org/10.1021/ma035944y
Barbetta, A., Dentini, M., Leandri, L., Ferraris, G., Coletta, A., Bernabei, M.: Synthesis and characterization of porous glycidylmethacrylate–divinylbenzene monoliths using the high internal phase emulsion approach. React. Func. Polym. 69, 724–736 (2009). https://doi.org/10.1016/j.reactfunctpolym.2009.05.007
Barby, D., Haq, Z.: US Patent 4522953 (1985)
Barlık, N., Keskinler, B., Kocakerim, M.M., Akay, G.: Surface modification of monolithic PolyHIPE polymers for anionic functionality and their ion exchange behavior. J. Appl. Polym. Sci. 132, 42286 (2015). https://doi.org/10.1002/app.42286
Barlık, N., Keskinler, B., Kocakerim, M.M., Akay, G.: Functionalized PolyHIPE polymer monoliths as an anion-exchange media for removal of nitrate ions from aqueous solutions. Desalin. Water Treat. 57, 26440–26447 (2016). https://doi.org/10.1080/19443994.2016.1164083
Benaddi, A.O., Cohen, O., Matyjaszewski, K., Silverstein, M.S.: RAFT polymerization within high internal phase emulsions: Porous structures, mechanical behaviors, and uptakes. Polymer 213,(2021). https://doi.org/10.1016/j.polymer.2020.123327
Benmachou, K., Deleuze, H., Herogueza, V.: Ring opening polymerisation of highly concentrated inverse emulsions to obtain microcellular foams. React. Funct. Polym. 55, 211–217 (2003). https://doi.org/10.1016/S1381-5148(02)00248-1
Benicewicz, B.C., Jarvinen, G.D., Kathios, D.J., Jorgensen, B.S.: Open-celled polymeric foam monoliths for heavy metal separations study. J. Radioanal. Nucl. Chem. 235, 31–35 (1998). https://doi.org/10.1007/BF02385933
Busby, W., Cameron, N.R., Jahoda, C.A.B.: Emulsion-derived foams (polyHIPEs) containing poly(ε-caprolactone) as matrixes for tissue engineering. Biomacromol 2, 154–164 (2001). https://doi.org/10.1021/bm0000889
Busby, W., Cameron, N.R., Jahoda, C.A.B.: Tissue engineering matrixes by emulsion templating. Polym. Int. 51, 871–881 (2002). https://doi.org/10.1002/pi.934
Butler, R., Hopkinson, I., Cooper, A.I.: Synthesis of porous emulsion-templated polymers using high internal phase CO2-in-water emulsions. J. Am. Chem. Soc. 125, 14473–14481 (2003). https://doi.org/10.1021/ja037570u
Caldwell, S., Johnson, D.W., Didsbury, M.P., Murray, B.A., Wu, J.J., Przyborskibd, Stefan A., Cameron, N.R.: Degradable emulsion-templated scaffolds for tissue engineering from thiol–ene photopolymerisation. Soft. Matter 8, 10344–10351 (2012). https://doi.org/10.1039/C2SM26250A
Cameron, N.R.: High internal phase emulsion templating as a route to well-defined porous polymers. Polymer 46, 1439–1449 (2005). https://doi.org/10.1016/j.polymer.2004.11.097
Cameron, N.R., Sherrington, D.C.: High internal phase emulsions (HIPEs)—structure, properties and use in polymer preparation. In: Biopolymers Liquid Crystalline Polymers Phase, Emulsion. Advances in Polymer Science, vol. 126. Springer, Berlin (1996). https://doi.org/10.1007/3-540-60484-7_4
Cameron, N.R., Sherrington, D.C.: Preparation and glass transition temperatures of elastomeric PolyHIPE materials. J. Mater. Chem. 7, 2209–2212 (1997). https://doi.org/10.1039/A702030I
Cameron, N.R., Sherrington, D.C., Albiston, L., Gregory, D.P.: Study of the formation of the open-cellular morphology of poly(styrene/divinylbenzene) polyHIPE materials by cryo-SEM. Colloid Polym. Sci. 274 (1996). https://doi.org/10.1007/BF00655236
Cameron, N.R., Krajnc, P., Silverstein, M.S.: Colloidal templating. In: Silverstein, M.S., Cameron, N.R., Marc, A. (eds.) Porous Polymers, pp. 119–172. Hillmyer. Wiley, Hoboken (2011)
Carnachan, R.J., Bokhari, M., Przyborskibc, S.A., Cameron, N.R.: Tailoring the morphology of emulsion-templated porous polymers. Soft Matter 2, 608–616 (2006). https://doi.org/10.1039/B603211G
Cauvin, S., Colver, P.J., Bon, S.A.F.: Pickering stabilized miniemulsion polymerization: preparation of clay armored latexes. Macromolecules 38, 7887–7889 (2005). https://doi.org/10.1021/ma051070z
Chen, C., Eissa, A.M., Schiller, T.L., Cameron, N.R.: Emulsion-templated porous polymers prepared by thiol-ene and thiol-yne photopolymerisation using multifunctional acrylate and non-acrylate monomers. Polymer 126, 395–401 (2017). https://doi.org/10.1016/j.polymer.2017.04.021
Chevalier, Y., Bolzinger, M.A.: Emulsions stabilized with solid nanoparticles: pickering emulsions. Colloid Surf. A Physicochem. Eng. Asp. 439, 23–34 (2013). https://doi.org/10.1016/j.colsurfa.2013.02.054
Christenson, E.M., Soofi, W., Holm, J.L., Cameron, N.R., Mikos, A.G.: Biodegradable fumarate-based polyHIPEs as tissue engineering scaffolds. Biomacromol 8, 3806–3814 (2007). https://doi.org/10.1021/bm7007235
Cohen, N., Silverstein, M.S.: Synthesis of emulsion-templated porous polyacrylonitrile and its pyrolysis to porous carbon monoliths. Polymer 52, 282–287 (2011). https://doi.org/10.1016/j.polymer.2010.11.026
Choudhury, S., Duffy, E., Connolly, D., Paull, B., White, B.: Graphene oxide nanoparticles and their influence on chromatographic separation using polymeric high internal phase emulsions. Separations 4, 5 (2017). https://doi.org/10.3390/separations4010005
