Skip to main content

A Review on Ammonia Derivatives as Corrosion Inhibitors for Metals and Alloys

  • Chapter
  • First Online:
Sustainable Ammonia Production

Abstract

Nowadays, metallic corrosion is one of the most challenging and damaging phenomena that is associated with huge economic and safety losses. The corrosion damages become more severe during some industrial cleaning processes where metallic materials are allowed for their surface treatment for their further processing and applications. Therefore, corrosion inhibitors, mostly organic compounds are employed during these processes. Most of the investigated inhibitors are associated with salient features, including the presence of heteroatoms (N, S, O, P, etc.) and aliphatic chains and aromatic rings. Generally, organic inhibitors adsorb and form defensive film that isolates the metal(s) from surrounding corrosive environment and protect from corrosion. Literature survey reveals that ammonia derivatives are highly used in almost all kinds of electrolytic media. Aliphatic and aromatic amines, amino acids, hydrazine and phenylhydrazine and their derivatives are most frequently used ammonia derivatives as corrosion inhibitors. Present chapter dealing with the collection of few major reports available on the topic “ammonia derivatives as corrosion inhibitors.” Amino acids (AAs) can also be regarded as mono-substituted amines; therefore, present chapter also includes literature available on AAs as corrosion inhibitors.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 129.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 159.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Mansor N, Abdullah S, Ariffin A, Syarif J (2014) A review of the fatigue failure mechanism of metallic materials under a corroded environment. Eng Fail Anal 42:353–365

    Article  CAS  Google Scholar 

  2. Gupta RK, Malviya M, Verma C, Quraishi M (2017) Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: experimental and DFT studies. Mater Chem Phys 198:360–373

    Article  CAS  Google Scholar 

  3. Verma C, Ebenso EE, Quraishi M (2017) Ionic liquids as green and sustainable corrosion inhibitors for metals and alloys: an overview. J Mol Liq 233:403–414

    Article  CAS  Google Scholar 

  4. Zaferani SH, Sharifi M, Zaarei D, Shishesaz MR (2013) Application of eco-friendly products as corrosion inhibitors for metals in acid pickling processes–a review. J Environ Chem Eng 1:652–657

    Article  CAS  Google Scholar 

  5. Emregül KC, Akay AA, Atakol O (2005) The corrosion inhibition of steel with Schiff base compounds in 2 M HCl. Mater Chem Phys 93:325–329

    Article  CAS  Google Scholar 

  6. Verma C, Olasunkanmi LO, Ebenso EE, Quraishi MA, Obot IB (2016) Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: experimental and theoretical studies. J Phys Chem C 120:11598–11611

    Article  CAS  Google Scholar 

  7. de Chialvo MG, Chialvo A (1998) Kinetics of hydrogen evolution reaction with Frumkin adsorption: re-examination of the Volmer-Heyrovsky and Volmer-Tafel routes. Electrochim Acta 44:841–851

    Article  Google Scholar 

  8. de Chialvo MG, Chialvo A (1999) The Tafel-Heyrovsky route in the kinetic mechanism of the hydrogen evolution reaction. Electrochem Commun 1:379–382

    Article  Google Scholar 

  9. Verma C, Olasunkanmi L, Ebenso EE, Quraishi M (2018) Substituents effect on corrosion inhibition performance of organic compounds in aggressive ionic solutions: a review. J Mol Liq 251:100–118

    Article  CAS  Google Scholar 

  10. Sastri VS (2012) Green corrosion inhibitors: theory and practice. John Wiley & Sons

    Google Scholar 

  11. Al-Sabagh AM, Nasser NM, Farag AA, Migahed MA, Eissa AM, Mahmoud T (2013) Structure effect of some amine derivatives on corrosion inhibition efficiency for carbon steel in acidic media using electrochemical and quantum theory methods. Egypt J Pet 22:101–116

    Article  Google Scholar 

  12. Babić-Samardžija K, Khaled K, Hackerman N (2005) N-heterocyclic amines and derivatives as corrosion inhibitors for iron in perchloric acid. Anti-Corros Methods Mater 52:11–21

    Article  CAS  Google Scholar 

  13. Yadav M, Kumar S, Sharma U, Yadav P (2013) Substituted amines as corrosion inhibitors for N80 steel in 15% HCl. J Mater Environ Sci 4:691–700

