Abstract
Titania layers were successfully prepared on the surfaces of Ti-6Al-4V alloy via anodic oxidation in H2SO4 or Na2SO4 solutions at room temperature. The titania layers consisted of pure rutile or a mixture of anatase and rutile structures after the Ti-6Al-4V alloy had been anodized in 1.0 M H2SO4 solution at 150 V or 0.5M Na2SO4 solution at 100 or 130 V. Good apatite-forming ability was demonstrated in simulated body fluid. However, surface layers with mainly titanium metallic phase or a pure anatase structure did not possess the ability to induce apatite formation. Anodic oxidation is an effective method to prepare bioactive Ti-6Al-4V alloy that can be used as an artificial bone substitute under load-bearing applications.
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References
R. Van Noort, J. Mater. Sci. 22, 3801 (1987).
M. Therin, A. Meunier, and P. Christel, J. Mater. Sci.: Mater. Med. 2, 1 (1991).
K. Wang, Mater. Sci. Eng. A 213, 134 (1996).
B. D. Ratner, Titanium in Medicine: Materials Science, Surface Science, Engineering, Biological Responses and Medical Applications (eds., D. M. Brunette, P. Tengvall, M. Textor, and P. Thomsen), p. 1, Springer, MA (2001).
M. P. Thomsen, A. S. Eriksson, R. Olsson, L. M. Bjursten, P. I. Branemark, and L. E. Ericson, Adv. Biomater. 7, 87 (1987).
K. de Groot, R. G. T. Geesink, C. P. A. T. Klein, and P. Serekian, J. Biomed. Mater. Res. 21, 1375 (1987).
M. Shirkhanzadeh, J. Mater. Sci.: Mater. Med. 3, 322 (1992).
H. Ishizawa and M. Ogino, J. Biomed. Mater. Res. 29, 65 (1995).
H.-M. Kim, F. Miyaji, T. Kokubo, and T Nakamura, J. Biomed. Mater. Res. 32, 409 (1996).
X. L. Zhu, K. H. Kim, and Y. Jeong, Biomaterials 22, 2199 (2001).
H.-M. Kim, H. Takadama, F. Miyaji, T. Kokubo, S. Nishiguchi, and T. Nakamura, J. Mater. Sci.: Mater. Med. 11, 555 (2000).
W. Q. Yan, T. Nakamura, M. Kobayashi, H.-M. Kim, F. Miyaji, and T. Kokubo, J. Biomed. Mater. Res. 37, 267 (1997).
S. Nishiguchi, H. Kato, H. Fujita, M. Oka, H.-M. Kim, T. Kokubo, and T. Nakamura, Biomaterials 22, 2525 (2001).
T. Kokubo, H.-M. Kim, M. Kawashita, and T. Nakamura, J. Mater. Sci.: Mater. Med. 15, 99 (2004).
M. Uchida, H.-M. Kim, T. Kokubo, and T. Nakamura, Bioceramics Vol. 12 (eds. H. Ohgushi, G. W. Hastings, and T. Yoshikawa), p. 149, World Scientific, Singapore (1999).
M. Uchida, H.-M. Kim, T. Kokubo, S. Fujibayashi, and T. Nakamura, J. Biomed. Mater. Res. 64A, 164 (2003).
T. Y. Xiong, X. Y. Cui, H.-M. Kim, M. Kawashita, T. Kokubo, J. Wu, H. Z. Jin, and T. Nakamura, Key Eng. Mater. 254–256, 375 (2004).
M. Kawashita, X. Y. Cui, H.-M. Kim, T. Kokubo, and T. Nakamura, Key Eng. Mater. 254–256, 459 (2004).
X. Cui, H.-M. Kim, M. Kawashita, L. Wang, T. Xiong, T. Kokubo, and T. Nakamura, J. Ceram. Soc. Jpn. 116, 329 (2008).
X. Cui, H.-M. Kim, M. Kawashita, L. Wang, T. Xiong, T. Kokubo, and T. Nakamura, J. Mater. Sci.: Mater. Med. 19, 1767 (2008).
X. Cui, H.-M. Kim, M. Kawashita, L. Wang, T. Xiong, T. Kokubo, and T. Nakamura, Dent. Mater. 25, 80 (2009).
T. Kokubo, H. Kushitani, S. Sakka, T. Kitsugi, and T. Yamamuro, J. Biomed. Mater. Res. 24, 721 (1990).
B. C. Yang, M. Uchida, H.-M. Kim, X. D. Zhang, and T. Kokubo, Biomaterials 25, 1003 (2004).
H. Takadama, H.-M. Kim, T. Kokubo, and T. Nakamura, J. Biomed. Mater. Res. 55, 185 (2001).
H. Takadama, H.-M. Kim, T. Kokubo, and T. Nakamura, J. Biomed. Mater. Res. 57, 441 (2001).
T. Kokubo, H.-M. Kim, and M. Kawashita, Biomaterials 24, 2161 (2003).
Joint Committee on Powder Diffraction Standards-International Center for Diffraction Data, Joint Committee on Powder Diffraction Standards Card. 2111276, Rutile.
Joint Committee on Powder Diffraction Standards-International Center for Diffraction Data, Joint Committee on Powder Diffraction Standards Card. 721243, Hydroxyapatite.
R. Z. LeGeros and J. P. LeGeros, An Introduction to Bioceramics (eds. L. L. Hench and J. Wilson), p. 139, World Scientific, Singapore (1993).
M. C. Bryan, Nature 260, 727 (1976).
J. M. Wu, S. Hayakawa, K. Tsuru, and A. Osaka, J. Am. Ceram. Soc. 87, 1635 (2004).
X. X. Wang, S. Hayakawa, K. Tsuru, and A. Osaka, J. Biomed. Mater. Res. 52, 171 (2000).
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Cui, X., Kim, HM., Kawashita, M. et al. Apatite formation on anodized Ti-6Al-4V alloy in simulated body fluid. Met. Mater. Int. 16, 407–412 (2010). https://doi.org/10.1007/s12540-010-0610-x
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DOI: https://doi.org/10.1007/s12540-010-0610-x