Davankov, V.A., Tsyurupa, M.P.: Structure and properties of hypercrosslinked polystyrene—the first representative of a new class of polymer networks. React. Polym. 13, 27–42 (1990). https://doi.org/10.1016/0923-1137(90)90038-6
David, D., Silverstein, M.S.: Porous polyurethanes synthesized within high internal phase emulsions. J. Polym. Sci., Part a: Polym. Chem. 47, 5806–5814 (2009). https://doi.org/10.1002/pola
Desforges, A., Deleuze, H., Mondain-Monval, O., Backov, R.: Palladium nanoparticle generation within microcellular polymeric foam and size dependence under synthetic conditions. Ind. Eng. Chem. Res. 44, 8521–8529 (2005). https://doi.org/10.1021/ie040239e
Desforges, A., Backov, R., Deleuze, H., Mondain-Monval, O.: Generation of palladium nanoparticles within macrocellular polymeric supports: application to the heterogeneous catalysis of the Suzuki-Miyaura coupling reaction. Adv. Funct. Mater. 15, 1689–1695 (2005). https://doi.org/10.1002/adfm.200500146
Elmes, A.R., Hammond, K., Sherrington, D.C.: EP 289238 (1994)
Esser-Kahn, A.P., Odom, S.A., Sottos, N.R., White, S.R., Moore, J.S.: Triggered release from polymer capsules. Macromolecules 44, 5539–5553 (2011). https://doi.org/10.1021/ma201014n
Flory, P.J.: Fundamental principles of condensation polymerization. Chem. Rev. 39(1), 137–197 (1946). https://doi.org/10.1021/cr60122a003
Freire, M.G., Dias, A.M.A., Coelho, M.A.Z., Coutinho, J.A.P., Marrucho, I.M.: Aging mechanisms of perfluorocarbon emulsions using image analysis. J. Colloid Interface Sci. 286, 224–232 (2005). https://doi.org/10.1016/j.jcis.2004.12.036
García-Landeros, S.A., Cervantes-Díaz, J.M., Gutiérrez-Becerra, A., Pelayo-Vázquez, J.B., Landazuri-Gomez, G., Herrera-Ordonez, J., Soltero-Martínez, J.F.A., Mota-Morales, J.D., Pérez-García, M.G.: Oil-in-eutectic mixture HIPEs co-stabilized with surfactant and nanohydroxyapatite: ring-opening polymerization for nanocomposite scaffold synthesis. Chem. Commun. 55, 12292–12295 (2019). https://doi.org/10.1039/C9CC06292K
Gokmen, M.T., Camp, W.V., Colver, P.J., Bon, S.A.F., Du Prez, F.E.: Fabrication of porous “clickable” polymer beads and rods through generation of high internal phase emulsion (HIPE) droplets in a simple microfluidic device. Macromolecules 42, 9289–9294 (2009). https://doi.org/10.1021/ma9018679
Grosse, M.T., Lamotte, M., Birot, M., Deleuz, H.: Preparation of microcellular polysiloxane monoliths. J. Polym. Sci. Part A: Polym. Chem. 46, 21–32 (2008). https://doi.org/10.1002/pola.22351
Gurevitch, I., Silverstein, M.S.: Nanoparticle-based and organic-phase-based AGET ATRP PolyHIPE synthesis within Pickering HIPEs and surfactant-stabilized HIPEs. Macromolecules 44, 3398–3409 (2011). https://doi.org/10.1021/ma200362u
Gurevitch, I., Silverstein, M.S.: One-pot synthesis of elastomeric monoliths filled with individually encapsulated liquid droplets. Macromolecules 45, 6450–6456 (2012). https://doi.org/10.1021/ma301007s
Hainey, P., Huxham, I.M., Rowatt, B., Sherrington, D.C., Tetley, L.: Synthesis and ultrastructural studies of styrene-divinylbenzene polyHIPE polymers. Macromolecules 24, 117–121 (1991). https://doi.org/10.1021/ma00001a019
Hamielec, A.E., Tobita, H.: Polymerization processes, 1. Fundamentals. In: Ullmann’s encyclopedia of industrial chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim (2012). https://doi.org/10.1002/14356007.a21_305.pub2
Hoyle, C.E., Bowman, C.N.: Thiol–ene click chemistry. Angew. Chem. Int. Ed. 49, 1540–1573 (2010). https://doi.org/10.1002/anie.200903924
Hu, Y., Wang, J., Li, X., Hu, X., Zhou, W., Dong, X., Wang, C., Yang, Z., Binks, B.P.: Facile preparation of bioactive nanoparticle/poly(ε-caprolactone) hierarchical porous scaffolds via 3D printing of high internal phase Pickering emulsions. J. Colloid. Interface Sci. 545, 104–115 (2019). https://doi.org/10.1016/j.jcis.2019.03.024
Huš, S., Krajnc, P.: PolyHIPEs from methyl methacrylate: Hierarchically structured microcellular polymers with exceptional mechanical properties. Polymer 55, 4420–4424 (2014). https://doi.org/10.1016/j.polymer.2014.07.007
Ikem, V.O., Menner, A., Bismarck, A.: High internal phase emulsions stabilized solely by functionalized silica particles. Angew. Chem. Int. Ed. 47, 8277–8279 (2008). https://doi.org/10.1002/anie.200802244
Jakubowski, W., Matyjaszewski, K.: Activator generated by electron transfer for atom transfer radical polymerization. Macromolecules 38, 4139–4146 (2005). https://doi.org/10.1021/ma047389l
Jeřábek, K., Pulko, I., Soukupova, K., Štefanec, D., Krajnc, P.: Porogenic solvents influence on morphology of 4-vinylbenzyl chloride based polyHIPEs. Macromolecules 41, 3543–3546 (2008). https://doi.org/10.1021/ma8002104
Jerenec, S., Šimić, M., Savnik, A., Podgornik, A., Kolar, M., Turnšek, M., Krajnc, P.: Glycidyl methacrylate and ethylhexyl acrylate based polyHIPE monoliths: morphological, mechanical and chromatographic properties. React. Func. Polym. 78, 32–37 (2014). https://doi.org/10.1016/j.reactfunctpolym.2014.02.011
