Skip to main content

Threshold Switching in Chalcogenide-Glass Thin Films

  • Chapter
Disordered Materials

Part of the book series: Institute for Amorphous Studies Series ((IASS))

  • 450 Accesses

Abstract

The application of sufficiently high electric fields to any material eventually results in deviations from linearity in the observed current-voltage I(V) characteristic. There are two general classes of explanations for such non-Ohmic effects— thermal and electronic. Thermal effects arise because the electrons accelerated by the field always emit phonons in an attempt to return to equilibrium. Electronic effects are due to changes in the response of the charged carriers to high applied fields. In general, both effects must be considered in any quantitative analysis, and the two can produce a coupled response ofter called “electrothermal.” The use of the terminology electrothermal encompasses predominantly thermal and predominantly electronic processes as well as all intermediate cases, and therefore should not prejudice the casual observer into concluding that both effects are necessarily important. In a discussion of the physical mechanism in a particular sample, the major parameters controlling its operation must be identified and separated out from the less significant features.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. S.R. Ovshinsky, Phys. Rev. Lett. 21, 1450 (1968).

    Article  ADS  Google Scholar 

  2. For comprehensive reviews of the extensive work done prior to 1971, see D. Adler, Amorphous Semiconductors (CRC Press, Cleveland, 1971), p. 96

    Google Scholar 

  3. H. Fritzsche, in Amorphous and Liquid Semiconductors, edited by J. Tauc (Plenum, New York, 1974), p. 313. For a more recent review

    Chapter  Google Scholar 

  4. D. Adler, H.K. Henisch, and N.F. Mott, Rev. Mod. Phys. 50, 209 (1978).

    Article  ADS  Google Scholar 

  5. D. Adler, in Amorphous and Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 695

    Google Scholar 

  6. H. Fritzsche and S.R. Ovshinsky, J. Non-Cryst. Solids 2, 393 (1970).

    Article  ADS  Google Scholar 

  7. M.P. Shaw, H.L. Grubin, and I.J. Gastman, IEEE Trans. Educ. ED-20, 169 (1973).

    Google Scholar 

  8. B.K. Ridley, Proc. Phys. Soc. 82, 954 (1963)

    Article  ADS  Google Scholar 

  9. H.K. Rockstad, and M.P. Shaw, IEEE Trans. Educ. ED-20, 593 (1973).

    Google Scholar 

  10. K.E. Petersen and D. Adler, J. Appl. Phys. 47, 256 (1976).

    Article  ADS  Google Scholar 

  11. R.W. Pryor and H.K. Henisch, J. Non-Cryst. Solids 7, 181 (1972).

    Article  ADS  Google Scholar 

  12. M.P. Shaw, S.H. Holmberg, and S.A. Kostylev, Phys. Rev. Lett. 31, 542 (1973).

    Article  ADS  Google Scholar 

  13. W.D. Buckley and S.H. Holmberg, Solid State Electron. 18, 127 (1975).

    Article  ADS  Google Scholar 

  14. D.K. Reinhard, D. Adler, and F.O. Arntz, J. Appl. Phys. 47, 1560 (1976).

    Article  ADS  Google Scholar 

  15. E.J. Yoffa and D. Adler, Phys. Rev. B 15, 2311 (1977).

    ADS  Google Scholar 

  16. B.P. Mathur, Ph.D. thesis, MIT, 1973.

    Google Scholar 

  17. F.A. Padovani and R. Stratton, Solid State Electron. 9, 695 (1966).

    Article  ADS  Google Scholar 

  18. K. Subhani, M.S. Shur, M.P. Shaw, and D. Adler, in Amorphous and Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 712.

