Definition of the Subject
Glasses belong to a well-known state of matter: we easily design glasses with desired mechanical or optical properties on an industrial scale,they are widely present in our daily life. Yet, a deep microscopic understanding of the glassy state of matter remains a challenge for condensedmatter physicists [6,67]. Glasses share similaritieswith crystalline solids (they are both mechanically rigid), but also with liquids (they both have similar disordered structures at the molecularlevel). It is mainly this mixed character that makes them fascinating even to non-scientists.
A glass can be obtained by cooling the temperature of a liquid below its glass temperature, T g. The quench must be fast enough that the more standard first order phase transition towards thecrystalline phase is avoided. The glass ‘transition’ is not a thermodynamic transition at all, since T gis only empirically defined as the temperature below which the material has become too viscous to...
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- 1.
The terminology ‘strong’ and ‘fragile’ is not related to the mechanical properties of the glass but to the evolution of the short-range order close to T g. Strong liquids, such as SiO2, have a locally tetrahedric structure which persists both below and above the glass transition contrary to fragile liquids whose short-range amorphous structure disappears rapidly upon heating above T g.
- 2.
The decrease at long times constitutes a major difference with spin glasses. In a spin glass, \( { \chi_4 } \) would be a monotonically increasing function of time whose long-time limit coincides with the static spin glass susceptibility. Physically, the difference is that spin glasses develop long-range static amorphous order while structual glasses do not or, at least, in a different and more subtle way.
- 3.
In order to have a well-defined thermodynamics, Bethe lattices are generated as random graphs with fixed connectivity, also called random regular graphs.
- 4.
There is of course no crystal state in disordered systems such as in Eq. (8). In the case of lattice glass models, there is a crystal phase but it can disappear depending whether the Bethe lattice is a Cayley tree or a random regular graph.
- 5.
A critical (different) behaviour is expected and predicted for models having a transition [158].
- 6.
- 7.
Most KCMs do not have a finite temperature dynamical transition and the ones displaying a transition have critical properties different from MCT.
Abbreviations
- Glossary:
-
In this preliminary section, a few concise definitions of the most important concepts discussed in this article are given.
- Glass transition:
-
For molecular liquids, the glass transition denotes a crossover from a viscous liquid to an amorphous solid. Experimentally, the crossover takes place at the glass temperature, T g, conventionally defined as the temperature where the liquid's viscosity reaches the arbitrary value of 1012 Pas. The glass transition more generally applies to many different condensed matter systems where a crossover or, less frequently, a true phase transition, takes place between an ergodic phase and a frozen, amorphous glassy phase.
- Aging:
-
In the glass phase, disordered materials are characterized by relaxation times that exceed common observation timescales, so that a material quenched in its glass phase never reaches equilibrium (neither a metastable equilibrium). It exhibits instead an aging behaviour during which its physical properties keep evolving with time.
- Dynamic heterogeneity:
-
Relaxation spectra of dynamical observables, e. g. the dynamical structure factor, are very broad in supercooled liquids. This is associated to a spatial distribution of timescales: at any given time, different regions in the liquid relax at different rates. Since the supercooled liquid is ergodic, slow regions eventually become fast, and vice versa. Dynamic heterogeneity refers to the existence of these non-trivial spatio-temporal fluctuations in the local dynamical behaviour, a phenomenon observed in virtually all disordered systems with slow dynamics.
- Effective temperature:
-
An aging material relaxes very slowly, trying (in vain) to reach its equilibrium state. During this process, the system probes states that do not correspond to thermodynamic equilibrium, so that its thermodynamic properties can not be rigorously defined. Any practical measurement of its temperature becomes a frequency-dependent operation. A ‘slow’ thermometer tuned to the relaxation timescale of the aging system measures an effective temperature corresponding to the ratio between spontaneous fluctuations (correlation) and linear response (susceptibility). This corresponds to a generalized form of the fluctuation‐dissipation theorem for off-equilibrium materials.
- Frustration:
-
Impossibility of simultaneously minimizing all the interaction terms in the energy function of the system. Frustration might arise from quenched disorder (as in spin glass models), from competing interactions (as in geometrically frustrated magnets), or from competition between a ‘locally preferred order’, and global, e. g. geometric, constraints (as in hard spheres packing problems).
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Acknowledgments
We thank C. Marchetti for inviting us to write this review and the collaborators who worked with us onglass physics. We thank J.-P. Bouchaud, A. Lefèvre, T. Sarlat for a careful reading of our manuscript and suggestions. Our work is supported by ANRGrants CHEF, TSANET and DYNHET.
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Berthier, L., Biroli, G. (2009). Glasses and Aging, A Statistical Mechanics Perspective on. In: Meyers, R. (eds) Encyclopedia of Complexity and Systems Science. Springer, New York, NY. https://doi.org/10.1007/978-0-387-30440-3_248
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