Kabalnov, A.S., Shchukin, E.D.: Ostwald ripening theory: applications to fluorocarbon emulsion stability. Adv. Colloid Interface Sci. 38, 69–97 (1992). https://doi.org/10.1016/0001-8686(92)80043-W
Kekevi, B., Mert, E.H.: Synthesis of β-myrcene-based macroporous nanocomposite foams: altering the morphological and mechanical properties by using organo-modified nanoclay. J. Appl. Polym. Sci. 138, 50074 (2021). https://doi.org/10.1002/app.50074
Kimmins, S.D., Wyman, P., Cameron, N.R.: Photopolymerised methacrylate-based emulsion-templated porous polymers. React. Funct. Polym 72, 947–954 (2012). https://doi.org/10.1016/j.reactfunctpolym.2012.06.015
Kirche, L., Theato, P., Cameron, N.R.: Reactive thiol-ene emulsion-templated porous polymers incorporating pentafluorophenyl acrylate. Polymer 54, 1755–1761 (2013). https://doi.org/10.1016/j.polymer.2013.01.024
Knight, E., Murray, B., Carnachan, R., Przyborski, S.: Alvetex®: polystyrene scaffold technology for routine three dimensional cell culture. Methods Mol. Biol. 695, 323–340 (2011). https://doi.org/10.1007/978-1-60761-984-0_20
Koler, A., Krajnc, P.: Macroporous titania monoliths from emulsion templated composites. Colloid Polym. Sci. 297, 799–807 (2019). https://doi.org/10.1007/s00396-019-04504-7
Koler, A., Krajnc, P.: Surface modification of hypercrosslinked vinylbenzyl chloride polyHIPEs by grafting via raft. Macromol. Chem. Phys. 222, 2000381 (2021). https://doi.org/10.1002/macp.202000381
Koler, A., Pulko, I., Krajnc, P.: Post polymerisation hypercrosslinking with emulsion templating for hierarchical and multi-level porous polymers. Acta Chim. Slov. 67, 349–360 (2020). https://doi.org/10.17344/acsi.2020.5901
Kovačič, S.: Ring opening metathesis polymerisation (ROMP) as a tool for PolyHIPEs with extraordinary mechanical properties. Acta Chim. Slov. 60, 448–454 (2013)
Kovačič, S., Krajnc, P.: Macroporous monolithic poly(4‐vinylbenzyl chloride) columns for organic synthesis facilitation by in situ polymerization of high internal phase emulsions. J. Polym Sci. Part A Polym. Chem. 47, 6726–6734 (2009). https://doi.org/10.1002/pola.23732
Kovačič, S., Slugovc, C.: Ring-opening metathesis polymerisation derived poly(dicyclopentadiene) based materials. Mater. Chem. Front. 4, 2235–2255 (2020). https://doi.org/10.1039/D0QM00296H
Kovačič, S., Štefanec, D., Krajnc, P.: Highly porous open-cellular monoliths from 2-hydroxyethyl methacrylate based high internal phase emulsions (HIPEs): preparation and void size tuning. Macromolecules 40, 8056–8060 (2007). https://doi.org/10.1021/ma071380c
Kovačič, S., Krajnc, P., Slugovc, C.: Inherently reactive polyHIPE material from dicyclopentadiene. Chem. Commun. 46, 7504–7506 (2010). https://doi.org/10.1039/C0CC02610G
Kovačič, S., Jeřabek, K., Krajnc, P.: Responsive poly(acrylic acid) and poly(n-isopropylacrylamide) monoliths by high internal phase emulsion (HIPE) templating. Macromol. Chem. Phys. 212, 2151–2158 (2011). https://doi.org/10.1002/macp.201100229
Kovačič, S., Jeřábek, K., Krajnc, P., Slugovc, C.: Ring opening metathesis polymerisation of emulsion templated dicyclopentadiene giving open porous materials with excellent mechanical properties. Polym. Chem. 3, 325–328 (2012). https://doi.org/10.1039/C2PY00518B
Kovačič, S., Matsko, N.B., Ferk, G., Slugovc, C.: Nanocomposite foams from iron oxide stabilized dicyclopentadiene high internal phase emulsions: preparation and bromination. Acta Chim. Slov. 61, 208–214 (2014)
Kovačič, S., Preishuber-Pflügl, F., Pahovnik, D., Žagar, E., Slugovc, C.: Covalent incorporation of the surfactant into high internal phase emulsion templated polymeric foams. Chem. Commun 51, 7725–7728 (2015). https://doi.org/10.1039/C4CC09199J
Kovalenko, A., Zimny, K., Mascaro, B., Brunet, T., Mondain-Monval, O.: Tailoring of the porous structure of soft emulsion-templated polymer materials. Soft Matter 12, 5154–5163 (2016). https://doi.org/10.1039/C6SM00461J
Krajnc, P., Brown, J.F., Cameron, N.R.: Monolithic scavenger resins by amine functionalizations of poly(4-vinylbenzyl chloride-co-divinylbenzene) polyHIPE materials. Org. Lett. 4(15), 2497–2500 (2002). https://doi.org/10.1021/ol026115k
Krajnc, P., Leber, N., Štefanec, D., Kontrec, S., Podgornik, A.: Preparation and characterisation of poly(high internal phase emulsion) methacrylate monoliths and their application as separation media. J. Chrom. A 1065, 69–73 (2005). https://doi.org/10.1016/j.chroma.2004.10.051
Krajnc, P., Štefanec, D., Pulko, I.: Acrylic acid “reversed” polyHIPEs. Macromol. Rapid Commun. 26, 1289–1293 (2005). https://doi.org/10.1002/marc.200500353
Kralchevsky, P.A., Ivanov, I.B., Ananthapadmanabhan, K.P., Lips, A.: On the thermodynamics of particle-stabilized emulsions: curvature effects and catastrophic phase inversion. Langmuir 21, 50–63 (2005). https://doi.org/10.1021/la047793d
Kulygin, O., Silverstein, M.S.: Porous poly (2-hydroxyethyl methacrylate) hydrogels synthesized within high internal phase emulsions. Soft Matter 3, 1525–1529 (2007). https://doi.org/10.1039/b711610a