    Google Scholar 

  19. D.K. Reinhard, F.O. Arntz, and D. Adler, Appl. Phys. Lett. 23, 521 (1973).

    Article  ADS  Google Scholar 

  20. H.K. Henisch, W.R. Smith, and W. Wihl, in Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London, 1974), p. 567.

    Google Scholar 

  21. K. Homma, Appl. Phys. Lett. 18, 198 (1971).

    Article  ADS  Google Scholar 

  22. M.P. Shaw, S.C. Moss, S.A. Kostylev, and L.H. Slack, Appl. Phys. Lett. 22, 114 (1973).

    Article  ADS  Google Scholar 

  23. M.P. Shaw and I.J. Gastman, Appl. Phys. Lett. 19, 243 (1971)

    Article  ADS  Google Scholar 

  24. M.P. Shaw and I.J. Gastman, J. Non-Cryst. Solids 8–10, 999 (1972).

    Article  Google Scholar 

  25. R.R. Shanks, J. Non-Cryst. Solids 2, 505 (1970).

    Article  ADS  Google Scholar 

  26. K.E. Petersen, D. Adler, and M.P. Shaw, IEEE Trans. Educ. ED-23, 471 (1976).

    ADS  Google Scholar 

  27. K.E. Petersen and D. Adler, Appl. Phys. Lett. 25, 211 (1974).

    Article  ADS  Google Scholar 

  28. R.C. Frye, D. Adler, and M.P. Shaw, J. Appl. Phys. 50 (1979).

    Google Scholar 

  29. P.J. Walsh, S. Ishioka, and D. Adler, Appl. Phys. Lett. 33, 593 (1978).

    Article  ADS  Google Scholar 

  30. K.B. Ma, J. Non-Cryst. Solids 24, 345 (1977).

    Article  ADS  Google Scholar 

  31. D. Adler and L.P. Flora, in Amorphous & Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London, 1974), p. 1407.

    Google Scholar 

  32. A.J. Hughes, P.A. Holland, and A.H. Lettington, J. Non-Cryst. Solids 17, 89 (1975).

    Article  ADS  Google Scholar 

  33. K.E. Petersen and D. Adler in Amorphous & Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 707

    Google Scholar 

  34. K.E. Petersen and D. Adler, J. Appl. Phys. 50, C.I.C.L. (1979).

    Google Scholar 

  35. K. Homma, H.K. Henisch, and S.R. Ovshinsky, J. Non-Cryst. Solids, 35/36, 1105 (1980).

    Article  Google Scholar 

  36. J.J. Hauser, F.J. DiSalvo, Jr., and R.S. Hutton, Philos. Mag. 35, 1557 (1977).

    Article  ADS  Google Scholar 

  37. P.W. Anderson, Phys. Rev. Lett. 34, 953 (1975).

    Google Scholar 

  38. R.A. Street and N.F. Mott, Phys. Rev. Lett. 35, 1293 (1975).

    Article  ADS  Google Scholar 

  39. S.G. Bishop, U. Strom, and P.C. Taylor, Phys. Rev. Lett. 34, 1346 (1975).

    Article  ADS  Google Scholar 

  40. M. Kastner, Phys. Rev. Lett. 28, 355 (1972).

    Article  ADS  Google Scholar 

  41. D. Adler, Sci. Am. 236, 36 (1977)

    Article  ADS  Google Scholar 

  42. K.L. Ngai, T.L. Reinecke, and E.N. Economou, Phys. Rev. B 17, 790 (1978); D. Adler and M. Kastner, (unpublished).

    ADS  Google Scholar 

  43. S.R. Ovshinsky and K. Sapru, in Amorphous and Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London, 1974), p. 447.

    Google Scholar 

  44. S.R. Ovshinsky, Phys. Rev. Lett. 36, 1469 (1976).

    Article  ADS  Google Scholar 

  45. M. Kastner, D. Adler, and H. Fritzsche, Phys. Rev. Lett. 37, 1504 (1976).

    Article  ADS  Google Scholar 

  46. D. Adler and E.J. Yoffa, Can. J. Chem. 55, 1920 (1977).

    Article  Google Scholar 

  47. D. Adler, J. Non-Cryst. Solids 35/36, 819 (1980)

    Google Scholar 

  48. M. Kastner and H. Fritzsche, Philos. Mag. 37B, 199 (1978).

    Google Scholar 

  49. M. Abkowitz and D.M. Pai, Phys. Rev. Lett. 38, 1412 (1977).

    Article  ADS  Google Scholar 

  50. D. Adler and E.J. Yoffa, Phys. Rev. Lett. 36, 1197 (1976).

    Article  ADS  Google Scholar 

  51. A.M. Barnett, IBM J. Res. Dev. 13, 522 (1969).

    Article  Google Scholar 

  52. I. Melngailis and A.G. Milnes, J. Appl. Phys. 33, 995 (1962).

    Article  ADS  Google Scholar 

  53. B.L. Gelmont and M.S. Shur, J. Phys. D 6, 842 (1973).

    ADS  Google Scholar 

  54. A. Blicher, Thyristor Physics (Springer-Verlag, New York, 1976).

    Book  Google Scholar 

  55. I.V. Varlamov and V.V. Osipov, Sov. Phys.-Semicond. 3, 893 (1970)

    Google Scholar 

  56. I.V. Varlamov, V.V. Osipov, and E.A. Poltoratskii, (lap)ibid, Sov. Phys.-Semicond. 3, (1970) 978.

    Google Scholar 

  57. See, for example, M.P. Shaw, H.L. Grubin, and P.R. Solomon, The Gunn-Hilsum Effect (Academic, New York, 1979).

    Google Scholar 

  58. P.N. Butcher, Rep. Prog. Phys. 30, 97 (1967)

    Article  ADS  Google Scholar 

  59. B.W. Knight and G.A. Peterson, Phys. Rev. 155, 393 (1967).

    Article  ADS  Google Scholar 

  60. D.L. Thomas and J.C. Male, J. Non-Cryst. Solids 8–10, 522 (1972).

    Article  Google Scholar 

  61. C. Popescu and N. Croitoru, J. Non-Cryst. Solids 8–10, 531 (1972).

    Article  Google Scholar 

  62. T. Kaplan and D. Adler, J. Non-Cryst. Solids 8–10, 538 (1972).

    Article  Google Scholar 

  63. D.N. Knoll and M.H. Cohen, J. Non-Cryst. Solids 8–10, 544 (1972).

    Google Scholar 

  64. S.H. Holmberg and M.P. Shaw in Amorphous & Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London, 1974), p. 687.

