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Physicochemical Studies of Crown and Cryptate Complexes

  • Chapter
Coordination Chemistry of Macrocyclic Compounds

Abstract

For many years coordination chemistry of alkali metal ions was completely ignored by chemists. Indeed, there was strong doubt that such coordination chemistry could even exist since it was universally accepted that the alkali ions in solutions were quite inert, i.e., they were highly resistant to solvolytic, redox, or complexation reactions. In fact, many studies of the more glamorous transition-metal complexes in solutions were often carried out in the presence of large concentrations of alkali salts so as to maintain a “constant ionic strength.” In most cases no thought was given to the possibility that a competitive formation of an alkali ion complex may also take place.

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Authors and Affiliations

  1. Department of Chemistry, Michigan State University, East Lansing, Michigan, USA

    Alexander I. Popov

  2. Department of Chemistry, Universitä Louis Pasteur de Strasbourg, Strasbourg, France

    Jean-Marie Lehn

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  1. Alexander I. Popov
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  2. Jean-Marie Lehn
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  1. Virginia Commonwealth University, Richmond, Virginia, USA

    Gordon A. Melson

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© 1979 Plenum Press, New York

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Popov, A.I., Lehn, JM. (1979). Physicochemical Studies of Crown and Cryptate Complexes. In: Melson, G.A. (eds) Coordination Chemistry of Macrocyclic Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2928-2_9

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  • DOI: https://doi.org/10.1007/978-1-4613-2928-2_9

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