Lafleur, J.P., Senkbeil, S., Novotny, J., Nys, G., Bøgelund, N., Rand, K.D., Foret, F., Kutter, J.P.: Rapid and simple preparation of thiol–ene emulsion-templated monoliths and their application as enzymatic microreactors. Lab Chip 15, 2162–2172 (2015). https://doi.org/10.1039/C5LC00224A
Lamson, M., Epshtein-Assor, Y., Silverstein, M.S., Matyjaszewski, K.: Synthesis of degradable polyHIPEs by AGET ATRP. Polymer 54, 4480–4485 (2013). https://doi.org/10.1016/j.polymer.2013.06.048
Lee, A., Langford, C.R., Rodriguez-Lorenzo, L.M., Thissen, H., Cameron, N.R.: Bioceramic nanocomposite thiol-acrylate polyHIPE scaffolds for enhanced osteoblastic cell culture in 3D. Biomater. Sci. 5, 2035–2047 (2017). https://doi.org/10.1039/C7BM00292K
Li, Z., Liu, H., Zeng, L., Liu, H., Wang. Y.: The facile synthesis of PMMA polyHIPEs with highly interconnected porous microstructures. J. Mater. Sci. 51, 9005–9018 (2016). https://doi.org/10.1007/s10853-016-0154-7
Li, X., Zhang, C., Du, Z., Li, H.: Preparation of hydrophilic/hydrophobic porous materials. J. Colloid Interface Sci. 323, 120–125 (2008). https://doi.org/10.1016/j.jcis.2008.03.028
Lissant, K.J.: The geometry of high-internal-phase-ratio emulsions. J. Colloid Interface Sci. 22, 462–468 (1966). https://doi.org/10.1016/0021-9797(66)90091-9
Livshina, S., Silverstein, M.S.: Cross-linker flexibility in porous crystalline polymers synthesized from long side-chain monomers through emulsion templating. Soft Matter 4, 1630–1638 (2008). https://doi.org/10.1039/B802173B
Lovelady, E., Kimmins, S.D., Wu, J., Cameron, N.R.: Preparation of emulsion-templated porous polymers using thiol–ene and thiol–yne chemistry. Polym. Chem. 2, 559–562 (2011). https://doi.org/10.1039/C0PY00374C
Lowe, A.B.: Thiol-ene ‘“click”’ reactions and recent applications in polymer and materials synthesis. Polym. Chem. 1, 17–36 (2010). https://doi.org/10.1039/B9PY00216B
Luo, J., Huang, Z., Liu, L., Wang, H., Ruan, G., Zhao, C., Du, F.: Recent advances in separation applications of polymerized high internal phase emulsions. J. Sep. Sci. 44, 169–187 (2021). https://doi.org/10.1002/jssc.202000612
Luo, Y., Wang, A.N., Gao, X.: Pushing the mechanical strength of polyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 8, 1824–1830 (2012). https://doi.org/10.1039/C1SM06756G
Ma, L., Luo, X., Cai, N., Xue, Y., Zhu, S., Fu, Z., Yu, F.: Facile fabrication of hierarchical porous resins via high internal phase emulsion and polymeric porogen. Appl. Surf. Sci. 305, 186–193 (2014). https://doi.org/10.1016/j.apsusc.2014.03.036
Ma, C., Wang, J., Cho, L.: Preparation of macroporous hybrid monoliths via iron-based MOFs-stabilized CO2-in-water HIPEs and use for β-amylase immobilization. Polym. Adv. Technol. 31, 2967–2979 (2020). https://doi.org/10.1002/pat.5019
Majer, J., Krajnc, P.: Amine functionalisations of glycidyl methacrylate based polyHIPE monoliths. Macromol. Symp. 296, 5–10 (2010). https://doi.org/10.1002/masy.201051002
Majer, J., Paljevac, M., Žagar, E., Kovačič, S., Krajnc, P.: Functionalization of 2-hydroxyethyl methacrylate-based polyHIPEs: effect of the leaving group. React. Funct. Polym. 109, 99–103 (2016). https://doi.org/10.1016/j.reactfunctpolym.2016.10.008
Malakian, A., Zhou, M., Zowada, R.T., Foudazi, R.: Synthesis and insitu functionalization of microfiltration membranes via high internal phase emulsion templating. Polym. Int. 68, 1378–1386 (2019). https://doi.org/10.1002/pi.5828
Mao, D., Li, T., Liu, H., Li, Z., Shao, H., Li, M.: Preparation of macroporous polyHIPE foams via radiation-induced polymerization at room temperature. Colloid Polym. Sci. 291, 1649–1656 (2013). https://doi.org/10.1007/s00396-013-2899-8
Matyjaszewski, K.: Atom transfer radical polymerization (ATRP): current status and future perspectives. Macromolecules 45, 4015–4039 (2012). https://doi.org/10.1021/ma3001719
Matyjaszewski, K., Spanswick, J.: Controlled/living radical polymerization. Materialstoday 8, 26–33 (2005). https://doi.org/10.1016/S1369-7021(05)00745-5
Matyjaszewski, K., Xia, J.: Atom transfer radical polymerization. Chem. Rev. 101, 2921–2990 (2001). https://doi.org/10.1021/cr940534g
Menner, A., Bismarck, A.: New evidence for the mechanism of the pore formation in polymerising high internal phase emulsions or why polyHIPEs have an interconnected pore network structure. Macromol. Symp. 242, 19–24 (2006). https://doi.org/10.1002/masy.200651004
Menner, A., Haibach, K., Powell, R., Bismarck, A.: Tough reinforced open porous polymer foams via concentrated emulsion templating. Polymer 47, 7628–7635 (2006). https://doi.org/10.1016/j.polymer.2006.09.022
Menner, A., Ikem, V., Salgueiro, M., Shaffer, M.S.P., Bismarck, A.: High internal phase emulsion templates solely stabilised by functionalised titania nanoparticles. Chem. Commun. 41, 4274–4276 (2007a). https://doi.org/10.1039/B708935J
Menner, A., Verdejo, R., Shaffer, M., Bismarck, A.: Particle-stabilized surfactant-free medium internal phase emulsions as templates for porous nanocomposite materials: poly-pickering-foams. Langmuir 23, 2398–2403 (2007b). https://doi.org/10.1021/la062712u
