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Hydrogen Production from Ammonia as an Environmentally Benign Solution for Vehicles

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Global Warming

Part of the book series: Green Energy and Technology ((GREEN))

Since historical times mankind is dependent on the use of fossil fuels. The exploitation and use of fossil fuel grew exponentially in the last two centuries when world experienced the industrial development. This period was characterized by extensive combustion of petroleum, natural gas, coal and as a consequence there are produced visible unbalances in the natural environment, especially due to the associated CO2 emissions.

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References

  • Blarigan, BV (2000) Advanced Internal Combustion Engine Research. Proceedings of the DOE Hydrogen Program Review, NREL/CP-570-28890.

    Google Scholar 

  • Bomelburg, HJ (1982) Use of ammonia in energy-related applications. Plant/Operations Progress 1:175–180.

    Google Scholar 

  • Brandhorst, H, Tartachuk, B, Cahlea, D, Barron, T, Baltazar-Lopez, M (2007) Ammonia transformation and utilization. Proceedings of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. Published online at http://www.energy.iastate.edu/Renewable/ammonia/ammonia/ammoniaMtg07.htm.

  • Cairns EJ, Simons EL, Tevebauch AD (1968) Ammonia-oxygen fuel cell. Nature 217:780–781.

    Article  Google Scholar 

  • Christensen, CH, Johannessen, T, Sorensen, RZ, Norskov, JK (2006) Towards an ammonia-mediated hydrogen economy? Catalysis Today 111:140–144.

    Article  Google Scholar 

  • Colonna, P, a Van der Stelt, TP (2004) FluidProp: a program for the estimation of thermo physical properties of fluids, Energy Technology Section, Delft University of Technology, The Netherlands. Published online at www.FluidProp.com.

  • Dincer, I (2007) Environmental and sustainability aspects of hydrogen and fuel cell systems, International Journal of Energy Research 31:29–55.

    Article  Google Scholar 

  • Dincer, I, Zamfirescu, C (2009) Methods and apparatus for using ammonia as sustainable fuel, refrigerant and NOx reduction agent. US Patent 61/064,133.

    Google Scholar 

  • DOE (2008) DOE Announces New Hydrogen Cost Goal. Published online at http://www1. eere.energy.gov/hydrogenandfuelcells/news_cost_goal.html (accessed on April 1, 2008).

  • Ford Focus (2008) H2ICE Ford Focus. Internet source http://media.ford.com/ article_display.cfm?article_id=16375 (accessed on February 4, 2008).

  • Ganley, JC, Seebauer, EG, Masel, RI (2004) Development of a microreactor for the production of hydrogen from ammonia. Journal of Power Sources 137:53–61.

    Google Scholar 

  • Holbroock J (2007) Wrap-up/Ammonia and the clean energy portfolio. Proceedings of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. published online at http://www.energy.iastate.edu/Renewable/ ammonia/ ammonia/ammoniaMtg07.htm.

  • IG (2008) Hydrogen. The innovation group. Published online at http://www.the-innovation-group.com/ChemProfiles/Hydrogen.htm (accessed on April 1, 2008).

  • Kordesh, K, Aronsson, RR, Kalal, P, Hacker, V, Faleschini, G (2007) Hydrogen from cracked ammonia for alkaline fuel cell – rechargeable battery and ICE vehicles. Proceeding of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. Published online at http://www.energy.iastate.edu/ Renewable/ammonia/ ammonia/ammoniaMtg07.htm.

  • Kroch, E (1945) Ammonia – a fuel for motor buses. Journal of the Institute of Petroleum 31:213–223.

    Google Scholar 

  • Lide, DR (1991) CRC Handbook of Chemistry and Physics, 72nd edition, CRC Press, Boca Raton, Florida.

    Google Scholar 

  • Maffei, N, Pelletier, L, Charland, JP, McFarlan, A (2007) A Direct Ammonia Fuel Cell Using Barium Cerate Proton Conducting Electrolyte Doped With Gadolinium and Praseodymium. Fuel Cells 4:323–328.

    Article  Google Scholar 

  • McFarlan, A (2007) Development of Direct Ammonia Fuel Cells for Efficient Stationary CHP Applications. Proceedings of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. Published online at http://www.energy.iastate.edu/Renewable/ammonia/ammonia/ammoniaMtg07.htm.

  • NIST (2008) Chemistry Webbook. Published online at http://webbook.nist.gov/chemistry/ (accessed on February 24, 2008).