    CAS  Google Scholar 

  14. Alsabagh A, Migahed M, Awad HS (2006) Reactivity of polyester aliphatic amine surfactants as corrosion inhibitors for carbon steel in formation water (deep well water). Corros Sci 48:813–828

    Article  CAS  Google Scholar 

  15. Rihan R, Shawabkeh R, Al-Bakr N (2014) The effect of two amine-based corrosion inhibitors in improving the corrosion resistance of carbon steel in sea water. J Mater Eng Perform 23:693–699

    Article  CAS  Google Scholar 

  16. De Damborenea J, Bastidas J, Vazquez A (1997) Adsorption and inhibitive properties of four primary aliphatic amines on mild steel in 2 M hydrochloric acid. Electrochim Acta 42:455–459

    Article  Google Scholar 

  17. Herrag L, Bouklah M, Patel N, Mistry B, Hammouti B, Elkadiri S, Bouachrine M (2012) Experimental and theoretical study for corrosion inhibition of mild steel 1 M HCl solution by some new diaminopropanenitrile compounds. Res Chem Intermed 38:1669–1690

    Article  CAS  Google Scholar 

  18. Migahed M, Attia A, Habib R (2015) Study on the efficiency of some amine derivatives as corrosion and scale inhibitors in cooling water systems. RSC Adv 5:57254–57262

    Article  CAS  Google Scholar 

  19. Fouda A, Abdallah M, Ahmed I, Eissa M (2012) Corrosion inhibition of aluminum in 1 M H3PO4 solutions by ethanolamines. Arab J Chem 5:297–307

    Article  CAS  Google Scholar 

  20. Mahida M, Chaudhari H (2012) Aromatic amines as corrosion inhibitors for zinc in hydrochloric acid. J Chem Pharm Res 4:5195–5201

    Google Scholar 

  21. Topal E, Gece G (2017) Untangling the inhibition effects of aliphatic amines on silver corrosion: a computational study. Chem J Moldova 12:64–70

    Article  CAS  Google Scholar 

  22. El Wanees SA, El Aal Mohamed AA, El Azeem MA, El Said R (2010) Inhibition of silver corrosion in nitric acid by some aliphatic amines. J Dispers Sci Technol 31(11):1516–1525

    Google Scholar 

  23. Verma C, Quraishi M, Kluza K, Makowska-Janusik M, Olasunkanmi LO, Ebenso EE (2017) Corrosion inhibition of mild steel in 1 M HCl by D-glucose derivatives of dihydropyrido [2, 3-d: 6, 5-d′] dipyrimidine-2, 4, 6, 8 (1H, 3H, 5H, 7H)-tetraone. Sci Rep 7:44432

    Article  CAS  Google Scholar 

  24. Antonijevic M, Petrovic M (2008) Copper corrosion inhibitors. A review, Int J Electrochem Sci 3(2008):1–28

    Google Scholar 

  25. Goyal M, Kumar S, Bahadur I, Verma C, Ebenso EE (2018) Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: a review. J Mol Liq 256:565–573

    Article  CAS  Google Scholar 

  26. Henríquez-Román JH, Padilla-Campos L, Páez MA, Zagal JH, Rubio MA, Rangel CM, Costamagna J, Cárdenas-Jirón G (2005) The influence of aniline and its derivatives on the corrosion behaviour of copper in acid solution: a theoretical approach. J Mol Struct (Thoechem) 757:1–7

    Article  CAS  Google Scholar 

  27. Ayobe EA, Abaza SF, Seleim SM, Ahmed AMM (2012) Anodic corrosion of copper in presence of aniline derivatives

    Google Scholar 

  28. Eldesoky A, El-Bindary M, El-Sonbati A, Morgan SM New eco-friendly corrosion inhibitors based on azo rhodanine derivatives for protection copper corrosion

    Google Scholar 

  29. Nasser R (2017) Investigation of the behavior of aminated jojoba derivatives as green corrosion inhibitors for mild steel at 0.5 N HCl. Der Chem Sinica 8(2017):123–132

    Google Scholar 

  30. Donya A, Pakter M, Shalimova M, Lambin V (2002) The effect of polar substituents in aniline and pyridine derivatives on the inhibition of steel corrosion in acids. Prot Met 38:216–219