Mert, E.H., Kaya, M.A., Yıldırım, H.: Preparation and characterization of polyester–glycidyl methacrylate polyHIPE monoliths to use in heavy metal removal. Des. Monomer. Polym. 15, 113–126 (2012). https://doi.org/10.1163/156855511X615001
Mert, H.H.: PolyHIPE composite based-form stable phase change material for thermal energy storage. Int. J. Energy Res. 44, 6583–6594 (2020). https://doi.org/10.1002/er.5390
Mert, E.H., Kekevi, B.: Synthesis of polyHIPEs through high internal phase emulsions of β-myrcene. Coloid. Polym. Sci. 298, 1423–1432 (2020). https://doi.org/10.1007/s00396-020-04730-4
Mert, E.H., Mert, H.H.: Preparation of polyHIPE nanocomposites: Revealing the influence of experimental parameters with the help of experimental design approach. Polym. Compos. 42, 724–738 (2021). https://doi.org/10.1002/pc.25861
Mert, H.H., Şen, S.: Synthesis and characterization of polyHIPE composites containing halloysite nanotubes. e-Polymers 16, 419–428 (2016). https://doi.org/10.1515/epoly-2016-0175
Mert, E.H., Yıldırım, H., Üzümcü, A.T., Kavas, H.: Synthesis and characterization of magnetic polyHIPEs with humic acid surface modified magnetic iron oxide nanoparticles. React. Funct. Polym. 73, 175–181 (2013). https://doi.org/10.1016/j.reactfunctpolym.2012.09.005
Mert, E.H., Slugovc, C., Krajnc, P.: Tailoring the mechanical and thermal properties of dicyclopentadiene polyHIPEs with the use of a comonomer. eXPRESS Polym. Lett. 9, 344–353 (2015). https://doi.org/10.3144/expresspolymlett.2015.32
Mert, H.H., Tekay, E., Nugay, N., Nugay, T., Şen, S.: Adsorptive polyHIPE composites based on biosorbent immobilized nanoclay: effects of immobilization techniques. Polym. Eng. Sci. 58, 1229–1240 (2018). https://doi.org/10.1002/pen.24684
Mert, H.H., Mert, M.S., Mert, E.H.: A statistical approach for tailoring the morphological and mechanical properties of polystyrene PolyHIPEs: looking through experimental design. Mater. Res. Express 6 (2019). https://doi.org/10.1088/2053-1591/ab437f
Mezhouda, S., Paljevac, M., Koler, A., Droumaguet, B.L., Grande, D., Krajnc, P.: Novel hypercrosslinking approach toward high surface area functional 2-hydroxyethyl methacrylate-based polyHIPEs. React. Func. Polym. 132, 51–59 (2018). https://doi.org/10.1016/j.reactfunctpolym.2018.09.009
Misra, P., Chitanda, J.M., Dalai, A.K., Adjaye, J.: Selective removal of nitrogen compounds from gas oil using functionalized polymeric adsorbents: efficient approach towards improving denitrogenation of petroleum feedstock. Chem. Eng. J. 295, 109–118 (2016). https://doi.org/10.1016/j.cej.2016.03.024
Moghbeli, M.R., Khajeh, A., Alikhani, M.: Nanosilica reinforced ion-exchange polyHIPE type membrane for removal of nickel ions: preparation, characterization and adsorption studies. Chem. Eng. J. 309, 552–562 (2017). https://doi.org/10.1016/j.cej.2016.10.048
Mrówka, J., Gackowski, M., Lityńska-Dobrzyńska, L., Bernasik, A., Kosydar, R., Drelinkiewicz, A., Hasik, M.: Poly(methylvinylsiloxane)-based high internal phase emulsion-templated materials (polyHIPEs)—preparation, incorporation of palladium, and catalytic properties. Ind. Eng. Chem. Res. 59, 19485–19499 (2020). https://doi.org/10.1021/acs.iecr.0c03429
Naranda, J., Sušec, M., Maver, U., Gradišnik, L., Gorenjak, M., Vukasović, A., Ivković, A., Rupnik, M.S., Vogrin, M., Krajnc, P.: Polyester type polyHIPE scaffolds with an interconnected porous structure for cartilage regeneration. Sci. Rep. 6, 28695 (2016). https://doi.org/10.1038/srep28695
Nikjoo, D., Akhtar, F.: Structured emulsion-templated porous copolymer based on photopolymerization for carbon capture. J. CO2 Util. 21, 473–479 (2017). https://doi.org/10.1016/j.jcou.2017.08.007
Nuyken, O., Pask, S.D.: Ring-opening polymerization—an introductory review. Polymers 5, 361–403 (2013). https://doi.org/10.3390/polym5020361
O’Brien, F.J.: Biomaterials & scaffolds for tissue engineering. Mater. Today 14, 88–95 (2011). https://doi.org/10.1016/S1369-7021(11)70058-X
Onder, O.C., Utroša, P., Caserman, S., Podobnik, M., Žnidarič, M.T., Grdadolnik, J., Kovačič, S., Žagar, E., Pahovnik, D.: Emulsion-templated synthetic polypeptide scaffolds prepared by ring-opening polymerization of N-carboxyanhydrides. Polym. Chem. 11, 4260–4270 (2020). https://doi.org/10.1039/d0py00387e
Oschatz, M., Borchardt, L., Thommes, M., Cychosz, K.A., Senkovska, I., Klein, N., Frind, R., Leistner, M., Presser, V., Gogotsi, Y., Kaskel, S.: Carbide-derived carbon monoliths with hierarchical pore architectures. Angew. Chem. Int. Ed. 51, 7577–7580 (2012). https://doi.org/10.1002/anie.201200024
Ostwald, W.: Beiträge zur kenntnis der emulsionen. Colloid Polym. Sci. 6, 103–109 (1910). https://doi.org/10.1007/BF01465754
Owen, R., Sherborne, C., Paterson, T., Green, N.H., Reilly, G.C., Claeyssens, F.: Emulsion templated scaffolds with tunable mechanical properties for bone tissue engineering. J. Mech. Behav. Biomed. Mater. 54, 159–172 (2016). https://doi.org/10.1016/j.jmbbm.2015.09.019
Pahovnik, D., Majer, J., Žagar, E., Kovačič, S.: Synthesis of hydrogel polyHIPEs from functionalized glycidyl methacrylate. Polym. Chem. 7, 5132–5138 (2016). https://doi.org/10.1039/C6PY01122E
