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Part of the book series: Lecture Notes in Physics ((LNP,volume 714))

Abstract

Classical concepts on polymer crystallization are under revision, due to the demands made by a wealth of new information acquired from experiments and computer simulations that explore the time-resolved molecular details of the crystallization process. A brief summary of the classical ideas and the contrasting new results is presented here.

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References

  1. K.H. Storks, An electron diffraction examination of some linear high polymers, J. Amer. Chem. Soc. 60, 1753–1761 (1938).

    Article  CAS  Google Scholar 

  2. A. Keller, A note on single crystals in polymers: evidence for a folded chain configuration, Phil Mag. 2, 1171–1175 (1957); P.H. Till, The growth of single crystals of linear polyethylene J. Polym. Sci. 24, 301–306 (1957); E. W. Fischer, Stufen- und spiralfoermiges Kristallwachstum beit Hochpolymeren, Z. Naturforsch. 12a, 753–754 (1957).

    Google Scholar 

  3. J.D. Hoffman, G.T. Davis and J.I. Lauritzen, in Treatise on Solid State Chemistry, Edited by N.P. Hannay, Plenum, N.Y. 1976; Vol. 3, Chapter 7, pp 497–614.

    Google Scholar 

  4. Organization of macromolecules in the condensed phase, Disc. Faraday Soc. 68 (1979).

    Google Scholar 

  5. P.J. Phillips, Polymer crystals, Rep. Prog. Phys. 53, 549–604 (1990).

    Article  CAS  Google Scholar 

  6. K. Armistead and G. Goldbeck-Wood, Polymer crystallization theories, Adv. Polym. Sci. 100, 219–312 (1992).

    Article  Google Scholar 

  7. J.I. Lauritzen and J.D. Hoffman, Theory of formation of polymer crystals with folded chains in dilute solution, J. Res. Nat. Bur. Std. 64A, 73–102 (1960).

    CAS  Google Scholar 

  8. I.C. Sanchez and E.A. DiMarzio, Dilute solution theory of polymer crystal growth: a kinetic theory of chain folding, J. Chem. Phys. 55, 893–908 (1971).

    Article  Google Scholar 

  9. G. Allegra, Chain folding and polymer crystallization: A statistical-mechanical approach, J. Chem. Phys. 66, 5453–5463 (1977).

    Article  CAS  Google Scholar 

  10. D.M. Sadler and G.H. Gilmer, A model for chain folding in polymer crystals: rough growth faces are consistent with the observed growth rates, Polymer 25, 1446–1452 (1984).

    Article  CAS  Google Scholar 

  11. J.J. Point and M. Dosière, Crystal growth rate as a function of molecular weight in polyethylene crystallized from the melt: an evaluation of the kinetic theory of polymer crystallization, Polymer 30, 2292–2296 (1989).

    Article  CAS  Google Scholar 

  12. M. Imai, K. Mori, T. Mizukami, K. Kaji and T. Kanaya, Structural formation of poly(ethylene terephthalate) during the induction period of crystallization: 1. Ordered structure appearing before crystal nucleation, Polymer, 33, 4451–4456 (1992).

    Article  CAS  Google Scholar 

  13. J.D. Hoffman and R.L. Miller, Kinetics of crystallization from the melt and chain folding in polyethylene fractions revisited: theory and experiment, Polymer 38, 3151–3212 (1997).

    Article  CAS  Google Scholar 

  14. P.D. Olmsted, W.C.K. Poon, T.C.B. McLeish, N.J. Terrill and A.J. Ryan, Spinodal-assisted crystallization in polymer melts, Phys. Rev. Lett. 81, 373–376 (1998).

    Article  CAS  Google Scholar 

  15. G. Reiter and J-U. Sommer, Crystallization of adsorbed polymer monolayers, Phys. Rev. Lett. 80, 3771–3774 (1998).

    Article  CAS  Google Scholar 

  16. N.V. Pogodina and H.H. Winter, Polypropylene crystallization as a physical gelation process, Macromolecules 31, 8164–8172 (1998).

    Article  CAS  Google Scholar 

  17. Y. Akpalu, L. Kielhorn, B.S. Hsiao, R.S. Stein, T.P. Russell, J. van Egmond and M. Muthukumar, Structure development during crystallization of homogeneous copolymers of ethene and 1-octene: Time-resolved synchrotron X-ray and SALS measurements, Macromolecules 32, 765–770 (1999).