    Google Scholar 

  65. D.K. Reinhard, D. Adler, and F.O. Arntz in Amorphous & Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London, 1974), p. 745.

    Google Scholar 

  66. H. Wey, Phys. Rev. B 13, 3495 (1976).

    ADS  Google Scholar 

  67. W.H. Weber and G.W. Ford, Solid State Electron 13, 1333 (1970).

    Article  ADS  Google Scholar 

  68. S.R. Ovshinsky, Proc. 6th Int. conf. Amorphous & Liquid Semiconductors, edited by B.T. Kolomeits (Nauka, Leningrad, U.S.S.R., 1976), p. 426.

    Google Scholar 

  69. M.P. Shaw, Handbook of Semiconductors (North-Hollnad, Amsterdam, 1979), Vol. 4, Chap. 1.

    Google Scholar 

  70. J.B. Gunn, Proc. Phys. Soc. 69, 781 (1956).

    Article  ADS  Google Scholar 

  71. J.B. Gunn, Proc. Phys. Soc. 8-B, 781 (1956).

    ADS  Google Scholar 

  72. M.C. Steele, H. Ando, and M.A. Lampert, J. Phys. Soc. Jpn. 17, 1729 (1962).

    Article  ADS  Google Scholar 

  73. H.K. Henisch, Sci. Am. 221, 2 (1969).

    Article  Google Scholar 

  74. H.K. Henisch, E.A. Fagen, and S.R. Ovshinsky, J. Non-Cryst. Solids 4, 538 (1979).

    Article  Google Scholar 

  75. N.F. Mott, Philos. Mag. 26, 1015 (1972);

    Article  ADS  Google Scholar 

  76. N.F. Mott, Philos. Mag. 32, 159 (1975).

    Article  ADS  Google Scholar 

  77. I. Lucas, J. Non-Cryst. Solids 6, 136 (1971).

    Article  ADS  Google Scholar 

  78. H. Haberland, Solid State Electron. 13, 207 (1970).

    Article  ADS  Google Scholar 

  79. P.J. Walsh and G.C. Vezzoli, in Amorphous & Liquid Semiconductors, edited by J. Stuke and W. Brenig (Taylor & Francis, London 1974), p. 1391.

    Google Scholar 

  80. K.W. Boer and R. Haislip, Phys. Rev. Lett. 29, 230 (1970).

    Article  ADS  Google Scholar 

  81. W. van Roosbroeck and H.C. Casey, Jr., Phys. Rev. B 5, 2154 (1972).

    ADS  Google Scholar 

  82. C. Popescu and H.K. Henisch, Phys. Rev. B 11, 1563 (1975).

    ADS  Google Scholar 

  83. B.D. Rodgers, C.B. Thomas, and H.S. Reehal, Philos, Mag. 31, 1013 (1976).

    Article  ADS  Google Scholar 

  84. S.H. Lee, H.K. Henisch, and W.D. Burgess, J. Non-Cryst. Solids 8–10, 422 (1972).

    Article  Google Scholar 

  85. R. Callarotti and P. Schmidt, in Amorphous & Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 717.

    Google Scholar 

  86. D. Allsopp, M.J. Thompson, and J. Allison, in Amorphous & Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 732.

    Google Scholar 

  87. J.M. Mackowski, J.P. Thomas, P. Kumurdjian, and J. Tousset, in Amorphous & Liquid Semiconductors, edited by W.E. Spear, (C.I.C.L., Edinburgh, Scotland, 1977), p. 570.

    Google Scholar 

  88. S.R. Ovshinsky, Proc. 4th Int. Congress for Reprographie and Information, Hanover, Germany, 1975 (unpublished).

    Google Scholar 

  89. This argument was developed with the assistance of R. Flasck.

    Google Scholar 

  90. M.J. Thomson, J. Allison, and S.R. Jones, in Amorphous & Liquid Semiconductors, edited by W.E. Spear (C.I.C.L., Edinburgh, Scotland, 1977), p. 727.

    Google Scholar 

  91. W.E. Spear and P.G. LeComber, Solid State Commun. 17, 1193 (1975).

    Article  ADS  Google Scholar 

  92. W. Paul, A.J. Lewis, G.A.N. Connell, and T.D. Moustakas, Solid State Commun. 20, 969 (1976).

    Article  ADS  Google Scholar 

  93. C. Kittel, Introduction to Solid State Physics (Wiley, New York, 1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Plenum Press, New York

About this chapter

Cite this chapter

Adler, D., Shur, M.S., Silver, M., Ovshinsky, S.R. (1991). Threshold Switching in Chalcogenide-Glass Thin Films. In: Adler, D., Schwartz, B.B., Silver, M. (eds) Disordered Materials. Institute for Amorphous Studies Series. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8745-9_16

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-8745-9_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8747-3

  • Online ISBN: 978-1-4684-8745-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics