Regular ArticleRb3P6N11 and Cs3P6N11—New Highly Condensed Nitridophosphates by High-Pressure High-Temperature Synthesis
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Cited by (28)
Phosphorus-doped nitrogen clusters (N<inf>n</inf>P<inf>m</inf>): Stable high energy density materials
2016, Chemical Physics LettersCitation Excerpt :Their study showed that unlike the Nn clusters, the NnPm cluster are stable and can be experimentally synthesized. Crystalline structures of MP4N7 (M = Na, K, Rb, Cs) and M3P6N11 (M = Rb, Cs) have been synthesized under high temperature and high pressure conditions and their structures studied by XRF [27,28]. Wang et al. [29] studied energetic and structural properties of P(N3)n and P(N4)n (n = 1–4), theoretically.
Novel TaPO <inf>5-x</inf>N <inf>2x/3</inf> oxynitrides
2012, Journal of Alloys and CompoundsCitation Excerpt :Phosphates present several similarities with silicates linked to the common structural entity formed by the XO4 (X = P, Si) tetrahedron. The progressive substitution of nitrogen for oxygen within the anionic network of metal phosphate compounds leads to the formation of a family of solids: the nitridophosphates [2], for example AP4N7 (A+ = Na, K, Rb, Cs) [3], A3P6N11 (A+ = Rb, Cs) [4], BaAP6N12 (A+ = Ca, Sr) and BaP2N4 [5]. The phosphorus-based tetrahedra can be fully nitrided in the ternary nitrides Mg2PN3, LiPN2 or Li7PN4 (PN4 tetrahedra), partially in the oxynitride PON (PO2N2 tetrahedra) and showing a large domain of compositions in nitrided phosphate glasses (PO4−xNx tetrahedra) [6–8].
State of Art and recent trends in bulk carbon nitrides synthesis
2008, Materials Science and Engineering R: ReportsHigh-pressure synthesis and X-ray powder structure determination of the nitridophosphate BaP<inf>2</inf>N<inf>4</inf>
2005, Journal of Solid State Chemistry
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