Pal, R.: Yield stress and viscoelastic properties of high internal phase ratio emulsions. Colloid Polym. Sci. 277, 583–588 (1999). https://doi.org/10.1007/s003960050429
Pan, J., Luo, J., Cao, J., Liu, J., Huang, W., Zhang, W., Yang, L.: Competitive adsorption of three phenolic compounds to hydrophilic urea-formaldehyde macroporous foams derived from lignin-based Pickering HIPEs template. RSC Adv. 6, 93894–93904 (2016). https://doi.org/10.1039/C6RA20919J
Parın, F.N., Mert, E.H.: Hydrophilic closed-cell macroporous foam preparation by emulsion templating. Mater. Lett. 277,(2020). https://doi.org/10.1016/j.matlet.2020.128287
Pérez-García, M.G., Gutierrez, M.C., Mota-Morales, J.D., Luna-Barcenas, G., del Monte, F.: Synthesis of biodegradable macroporous poly(L-lactide)/ poly(ε-caprolactone) blend using oil-in-eutectic-mixture high internal phase emulsions as template. ACS Appl. Mater. Interfaces 8, 16939–16949 (2016). https://doi.org/10.1021/acsami.6b04830
Perrier, S.: 50th anniversary perspective: RAFT polymerization—a user guide. Macromolecules 50(19), 7433–7447 (2017). https://doi.org/10.1021/acs.macromol.7b00767
Pickering, S.U.: CXCVI.—Emulsions. J. Chem. Soc. Trans. 91, 2001−2021 (1907). https://doi.org/10.1039/CT9079102001
Pulko, I., Kolar, M., Krajnc, P.: Atrazine removal by covalent bonding to piperazine functionalized polyHIPES. Sci. Total Environ. 386, 114–123 (2007). https://doi.org/10.1016/j.scitotenv.2007.06.032
Pulko, I., Krajnc, P.: Open cellular reactive porous membranes from high internal phase emulsions. Chem. Commun. 4481–4483 (2008). https://doi.org/10.1039/B807095D
Pulko, I., Krajnc, P.: High internal phase emulsion templating—a path to hierarchically porous functional polymers. Macromol. Rapid Commun. 33, 1731–1746 (2012). https://doi.org/10.1002/marc.201200393
Pulko, I., Wall, J., Krajnc, P., Cameron, N.R.: Ultra-high surface area functional porous polymers by emulsion templating and hypercrosslinking: efficient nucleophilic catalyst supports. Chem. Eur. J. 16, 2350–2354 (2010). https://doi.org/10.1002/chem.200903043
Pulko, I., Smrekar, V., Podgornik, A., Krajnc, P.: Emulsion templated open porous membranes for protein purification. J. Chrom. a. 1218, 2396–2401 (2011). https://doi.org/10.1016/j.chroma.2010.11.069
Puupponen, S., Mikkola, V., Ala-Nissila, T., Seppälä, A.: Novel microstructured polyol–polystyrene composites for seasonal heat storage. Appl. Energy 172, 96–106 (2016). https://doi.org/10.1016/j.apenergy.2016.03.023
Quell, A., Bergolis, B., Drenckhan, W., Stubenrauch, C.: How the locus of initiation influences the morphology and the pore connectivity of a monodisperse polymer foam. Macromolecules 49, 5059–5067 (2016). https://doi.org/10.1021/acs.macromol.6b00494
Ramsden, W.: Separation of solids in the surface-layers of solutions and suspensions (observations on surface-membranes, bubbles, emulsions and mechanical coagulation)-preliminary account. Proc. r. Soc. Lond. 72, 156–164 (1903). https://doi.org/10.1098/rspl.1903.0034
Rao, K.M., Anbananthana, N., Rajulu, A.V.: Bicontinuous highly cross-linked poly(acrylamide-co-ethyleneglycol dimethacrylate) porous materials synthesized within high internal phase emulsions. Soft Matter 7, 10780–10786 (2011). https://doi.org/10.1039/C1SM06084H
Robinson, J.L., Moglia, R.S., Stuebben, M.C., McEnery, M.A.P., Cosgriff-Hernandez, E.: Achieving interconnected pore architecture in injectable polyHIPEs for bone tissue engineering. Tissue Eng Part A 20, 1103–11012 (2014). https://doi.org/10.1089/ten.tea.2013.0319
Rohm, K., Manas-Zloczower, I., Feke, D.: Poly(HIPE) morphology, crosslink density, and mechanical properties influenced by surfactant concentration and composition. Colloid Surf. A Physicochem. Eng. Asp. 583,(2019). https://doi.org/10.1016/j.colsurfa.2019.123913
Sanda, F., Endo, T.: Radical ring-opening polymerization. J. Polym. Sci. Part A: Polym. Chem. 39, 265–276 (2001). https://doi.org/10.1002/1099-0518(20010115)39:2<265::AID-POLA20>3.0.CO;2-D
Schwab, M.G., Senkovska, I., Rose, M., Klein, N., Koch, M., Pahnke, J., Jonschker, G., Schmitz, B., Hirscher, M., Kaskel, S.: High surface area polyHIPEs with hierarchical pore system. Soft Matter 5, 1055–1059 (2009). https://doi.org/10.1039/B815143A
Sergent, B., Birot, M., Deleuze, H.: Preparation of thiol–ene porous polymers by emulsion templating. React. Func. Polym. 72, 962–966 (2012). https://doi.org/10.1016/j.reactfunctpolym.2012.02.011
Sergienko, A.Y., Tai, H., Narkis, M., Silverstein, M.S.: Polymerized high internal-phase emulsions: properties and interaction with water. J. Appl. Polym. Sci. 84, 2018–2027 (2002). https://doi.org/10.1002/app.10555
Shen, X., Ye, L.: Interfacial molecular imprinting in nanoparticle-stabilized emulsions. Macromolecules 44, 5631–5637 (2011). https://doi.org/10.1021/ma200837n
Sherrington, D.C., Hodge, P.: Synthesis separations using functional polymers. Wiley-VCH Verlag GmbH&Co, KGaA (1988)
Silverstein, S.: Emulsion-templated porous polymers: a retrospective perspective. Polymer 55, 304–320 (2014)
