Abstract
Total suspended particles (TSP) and particulate matter ≤ 2.5 µm (PM2.5) from Beijing, China, were studied for a time period of three years (2005– 2008). Beside the total mass and the element concentrations, also the chemical fractionation and bioavailability of various elements was investigated by applying a four-step sequential extraction scheme.
Potential toxic metals like Zn, Cd, As, Pb, and Mn occurred to a high percentage in the mobile fractions and are, thus, especially harmful to the environment and exposed people due to an assumed high bioavailability. Arsenic, Pb, and Ni were even more mobile in the fine fraction (PM2.5 samples), which is of special concern with regard to human health because smaller particles are considered to be more health relevant.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
WHO (2001) Environment and people’s health in China.
Kappos A, Bruckmann P, Eikmann T, Englert N, Heinrich U, Höppe P, Koch E, Krause G, Kreyling W, Rauchfuss K, Rombout P, Schulz-Klemp V, Thiel W, Wichmann, H-E (2004) Health effects of particles in ambient air. International Journal of Hygiene and Environmental Health 207, 399–407.
Schwartz J, Dockery D, Neas L (1996) Is daily mortality associated specifically with fine particles? Journal of the Air and Waste Management Association 46, 927–939.
Dreher KL, Jaskot RH, Lehmann JR, Richards JH, McGee JK, Ghio AJ, Costa DL (1997) Soluble transition metals mediate residual oil flyash induced acute lung injury. Journal of Toxicology and Environmental Health 50, 258–305.
Kodavanti UP, Jaskot RH, Costa DL, Dreher KL (1997) Pulmonary proinflammatory gene induction following acute exposure to residual oil fly ash: roles of particle-associated metals. Inhalation Toxicology, 9(7), 679–701.
Chillrud SN, Epstein D, Ross JM, Sax SN, Pederson D, Spengler J, Kinney PL (2004) Elevated airborne exposures of teenagers to manganese, chromium, and iron from steel dust and New York City’s subway system. Environmental Science and Technology 38(3), 732–737.
Smichowski P, Polla G, Gómez D (2005) Metal fractionation of atmospheric aerosols via sequential chemical extraction: a review. Analytical and Bioanalytical Chemistry 381, 302–316.
Hirner AV (1992) Trace element speciation in soils and sediments using sequential extraction methods. International Journal of Environmental Analytical Chemistry 46, 77–85.
Linge KL (2008) Methods for investigating trace element binding in sediments. Critical Reviews in Environmental Science and Technology 38, 165–196.
Hlavay J, Polyák K, Bódog I, Molnár Á, Mészáros E (1996) Distribution of trace elements in filter-collected aerosol samples. Fresenius Journal of Analytical Chemistry 354, 227–232.
Heiser U, Norra S, Stüben D, Wagner M (1999) SequentielleSchwermetallextraktion aus Staubniederschlägen und Straßensedimenten –Teil II: Sequentielle Schwermetallextraktion von städtischen Stäuben.Umweltwissenschaften und Schadstoffforschung 11 (2), 73 –78 (in Germanwith English abstract).
Fernández Espinosa AJ, Ternero Rodríguez M, Barragán de la Rosa FJ, Jiménez Sánchez JC (2000) An approach to characterization of sources of urban airborne particles through heavy metal speciation. Chemosphere – Global Change Science 2, 123–136.
Fujiwara F, Dos Santos M, Marrero J, Polla G, Gómez D, Dawidowski L, Smicowski P (2006) Fractionation of eleven elements by chemical bonign from airborne particulate matter collected in an industrial city in Argentina. Journal of Environmental Monitoring 8, 913–922.
Richter P, Griño P, Ahumada I, Giordano A (2007). Total element concentration and chemical fractionation in airborne particulate matter from Santiago, Chile. Atmospheric Environment 41, 6729–6738.
Canepari S, Perrino C, Olivieri F, Astolfi ML (2008) Characterisation of the traffic sources of PM through size-segregated sampling, sequential leaching and ICP analysis. Atmospheric Environment 42, 8161–8175.
Praveen Kumar M, Venkata Mohan S, Jayarama Reddy S (2008) Chemical fractionation of heavy metals in airborne particulate matter (PM10) by sequential extraction procedure. Toxicology and Environmental Chemistry 90(1), 31–41.
Fernández Espinosa AJ, Ternero Rodríguez M, Barragán de la Rosa FJ, Jiménez Sánchez JC (2002) A chemical speciation of trace metals for fine urban particles. Atmospheric Environment 36, 773–780.
Schleicher N, Norra S, Chai F, Chen Y, Wang S, Stüben D (2010) Anthropogenic versus geogenic contribution to total suspended atmospheric particulate matter and its variations during a two-year sampling period in Beijing, China. Journal of Environmental Monitoring 12, 434–441.
Norra S, Schleicher N, Stüben D, Chai F, Chen Y, Wang S (2010) Assessment of aerosol concentration sampled at five sites in Beijing from 2005 till 2007. In: Rauch S. et al. (eds.), Highway and Urban Environment, Alliance for Global Sustainability Bookseries 17, 133–140, Springer.
Schleicher N, Norra S, Chai F, Chen Y, Wang S, Stüben D. (2010) Seasonal trend of water-soluble ions at one TSP and five PM2.5 sampling sites in Beijing, China. In: Rauch S. et al. (eds.), Highway and Urban Environment, Alliance for Global Sustainability Bookseries 17, 87 95, Springer.
Reimann C and Caritat P (Eds.) (1998) Chemical elements in the environment. Factsheets for the geochemist and environmental scientist. Springer.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2012 Springer Science+Business Media B.V.
About this paper
Cite this paper
Schleicher, N. et al. (2012). Mobility of trace metals in urban atmospheric particulate matter from Beijing, China. In: Rauch, S., Morrison, G. (eds) Urban Environment. Alliance for Global Sustainability Bookseries, vol 19. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2540-9_18
Download citation
DOI: https://doi.org/10.1007/978-94-007-2540-9_18
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-2539-3
Online ISBN: 978-94-007-2540-9
eBook Packages: EngineeringEngineering (R0)