  • NRC-NAE (2004) The hydrogen economy – opportunities, costs, barriers and R&D needs. National Research Council and National Academy of Engineering. The National Academic Press. Washington DC, p. 256.

    Google Scholar 

  • Olson, N (2007) BioAmmonia – A comparison with other biofuels. Proceedings of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. Published online at http://www.energy.iastate.edu/Renewable/ ammonia/ammonia/ammoniaMtg07.htm.

  • PEW Center (2008), The Distribution of CHG Emissions by Sector. PEW center on global climate change. Published online at http://www.pewclimate.org/global-warming-basics/facts_and_figures/us.emissions/usghgemsector.cfm (accessed on May 27, 2008).

  • Sørensen, RZ, Nielsen, LJE, Jensen, S, Hansen, O, Johannessen, T, Quaade, U, Christensen, CH (2005) Catalytic ammonia decomposition: miniaturized production of COx-free hydrogen for fuel cells. Catalysis Communications 6:229–232.

    Article  Google Scholar 

  • Spath, PL a Mann, MK (2001) Life cycle assessment of hydrogen production via natural gas steam reforming. National Renewable Energy Laboratory p. 33.

    Google Scholar 

  • Starkman, ES, Newhall, HK, Sutton, R, Maguire, T, Farbar, L (1967) Ammonia as a spark ignition engine fuel: theory and application. SAE Transactions paper 660155, pp. 765–784.

    Google Scholar 

  • Stockes, K (2007) Ammonia construction record and comments on ammonia fuel. Proc. Of the Ammonia – Sustainable, Emission Free Fuel Conference, October 15–16, San Francisco, CA, Iowa Energy Center. Published online at http://www.energy.iastate.edu/ Renewable/ammonia/ammonia/ammoniaMtg07.htm.

  • Thomas, G, Parks, G (2008) Potential Roles of Ammonia in a Hydrogen Economy. published onlione at http:\\www.hydrogen.energy.gov/pdfs/nh3_paper.pdf (accessed on April 2, 2008).

  • Veziroglu, TN (2007) 21st Century’s energy: hydrogen energy system. International Scientific Journal for Alternative Energy and Ecology 4:29–39.

    Google Scholar 

  • Waitzman, DA (1979) Ammonia from coal: a technical/economic review. Process technology and flow sheets. V. Cavaseno Eds., Chemical Engineering, McGraw-Hill Publishing Co, NY, pp 63–65.

    Google Scholar 

  • Wesley, C (2008) Separating carbon from natural gas and reusing it to make carbon fiber. Canadian Business, March 17:64–64.

    Google Scholar 

  • Xie K, Ma Q, Jiang Y, Gao J, Liu X, Meng G (2007) An ammonia fuelled SOFC with a Ce0.9Nd0.1O3− δ thin electrolyte prepared with a suspension spray. Journal of Power Sources 170:38–41.

    Article  Google Scholar 

  • Yin, SF, Xu, BQ, Zhou, XP, Au, CT (2004) A mini-review on ammonia decomposition catalysts for on-site generation of hydrogen for fuel cell applications. Applied Catalysis A: General 277:1–9.

    Article  Google Scholar 

  • Zamfirescu, C, Dincer, I (2008a) Environmentally-benign hydrogen production from ammonia for vehicles. Proceedings of Global Conference on Global Warming, Istanbul July 6–10 paper 626.

    Google Scholar 

  • Zamfirescu, C, Dincer, I (2008b) Using ammonia as a sustainable fuel, Journal of Power Sources 85:459–465.

    Article  Google Scholar 

  • Zamfirescu, C, Dincer, I (2008c) Ammonia as a green fuel for transportation. Proceedings of ASME, Energy Sustainability Conference, August 10–14, Jacksonville, FL, paper 54329.

    Google Scholar 

  • Zamfirescu, C, Dincer, I (2009) Ammonia as a green fuel and hydrogen source for vehicular applications. Fuel Processing Technology. 90:729–737.

    Article  Google Scholar 

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Acknowledgment

The authors acknowledge the financial support provided by the Natural Sciences and Engineering Research Council of Canada in Canada.

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Zamfirescu, C., Dincer, I. (2010). Hydrogen Production from Ammonia as an Environmentally Benign Solution for Vehicles. In: Dincer, I., Hepbasli, A., Midilli, A., Karakoc, T. (eds) Global Warming. Green Energy and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-1017-2_5

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  • DOI: https://doi.org/10.1007/978-1-4419-1017-2_5

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