    Article  CAS  Google Scholar 

  18. G. Strobl, From the melt via mesomorphic and granular crystalline layers to lamellar crystallites: A major route followed in polymer crystallization?, Eur. Phys. J. E 3, 165–183 (2000).

    Article  CAS  Google Scholar 

  19. B. Lotz, What can polymer structure tell about polymer crystallization processes?, Eur. Phys. J. E 3, 185–194 (2000).

    Article  CAS  Google Scholar 

  20. S.Z.D. Cheng, C.Y. Li and L. Zhu, Commentary on polymer crystallization: Selection rules in different length scales of a nucleation process, Eur. Phys. J. E 3, 195–197 (2000).

    Article  CAS  Google Scholar 

  21. J.K. Hobbs, T.J. McMaster, M.J. Miles and P.J. Barham, Direct observations of the growth of spherulites of poly(hydroxybutyrate-co-valerate) using atomic force microscopy, Polymer 39, 2437–2446 (1998).

    Article  CAS  Google Scholar 

  22. Y.K. Godovsky and S.N. Magonov, Atomic force microscopy visualization of morphology and nanostructure of an ultrathin layer of polyethylene during melting and crystallization, Langmuir 16, 3549–3552 (2000).

    Article  CAS  Google Scholar 

  23. M. Al-Hussein, and G. Strobl, The melting line, the crystallization line, and the equilibrium melting temperature of isotatic polystyrene, Macromolecules 35, 3895–3913 (2002).

    Article  CAS  Google Scholar 

  24. A. Wurm, R. Soliman, and C. Schick, Early stages of polymer crystallization - a dielectric study, Polymer 44, 7467–7476 (2003).

    Article  CAS  Google Scholar 

  25. S.Z.D. Cheng, and B. Lotz, Nucleation control in polymer crystallization: structural and morphological probes in different length- and time-scales for selection processes, Phil. Trans. Ro. Soc. London, A-Mathemat. Phys. and Engr. Sci 361, 517–536 (2003).

    Article  CAS  Google Scholar 

  26. M. Muthukumar, Molecular modelling of nucleation in polymers, Phil. Trans. R. Soc. Lond. A 361, 539–556 (2003).

    Article  CAS  Google Scholar 

  27. S. Umemoto, and N. Okui, Power law and scaling for molecular weight dependence of crystal growth rate in polymeric materials, Polymer 46, 8790–8795 (2005).

    CAS  Google Scholar 

  28. S. Rastogi, D.R. Lippits, G.W.M. Peters, R. Graf, Y.F. Yao, H.W. Spiess, Heterogeneity in polymer melts from melting of polymer crystals, Nature Materials 4, 635–641 (2005).

    Article  CAS  Google Scholar 

  29. C. Liu and M. Muthukumar, Langevin dynamics simulations of early-stage polymer nucleation and crystallization, J. Chem. Phys. 109, 2536–2542 (1998).

    Article  CAS  Google Scholar 

  30. J.P.K. Doye and D. Frenkel, Kinetic Monte Carlo simulations of the growth of polymer crystals, J. Chem. Phys. 110, 2692–2702 (1999).

    Article  CAS  Google Scholar 

  31. J-U. Sommer and G. Reiter, Polymer crystallization in quasi-two dimensions. II. Kinetic models and computer simulations, J. Chem. Phys. 112, 4384–4393 (2000).

    Article  CAS  Google Scholar 

  32. P. Welch and M. Muthukumar, Molecular mechanism of polymer crystallization from solution, Phys. Rev. Lett. 87, 218302-1-218302-4 (2001).

    Google Scholar 

  33. T. Yamamoto, Molecular dynamics simultion of polymer ordering. II. Crystallization from the melt, J. Chem. Phys. 115, 8675–8680 (2001).

    Article  CAS  Google Scholar 

  34. A. Toda, Kinetic barrier of pinning in polymer crystallization: Rate equation approach, J. Chem. Phys. 118, 8446–8455 (2003).

    Article  CAS  Google Scholar 

  35. T. Yamamoto, Molecular dynamics modeling of polymer crystallization from the melt, 45 1357–1364 (2004).

    Google Scholar 

  36. J. Zhang and M. Muthukumar, preprint.

    Google Scholar 

  37. A. Kundagrami and M. Muthukumar, foreprint.

    Google Scholar 

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Muthukumar, M. (2007). Shifting Paradigms in Polymer Crystallization. In: Reiter, G., Strobl, G.R. (eds) Progress in Understanding of Polymer Crystallization. Lecture Notes in Physics, vol 714. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-47307-6_1

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