Silverstein, M.S.: PolyHIPEs: recent advances in emulsion-templated porous polymers. Prog. Polym. Sci. 39, 199–234 (2014). https://doi.org/10.1016/j.progpolymsci.2013.07.003
Silverstein, M.S., Cameron, N.R.: PolyHIPEs—porous polymers from high internal phase emulsions. In: Encyclopedia of Polymer Science and Technology. Wiley, Hoboken (2010). https://doi.org/10.1002/0471440264.pst571
Song, X., Zhao, Y., Wang, H., Du, Q.: Fabrication of polymer microspheres using titania as a photocatalyst and Pickering stabilizer. Langmuir 25, 4443–4449 (2009). https://doi.org/10.1021/la8039237
Su, F., Bray, C.L., Tan, B., Cooper, A.I.: Rapid and reversible hydrogen storage in clathrate hydrates using emulsion-templated polymers. Adv. Mater. 20, 2663–2666 (2008). https://doi.org/10.1002/adma.200800550
Sušec, M., Ligon, S.C., Stampfl, J., Liska, R., Krajnc, P.: Hierarchically porous materials from layer-by-layer photopolymerization of high internal phase emulsions. Macromol. Rapid. Commun. 34, 938–943 (2013). https://doi.org/10.1002/marc.201300016
Tadros, T.F.: Emulsions formation, stability, industrial applications, De Gruyter Textbook, De Gruyter (2016). ISBN: 9783110452242
Taylor, P.: Ostwald ripening in emulsions. Colloids Surf. A Physicochem. Eng. Asp. 99, 175–185 (1995). https://doi.org/10.1016/0927-7757(95)03161-6
Teixeira, R.F.A., Bon, S.A.F.: Physical methods for the preparation of hybrid nanocomposite polymer latex particles. Adv. Polym. Sci. 233, 19–52 (2010). https://doi.org/10.1007/12_2010_65
Trupej, N., Novak, Z., Knez, Ž., Slugovc, C., Kovačič, S.: Supercritical CO2 mediated functionalization of highly porous emulsion-derived foams: ScCO2 absorption and epoxidation. J. CO2 Util. 21, 336–341 (2017). https://doi.org/10.1016/j.jcou.2017.07.024
Tsyurupa, M.P., Davankov, V.A.: Hypercrosslinked polymers: basic principle of preparing the new class of polymeric materials. React. Funct. Polym. 53, 193–203 (2002). https://doi.org/10.1016/S1381-5148(02)00173-6
Ungureanu, S., Deleuze, H., Sanchez, C., Popa, M.I., Backov, R.: First Pd@Organo-Si(HIPE) open-cell hybrid monoliths generation offering cycling heck catalysis reactions. Chem. Mater. 20, 6494−6500 (2008). https://doi.org/10.1021/cm801525c
Utroša, P., Onder, O.C., Žagar, E., Kovacič, S., Pahovnik, D.: Shape memory behavior of emulsion-templated poly(εcaprolactone) synthesized by organocatalyzed ring-opening polymerization. Macromolecules 52, 9291–9298 (2019). https://doi.org/10.1021/acs.macromol.9b01780
Vílchez, A., Rodríguez-Abreu, C., Menner, A., Bismarck, A., Esquena, J.: Antagonistic effects between magnetite nanoparticles and a hydrophobic surfactant in highly concentrated pickering emulsions. Langmuir 30, 5064–5074 (2014). https://doi.org/10.1021/la4034518
Wang, Z.J., Landfester, K., Zhang, K.A.I.: Hierarchically porous p-conjugated polyHIPE as a heterogeneous photoinitiator for free radical polymerization under visible light. Polym. Chem. 5, 3559–3562 (2014). https://doi.org/10.1039/c4py00323c
Wang, A., Paterson, T., Owen, R., Sherborne, C., Dugan, J., Li, J., Claeyssens, F.: Photocurable high internal phase emulsions (HIPEs) containing hydroxyapatite for additive manufacture of tissue engineering scaffolds with multi-scale porosity. Mater. Sci. Eng. C 67, 51–58 (2016). https://doi.org/10.1016/j.msec.2016.04.087
Weinstock, L., Sanguramath, R., Silverstein, M.S.: Encapsulating an organic phase change material within emulsion-templated poly(urethane urea)s. Polym. Chem. 10, 1498–1507 (2019). https://doi.org/10.1039/C8PY01733F
Williams, J.M.: High internal phase water-in-oil emulsions: influence of surfactants and cosurfactants on emulsion stability and foam quality. Langmuir 7, 1370–1377 (1991). https://doi.org/10.1021/la00055a014
Williams, J.M., Gray, A.J., Wilkerson, M.H.: Emulsion stability and rigid foams from styrene or divinylbenzene water-in-oil emulsions. Langmuir 6, 437–444 (1990). https://doi.org/10.1021/la00092a026
Williams, J.M., Wrobleski, D.A.: Spatial distribution of the phases in water-in-oil emulsions. Open and closed microcellular foams from cross-linked polystyrene. Langmuir 4, 656–662 (1988). https://doi.org/10.1021/la00081a027
Woodward, R.T., Fam, D.W.H., Anthony, D.B., Hong, J., McDonald, T.O., Petit, C., Shaffer, M.S.P., Bismarck, A.: Hierarchically porous carbon foams from pickering high internal phase emulsions. Carbon 101, 253–260 (2016). https://doi.org/10.1016/j.carbon.2016.02.002
Yadav, A., Pal, J., Nandan, B., Srivastava, R.K.: Macroporous scaffolds of cross-linked Poly(ɛ-caprolactone) via high internal phase emulsion templating. Polymer 176, 66–73 (2019). https://doi.org/10.1016/j.polymer.2019.05.034
Yadav, A., Erdal, N.B., Hakkarainen, M., Nandan, B., Srivastava, R.K.: Cellulose-derived nanographene oxide reinforced macroporous scaffolds of high internal phase emulsion-templated cross-linked poly(ε-caprolactone). Biomacromol 21, 589–596 (2020). https://doi.org/10.1021/acs.biomac.9b01330
Yang, T., Hu, Y., Wang, C., Binks, B.P.: Fabrication of hierarchical macroporous biocompatible scaffolds by combining Pickering high internal phase emulsion templates with three-dimensional printing. ACS Appl. Mater. Interfaces 9, 22950–22958 (2017). https://doi.org/10.1021/acsami.7b05012
