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A thermochemical study of cesium and nitrile perchloratozirconates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Measurements were carried out for the solution enthalpies of zirconium perchlorate, nitrile perchlorate, nitrile perchloratozirconate, and cesium perchloratozirconate in concentrated nitric acid. A thermochemical reaction cycle was established and the enthalpies of formation ΔHf 0 at 298.15 K were found for Zr(ClO4)4(s) (−745.5±2.7 kJ/mole), (NO2)2[Zr(ClO4)6](s) (−714.2±4.4 kJ/mole), and Cs2[Zr(ClO4)6](s) (−1656.3±4.5 kJ/mole).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    N. V. Krivtsov, V. P. Babaeva & V. Ya. Rosolovskii

Authors
  1. N. V. Krivtsov
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  2. V. P. Babaeva
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  3. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–913, April, 1990.

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Krivtsov, N.V., Babaeva, V.P. & Rosolovskii, V.Y. A thermochemical study of cesium and nitrile perchloratozirconates. Russ Chem Bull 39, 817–820 (1990). https://doi.org/10.1007/BF00960355

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  • DOI: https://doi.org/10.1007/BF00960355

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