    Article  CAS  Google Scholar 

  31. El-Haddad MN, Fouda AE-AS (2013) Corrosion inhibition effect and adsorption of aniline derivatives on QD36 steel surface in acidic solution. Protection of Metals and Phys Chem Surfaces 49:753–762

    Article  CAS  Google Scholar 

  32. Belghiti M, Bouazama S, Echihi S, Mahsoune A, Elmelouky A, Dafali A, Emran K, Hammouti B, Tabyaoui M (2017) Understanding the adsorption of newly benzylidene-aniline derivatives as a corrosion inhibitor for carbon steel in hydrochloric acid solution: experimental, DFT and molecular dynamic simulation studies. Arab J Chem

    Google Scholar 

  33. Prabhu R, Venkatesha T, Shanbhag A, Kulkarni G, Kalkhambkar R (2008) Inhibition effects of some Schiff’s bases on the corrosion of mild steel in hydrochloric acid solution. Corros Sci 50:3356–3362

    Article  CAS  Google Scholar 

  34. Hayaoui M, Drissi M, Fahim M, Salim R, Rais Z, Mouffarih S, Baba MF, El Hajjaji F, Zarrouk A, Taleb M (2017) Benzenamine derivative as corrosion inhibitor of carbon steel in hydrochloric acid solution: electrochemical and theoretical studies. J Mater Environ Sci 8:1877

    CAS  Google Scholar 

  35. Ashassi-Sorkhabi H, Shabani B, Aligholipour B, Seifzadeh D (2006) The effect of some Schiff bases on the corrosion of aluminum in hydrochloric acid solution. Appl Surf Sci 252:4039–4047

    Article  CAS  Google Scholar 

  36. Kumar S, Ladha D, Shah N Adsorption behaviour, thermodynamic and electrochemical studies of chloro derivatives of N-(4-methoxybezylidene) aniline as corrosion inhibitors for zinc in hydrochloric acid

    Google Scholar 

  37. Kumar S, Ladha D, Jha P, Shah N (2013) Theoretical study of chloro-N-(4-methoxybenzylidene) aniline derivatives as corrosion inhibitors for zinc in hydrochloric acid. Int J Corros 2013

    Google Scholar 

  38. Vashi R, Desai K Aniline as corrosion inhibitor for zinc in hydrochloric acid

    Google Scholar 

  39. El Azzouzi M, Aouniti A, Tighadouin S, Elmsellem H, Radi S, Hammouti B, El Assyry A, Bentiss F, Zarrouk A (2016) Some hydrazine derivatives as corrosion inhibitors for mild steel in 1.0 M HCl: weight loss, electrochemical, SEM and theoretical studies. J Mol Liq 221:633–641

    Google Scholar 

  40. Belghiti M, Tighadouini S, Karzazi Y, Dafali A, Hammouti B, Radi S, Solmaz R (2016) New hydrazine derivatives as corrosion inhibitors for mild steel protection in phosphoric acid medium. Part A: Exp Study, J Mater Environ Sci 7(2007):337–346

    CAS  Google Scholar 

  41. Chafai N, Chafaa S, Benbouguerra K, Hellal A, Mehri M (2019) Synthesis, spectral analysis, anti-corrosive activity and theoretical study of an aromatic hydrazone derivative. J Mol Struct 1181:83–92

    Article  CAS  Google Scholar 

  42. Abdallah M, Al-Agez M, Fouda A (2009) Phenylhydrazone derivatives as corrosion inhibitors for-α-brass in hydrochloric acid solutions. Int J Electrochem Sci 4:336–352

    CAS  Google Scholar 

  43. Quraishi MA, Jamal D, Singh RN (2001) Inhibition of mild steel corrosion in the presence of fatty acid thiosemicarbazides. Corrosion 28:201–207

    Google Scholar 

  44. Kandemirli F, Sagdinc S (2007) Theoretical study of corrosion inhibition of amides and thiosemicarbazones. Corros Sci 49:2118–2130

    Article  CAS  Google Scholar 

  45. Goulart CM, Esteves-Souza A, Martinez-Huitle CA, Rodrigues CJF, Maciel MAM, Echevarria A (2013) Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors. Corros Sci 67:281–291

    Article  CAS  Google Scholar 

  46. Mahgoub FM, Al-Rashdi SM (2016) Investigate the corrosion inhibition of mild steel in sulfuric acid solution by thiosemicarbazide. Open J Phys Chem 6:54–66