Yang, S., Wang, Y., Jia, Y., Sun, X., Sun, P., Qin, Y., Li, R., Liu, H., Nie, C.: Tailoring the morphology and epoxy group content of glycidyl methacrylate-based polyHIPE monoliths via radiation-induced polymerization at room temperature. Colloid Polym. Sci. 296, 1005–1016 (2018). https://doi.org/10.1007/s00396-018-4307-x
Yang, Y., Wei, Z., Wang, C., Tong, Z.: Lignin-based Pickering HIPEs for macroporous foams and their enhanced adsorption of copper (II) ions. Chem. Commun. 49, 7144–7146 (2013). https://doi.org/10.1039/C3CC42270D
Yang, X., Yin, Z., Zhang, X., Zhu, Y., Zhang, S.: Fabrication of emulsion-templated macroporous poly(ε-caprolactone) towards highly effective and sustainable oil/water separation. Polymer 204 (2020). https://doi.org/10.1016/j.polymer.2020.122852
Yang, S., Zeng, L., Li, Z.C., Zhang, X., Liu, H., Nie, C., Liu, H.: Tailoring the morphology of emulsion-based (glycidyl methacrylate-divinylbenzene) monoliths. Eur. Polym. J. 57, 127–136 (2014). https://doi.org/10.1016/j.eurpolymj.2014.05.014
Yao, C.H., Qi, L., Jia, H.Y., Xin, P.Y., Yang, G.L., Chen, Y.: A novel glycidyl methacrylate-based monolith with sub-micron skeletons and well-defined macropores. J. Mater. Chem. 19, 767–772 (2009). https://doi.org/10.1039/B816712E
Yeşil, R., Çetinkaya, S.: Mn3O4/p(DCPD)HIPE nanocomposites as an efficient catalyst for oxidative degradation of phenol. J. Nanopart. Res. 22, 198 (2020). https://doi.org/10.1007/s11051-020-04931-6
Yi, F., Gao, Y., Li, H., Yi, L., Chen, D., Lu, S.: Nitrogen- and oxygen-codoped porous carbonaceous foam templated from high internal emulsion as PtRu catalyst support for direct methanol fuel cell. Electrochim. Acta 211, 768–776 (2016a). https://doi.org/10.1016/j.electacta.2016.06.092
Yi, W., Wu, H., Wang, H., Du, Q.: Interconnectivity of macroporous hydrogels prepared via graphene oxide-stabilized pickering high internal phase emulsions. Langmuir 32(4), 982–990 (2016b). https://doi.org/10.1021/acs.langmuir.5b04477
Yin, D., Guan, Y., Gu, H., Jia, Y., Zhang, Q.: Polymerized high internal phase emulsion monolithic material: a novel stationary phase of thin layer chromatography. RSC Adv. 7, 7303–7309 (2017). https://doi.org/10.1039/C6RA27609A
Yin, J., Zhang, T., Schulman, E., Liu, D., Meng, J.: Hierarchical porous metallized poly-melamineformaldehyde (pmf) as low-cost and high-efficiency catalyst for cyclic carbonate synthesis from CO2 and epoxides. J. Mater. Chem. A 6, 8441–8448 (2018). https://doi.org/10.1039/C8TA00625C
Yuan, W., Chen, X., Xu, Y., Yan, C., Liu, Y., Lian, W., Zhou, Y., Li, Z.: Preparation and recyclable catalysis performance of functional macroporous polyHIPE immobilized with gold nanoparticles on its surface. RSC Adv. 8, 5912–5919 (2018). https://doi.org/10.1039/C8RA00089A
Yüce, E., Krajnc, P., Mert, H.H., Mert, E.H.: Influence of nanoparticles and antioxidants on mechanical properties of titania/polydicyclopentadiene polyHIPEs: A statistical approach. J. Appl. Polym. Sci. 136, 46913 (2019). https://doi.org/10.1002/app.46913
Yüce, E., Mert, E.H., Krajnc, P., Parın, F.N., San, N., Kaya, D., Yıldırım, H.: Photocatalytic activity of titania/polydicyclopentadiene polyHIPE composites. Macromol. Mater. Eng. 302, 1700091 (2017). https://doi.org/10.1002/mame.201700091
Yüce, E., Parın, F.N., Krajnc, P., Mert, H.H., Mert, E.H.: Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites. React. Func. Polym. 130, 8–15 (2018). https://doi.org/10.1016/j.reactfunctpolym.2018.05.009
Zhang, T., Gui, H., Xu, Z., Zhao, Y.: Hydrophobic polyurethane polyHIPEs templated from mannitol within nonaqueous high internal phase emulsions for oil spill recovery. J. Polym. Sci., Part a: Polym. Chem. 57, 1315–1321 (2019a). https://doi.org/10.1002/pola.29392
Zhang, T., Sanguramath, R.A., Israel, S., Silverstein, M.S.: Emulsion templating: porous polymers and beyond. Macromolecules 52, 5445–5479 (2019b). https://doi.org/10.1021/acs.macromol.8b02576
Zhang, T., Xu, Z., Li, X., Gao, G., Zhao, Y.: Closed-cell, phase change material-encapsulated, emulsion-templated monoliths for latent heat storage: flexibility and rapid preparation. Appl. Mater. Today 21 (2020). https://doi.org/10.1016/j.apmt.2020.100831
Zheng, Z., Zheng, X., Wang, H., Du, Q.: Macroporous graphene oxide−polymer composite prepared through Pickering high internal phase emulsions. Appl. Mater. Interfaces 5, 7974–7982 (2013). https://doi.org/10.1021/am4020549
Zhou, C., Qiao, M., Zhang, X., Zhu, Y., Zhang, S., Chen, J.: Production of high internal phase emulsion with a miniature twin screw extruder. ACS Omega 4, 9957–9963 (2019). https://doi.org/10.1021/acsomega.9b01156
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Mert, H.H., Mert, E.H. (2022). Emulsion Templated Hierarchical Macroporous Polymers. In: Uthaman, A., Thomas, S., Li, T., Maria, H. (eds) Advanced Functional Porous Materials. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-85397-6_3
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