    Article  CAS  Google Scholar 

  47. Ameer MA, Khamis E, Al-Senani G (2000) Adsorption studies of the effect of thiosemicarbazides on the corrosion of steel in phosphoric acid. Adsorpt Sci Technol 18:177–194

    Article  CAS  Google Scholar 

  48. El-Shafei AA, Moussa MNH, El-Far AA (2001) The corrosion inhibition character of thiosemicarbazide and its derivatives for C-steel in hydrochloric acid solution. Mater Chem Phys 70:175–180

    Article  CAS  Google Scholar 

  49. Ramya K, Mohan R, Anupama KK, Joseph A (2015) Electrochemical and theoretical studies on the synergistic interaction and corrosion inhibition of alkyl benzimidazoles and thiosemicarbazide pair on mild steel in hydrochloric acid. Mater Chem Phys 149–150:632–647

    Article  CAS  Google Scholar 

  50. Musa∗ AY, Kadhum AAH, Mohamad AB, Takriff MS (2011) Molecular dynamics and quantum chemical calculation studies on 4,4-dimethyl-3-thiosemicarbazide as corrosion inhibitor in 2.5 M H2SO4. Mater Chem Phys 129:660–665

    Google Scholar 

  51. Badr GE (2009) The role of some thiosemicarbazide derivatives as corrosion inhibitors for C-steel in acidic media. Corros Sci 51:2529–2536

    Article  CAS  Google Scholar 

  52. Ebenso EE, Isabirye DA, Eddy NO (2010) Adsorption and quantum chemical studies on the inhibition potentials of some thiosemicarbazides for the corrosion of mild steel in acidic medium. Int J Mol Sci 11:2473–2498

    Article  CAS  Google Scholar 

  53. Mohan P, Kalaignan GP (2013) 1, 4-Bis (2-nitrobenzylidene) thiosemicarbazide as effective corrosion inhibitor for mild steel. J Mater Sci Technol 29(11):1096–1100

    Article  CAS  Google Scholar 

  54. Shahabi S, Norouzi P, Ganjali MR (2015) Electrochemical and theoretical study of the inhibition effect of two synthesized thiosemicarbazide derivatives on carbon steel corrosion in hydrochloric acid solution. RSC Adv 5:20838–20847

    Article  CAS  Google Scholar 

  55. Wazzan NA (2015) DFT calculations of thiosemicarbazide, arylisothiocynates, and 1-aryl-2,5-dithiohydrazodicarbonamides as corrosion inhibitors of copper in an aqueous chloride solution. J Indus Eng Chem 26:291–308

    Article  CAS  Google Scholar 

  56. Ita BI, Offiong OE (1999) Corrosion inhibitory properties of 4-phenylsemicarbazide and semicarbazide on mild steel in hydrochloric acid. Mater Chem Phys 59:179–184

    Article  CAS  Google Scholar 

  57. Fouda AS, Madkour LH, Elshafei AA, Elasklany AH (1995) Inhibitory effect of some carbazides on corrosion of aluminium in hydrochloric acid and sodium hydroxide solutions. Mat-wiss u Werkstofftech 26:342–346

    Article  CAS  Google Scholar 

  58. Ramya K, Anupama KK, Shainy KM, Joseph A (2017) Corrosion protection of mild steel in hydrochloric acid solution through the synergistic of alkylbenzimidazoles and semicarbazide pair—electroanalytical and computational studies. Egypt J Pet 26:421–437

    Article  Google Scholar 

  59. Al-Bonayan AM (2015) Inhibiting effect of thiosemicarbazide and 4-phenyl thiosemicarbazide towards the corrosion of carbon steel in H3PO4 solutions. Int J Electrochem Sci 10:589–601

    CAS  Google Scholar 

Download references

Acknowledgements

Dr. Chandrabhan Verma, thankfully acknowledges the North-West University South Africa for providing financial support under post doctor scheme.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chandrabhan Verma .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Verma, C., Quraishi, M.A., Ebenso, E.E. (2020). A Review on Ammonia Derivatives as Corrosion Inhibitors for Metals and Alloys. In: Inamuddin, Boddula, R., Asiri, A. (eds) Sustainable Ammonia Production. Green Energy and Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-35106-9_3

Download citation

  • DOI: https://doi.org/10.1007/978-3-030-35106-9_3

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-35105-2

  • Online ISBN: 978-3-030-35106-9

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics